Skip to main content

Effect of Active Elements on Diffusion Properties of Synthetic Oxides

  • Chapter

Abstract

The current understanding of the effect of dopants on diffusion through the lattice and along grain boundaries in oxides is reviewed. The experimental studies for grain boundary diffusion, which is the more relevant to oxidation, show apparently contradictory results and these are discussed critically in terms of the experimental conditions employed. Guided by the results of computer simulations, a possible rationalisation is proposed to explain the results on synthetic oxides and the influence of reactive elements on transport through oxidation scales.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. D.P. Whittle and J. Stringer; Phil. Trans. Roy. Soc. Lond., 1980, A295, 309–329.

    Google Scholar 

  2. A.M. Huntz; Mater. Sci. Eng., 1987, 87, 251–260.

    Article  CAS  Google Scholar 

  3. V.G. Schwier, R. Dieckmann and H. Schmalzried; Ber. Bunsen. Phys. Chem., 1973, 77, (6), 402–408.

    CAS  Google Scholar 

  4. R. Dieckmann; Solid State Ionics, 1984, 12, 1–22.

    Article  CAS  Google Scholar 

  5. W.C. Mackrodt; Solid State Ionics, 1984, 12, 175–188.

    Article  CAS  Google Scholar 

  6. A. Atkinson, A.E. Hughes, and A. Hammou; Philos. Mag. A, 1981, 43, (5), 1071–1091.

    Article  CAS  Google Scholar 

  7. C. Wagner; Z. Phys. Chem. B, 1933, 21, (1/2), 25–41.

    Google Scholar 

  8. C. Wagner; Corros. Sci., 1969, 9, 91–109.

    Article  CAS  Google Scholar 

  9. W.W. Smeltzer; in “Oxidation of Metals and Associated Mass Transport”, (eds. M.A. Dayananda ETAL.), 109–129; 1986, Warrendale PA, The Metals Society.

    Google Scholar 

  10. A. Atkinson, D.W. Smart and R.I. Taylor; Werkst. u. Korros., 1987, 38, 704–709.

    Article  CAS  Google Scholar 

  11. A. Atkinson; Rev. Mod. Phys., 1985, 57, (2), 437–470.

    Article  CAS  Google Scholar 

  12. A.T. Chadwick and R.I. Taylor; Solid State Ionics, 1984, 12, 343–351.

    Article  CAS  Google Scholar 

  13. A.A. Moosa, S.J. Rothman and L.J. Nowicki; Oxidation of Metals, 1985, 24, (3/4), 115–132.

    Article  CAS  Google Scholar 

  14. J.W. Osenbach and V.S. Stubican; J. Amer. Ceram. Soc., 1983, 66, (3), 191–195.

    Article  CAS  Google Scholar 

  15. J-H. Park, W.E. King and S.J. Rothman; J. Amer. Ceram. Soc., 1987, 70, (12), 880–885.

    Article  CAS  Google Scholar 

  16. D.P. Moon; 1987, D. Phil. Thesis, University of Oxford, UK.

    Google Scholar 

  17. P.J. George, M.J. Bennett, H.E. Bishop and G. Dearnaley; AERE Report R12873, Harwell Laboratory, UK, 1988.

    Google Scholar 

  18. A. Atkinson and R.I. Taylor; J. Phys. Chem. Solids, 1986, 47, 315–320.

    Article  CAS  Google Scholar 

  19. B. Bender, D.B. Williams and M.R. Nous; J. Amer. Ceram. Soc., 1980, 63, (9/10), 542–546.

    Article  CAS  Google Scholar 

  20. M.F. Yan, R.M. Cannon and H.K. Bowen; J. Appl. Phys., 1983, 54, (2), 764.

    Article  CAS  Google Scholar 

  21. D.M. Duffy and P.W. Tasker; Philos. Mag. A, 1986, 54, 759.

    Article  CAS  Google Scholar 

  22. D.M. Duffy and P.W. Tasker; Report TP 1155, Harwell Laboratory, UK, 1986.

    Google Scholar 

  23. C.E. Birchenall; in “Mass Transport in Oxides”, (eds. J.B. Wachtman and A.D. Franklin), NBS Special Publication 296 (Washington, 1968), 119–127.

    Google Scholar 

  24. H. Matzke; Advances in Ceramics, 1986, 17, 1–54.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1989 ECSC, EEC, EAEC. Brussels and Luxembourg

About this chapter

Cite this chapter

Atkinson, A. (1989). Effect of Active Elements on Diffusion Properties of Synthetic Oxides. In: Lang, E. (eds) The Role of Active Elements in the Oxidation Behaviour of High Temperature Metals and Alloys. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1147-5_5

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-1147-5_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7009-6

  • Online ISBN: 978-94-009-1147-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics