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The Scattering of Light by Swollen Networks

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Biological and Synthetic Polymer Networks

Abstract

Swollen networks scatter more light than solutions of linear molecules of the same concentration. This occurs because of the concentration fluctuations associated with the variation of the local degree of swelling related to variations in the local crosslink density. Measurements are reported on model end-linked bimodal networks of controlled heterogeneity, and compared with theoretical estimates of the effect. The observed discrepancy is indicative of the need for an improvement in concepts of micro deformation of networks during swelling.

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References

  1. Bhagavantam, S., The Scattering of Light and the Raman Effect, Chemical Publishing Co., New York, 1942.

    Google Scholar 

  2. Debye, P. and Bueche, A. M., J. Appl. Phys., 1949, 20, 518.

    Article  CAS  Google Scholar 

  3. Benoit, H. et al., J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 2119.

    Google Scholar 

  4. Stein, R. S., J. Polym. Sci., Polym. Lett. Ed., 1969, 7, 657.

    Article  CAS  Google Scholar 

  5. Flory, P. J. and Rehner, J., J. Chem. Phys., 1949, 11, 521.

    Article  Google Scholar 

  6. Flory, P. J., Principles of Polymer Chemistry, Cornell University Press, Ithaca, New York, 1953.

    Google Scholar 

  7. Flory, P. J., J. Chem. Phys., 1942, 10, 51.

    Article  CAS  Google Scholar 

  8. Huggins, M. H., J. Phys. Chem., 1942, 46, 151;

    Article  CAS  Google Scholar 

  9. Huggins, M. H.Ann. NY Acad. Sci., 1942, 41, 1.

    Article  Google Scholar 

  10. Kuhn, W., Koll. Zeitschr., 1936, 76, 258;

    Article  CAS  Google Scholar 

  11. Kuhn, W. Angew. Chem., 1938, 51, 640.

    Article  CAS  Google Scholar 

  12. James, H. M. and Guth, E., J. Chem. Phys., 1947, 15, 651.

    Article  CAS  Google Scholar 

  13. Langley, N. R., Macromolecules, 1968, 1, 348.

    Article  CAS  Google Scholar 

  14. Edwards, S. F., Brit. Polym. J., 1977, 9, 140.

    Article  CAS  Google Scholar 

  15. Flory, P. J. and Erman, B., Macromolecules, 1982, 15, 800, 806.

    Google Scholar 

  16. Einstein, A., Ann. de Physik, 1910, 33, 1275.

    Article  CAS  Google Scholar 

  17. Mark, J. E., in Elastomers and Rubber Elasticity, Mark, J. E. and Lal, J. (Eds), American Chemical Society, Washington, DC, 1982.

    Chapter  Google Scholar 

  18. Schultz, G. V., Z. Physik. Chem., 1939, B43, 25.

    Google Scholar 

  19. Stein, R. S., Farris, R. J., Kumar, S. and Soni, V., in Elastomers and Rubber Elasticity, Mark, J. E. and Lal, J. (Eds), American Chemical Society, Washington, DC, 1982.

    Google Scholar 

  20. Soni, V. K., Optical studies of swollen polymer networks, PhD Dissertation, University of Massachusetts, Amherst, 1986.

    Google Scholar 

  21. Fischer, A. and Gotlieb, M., Poster at Networks’86, Elsinore, Denmark, September 1986.

    Google Scholar 

  22. Stein, R. S., Soni, V. K. and Yang, H. E., Optical Studies of Network Topology, in press.

    Google Scholar 

  23. Stein, R. S. and Keane, J. J., J. Polym. Sci., 1955, 17, 21.

    Article  CAS  Google Scholar 

  24. Hrabowska, J. and Stein, R. S., Poster at Networks’86, Elsinore, Denmark, September 1986.

    Google Scholar 

  25. Bastide, J., Picot, C. and Candau, S., J. Macromol. Sci., Phys., 1981, B19, 13.

    CAS  Google Scholar 

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© 1988 Elsevier Applied Science Publishers Ltd

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Stein, R.S., Soni, V.K., Yang, H., Erman, B. (1988). The Scattering of Light by Swollen Networks. In: Kramer, O. (eds) Biological and Synthetic Polymer Networks. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1343-1_26

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  • DOI: https://doi.org/10.1007/978-94-009-1343-1_26

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7097-3

  • Online ISBN: 978-94-009-1343-1

  • eBook Packages: Springer Book Archive

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