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Rhodium and iridium

  • Chapter
Chemistry of Precious Metals

Abstract

Rhodium and iridium were discovered independently in the same year and also share many resemblances in their chemistry [1–10]. They form a wide range of conventional complexes as well as those of π-bonding ligands. Both metals exhibit an extensive chemistry, principally in the +3 oxidation state, with +1 also being important, and a significant chemistry of iridium +4 existing. Few compounds are known in the +2 state, in contrast to the situation for cobalt, their lighter homologue (factors responsible include the increased stability of the +3 state consequent upon the greater stabilization of the low spin d6 configuration as 10 Dq increases).

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    Dr S. A. Cotton

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Cotton, S.A. (1997). Rhodium and iridium. In: Chemistry of Precious Metals. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1463-6_2

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