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Cationic Transannular Oligomerization Of 1,5-Cyclooctadiene

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Integration of Fundamental Polymer Science and Technology—2

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Abstract

Cationic transannular oligomerization of 1,5-cyclooctadiene initiated by BF3OEt2 and AlCl3 is presented in this paper. The number-average molecular weight of the resultant polymer is about 1,500, and the softening temperature range is 140–160°C. By means of NMR, IR and PC-MS analyses, the chain structure of poly(l,5-cyclooctadiene) proposed earlier by Marvel et al. is corroborated.

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References

  1. Reichel, B. and Marvel, C.S., J.Polymer Sci; Part A, 1963, 1, 2935.

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  2. Deyue Yan, Qigui Guo, Ping Xia, Xueqing Wu, Seng Li, Kexue Tongbao, (in Chinese) 1984, 29, 1560.

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  3. Ledwith, A. and Sherrington, D.C., Reactivity and Mechanism in Cationic Polymerization, Chap. 9, In Reactivity, Mechanism and Structure in Polymer Chemistry, ed. A.D. Jenkins and A. Ledwith, Wiley-Inter- science, New York, 1974.

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  4. Kennedy, J.P & Feinberg, S.C., J. Polymer Sci.:Polym. Chem.Ed., 1978, 16, 2191.

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Author information

Authors and Affiliations

  1. polymeric Materials Research Institute, Shanghai Jiao Tong University, China

    Cuiming Yuan, Deyue Yan & Xiangming Xu

  2. Changchun Institute of Applied Chemistry, Academia Sinica, China

    Fosong Wang

Authors
  1. Cuiming Yuan
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  2. Deyue Yan
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  3. Xiangming Xu
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  4. Fosong Wang
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Editor information

Editors and Affiliations

  1. Eindhoven University of Technology, Eindhoven, The Netherlands

    P. J. Lemstra

  2. DSM-Research, Geleen, The Netherlands

    L. A. Kleintjens

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© 1988 Elsevier Applied science publishers Ltd.

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Yuan, C., Yan, D., Xu, X., Wang, F. (1988). Cationic Transannular Oligomerization Of 1,5-Cyclooctadiene. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—2. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1361-5_10

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  • DOI: https://doi.org/10.1007/978-94-009-1361-5_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7106-2

  • Online ISBN: 978-94-009-1361-5

  • eBook Packages: Springer Book Archive

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