Abstract
The current understanding of the effect of dopants on diffusion through the lattice and along grain boundaries in oxides is reviewed. The experimental studies for grain boundary diffusion, which is the more relevant to oxidation, show apparently contradictory results and these are discussed critically in terms of the experimental conditions employed. Guided by the results of computer simulations, a possible rationalisation is proposed to explain the results on synthetic oxides and the influence of reactive elements on transport through oxidation scales.
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References
D.P. Whittle and J. Stringer; Phil. Trans. Roy. Soc. Lond., 1980, A295, 309–329.
A.M. Huntz; Mater. Sci. Eng., 1987, 87, 251–260.
V.G. Schwier, R. Dieckmann and H. Schmalzried; Ber. Bunsen. Phys. Chem., 1973, 77, (6), 402–408.
R. Dieckmann; Solid State Ionics, 1984, 12, 1–22.
W.C. Mackrodt; Solid State Ionics, 1984, 12, 175–188.
A. Atkinson, A.E. Hughes, and A. Hammou; Philos. Mag. A, 1981, 43, (5), 1071–1091.
C. Wagner; Z. Phys. Chem. B, 1933, 21, (1/2), 25–41.
C. Wagner; Corros. Sci., 1969, 9, 91–109.
W.W. Smeltzer; in “Oxidation of Metals and Associated Mass Transport”, (eds. M.A. Dayananda ETAL.), 109–129; 1986, Warrendale PA, The Metals Society.
A. Atkinson, D.W. Smart and R.I. Taylor; Werkst. u. Korros., 1987, 38, 704–709.
A. Atkinson; Rev. Mod. Phys., 1985, 57, (2), 437–470.
A.T. Chadwick and R.I. Taylor; Solid State Ionics, 1984, 12, 343–351.
A.A. Moosa, S.J. Rothman and L.J. Nowicki; Oxidation of Metals, 1985, 24, (3/4), 115–132.
J.W. Osenbach and V.S. Stubican; J. Amer. Ceram. Soc., 1983, 66, (3), 191–195.
J-H. Park, W.E. King and S.J. Rothman; J. Amer. Ceram. Soc., 1987, 70, (12), 880–885.
D.P. Moon; 1987, D. Phil. Thesis, University of Oxford, UK.
P.J. George, M.J. Bennett, H.E. Bishop and G. Dearnaley; AERE Report R12873, Harwell Laboratory, UK, 1988.
A. Atkinson and R.I. Taylor; J. Phys. Chem. Solids, 1986, 47, 315–320.
B. Bender, D.B. Williams and M.R. Nous; J. Amer. Ceram. Soc., 1980, 63, (9/10), 542–546.
M.F. Yan, R.M. Cannon and H.K. Bowen; J. Appl. Phys., 1983, 54, (2), 764.
D.M. Duffy and P.W. Tasker; Philos. Mag. A, 1986, 54, 759.
D.M. Duffy and P.W. Tasker; Report TP 1155, Harwell Laboratory, UK, 1986.
C.E. Birchenall; in “Mass Transport in Oxides”, (eds. J.B. Wachtman and A.D. Franklin), NBS Special Publication 296 (Washington, 1968), 119–127.
H. Matzke; Advances in Ceramics, 1986, 17, 1–54.
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© 1989 ECSC, EEC, EAEC. Brussels and Luxembourg
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Atkinson, A. (1989). Effect of Active Elements on Diffusion Properties of Synthetic Oxides. In: Lang, E. (eds) The Role of Active Elements in the Oxidation Behaviour of High Temperature Metals and Alloys. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1147-5_5
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DOI: https://doi.org/10.1007/978-94-009-1147-5_5
Publisher Name: Springer, Dordrecht
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