Abstract
Femtosecond laser spectroscopy and nonlinear optical or photophysical measurements up to 100 picoseconds have become a powerful tool to explore dynamics, photophysics, photochemistry and photobiology of molecules in dense media. A review of contempory details of the experimental design concepts in ultrafast pump—probe laser spectroscopy links the observables with the underlying theory, where the currei. limits of time resolution approach a few optical cycles. Selected studies are then outlined to illustrate some of the scientific questions currently being investigated in our research group and several other laser laboratories, whose focus is on the time evolution of dynamical events in dense media.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Applications of Picosecond Spectroscopy to Chemistry, ed. K.B. Eisenthal (D.Reidel Publishing Company, Boston, 1984).
M.D. Levenson, Introduction to Nonlinear Laser Spectroscopy (Academic Press, N.Y.1982).
J.P. Hansen and I. MacDonald Optical Phase Conjugation, ed. R.A. Fisher, (Academic Press, N.Y. 1983).
Ultrafast Phenomena, (Springer-Verlag); a research series published biannually since 1978. These books comprise the invited papers and proceedings of the International Ultrafast Phenomena meetings with the conference chairman as editors.
Ultrafast Phenomena, Special Issue of International Quantum Electronics, IEEE JQE 24 (1988) ed. A.Johnson and references therein to the various papers on pulse generation, amplification, nonlinear optical measurements and dynamics.
B.J. Berne and R. Pecora, Dynamic Light Scattering, (Wiley N.Y. 1976).
Molecular Liquids = Dynamics and Interactions ed.A.J.Barnes, W.J.Orville-Thomas and J.Yarwood (Dreidel Publishing Company, 1984).
B. Berne in Advanced Treatise on Physical Chemistry, vol VIII B ed. D.Henderson, Academic Press 1971; R.G.Gordon, Adv.Magnetic Res. 3, 1(1968).
J.D. Simon, Acc.Chem. Res. 21(3) 128–134 (1988).
G.A. Kenney-Wallace, Ultrafast Laser Spectroscopy and Applications in Lasers in Chemistry, ed. K.Evans (Marcel Dekker, N.Y. 1988).
E. Quitevis, P.M. Kro er, C. Kalpouzos, G.A. Kenney-Wallace, Can.J.Chem.61, 975 (1983).
D. McMorrow, W.T. Lotshaw and G.A. Kenney-Wallace IEEE J.Quant.Elec. 24, 443(1988).
G.A. Kenney-Wallace, M. Golombok, and T. Dickson, J.Chem.Soc.Faraday 83, 1825 (1987).
J.A. Valdmanis, R.L. Fork, and J.P. Gordon Optic. Lett.10, 131 (1985) and references therein.
E.B. Treacy IEEE J. Quant. Elec. QE-5, 454, 1959; B.Nikolaus and D.Grischkowsky, Applied Phys. Lett. 43, 228 (1983) and references therein
G.A. Kenney-Wallace, E. Quitevis, and E. Templeton, Reviews of Chem. Intermediates 6, 197 (1985).
A.E. Siegman, Appl. Phys. Lett. 30, 21 (1977);
R. Trebino, C.E. Barber, and A.E. Siegman, IEEE J. Quant. Elec. QE-22 1413 (1986).
B. Bagchi, D.W. Oxtoby, and G.R. Fleming, Chem. Phys. 86, 257(1984).
G. Van der Zwan, and J.T. Hynes, J. Phys. Chem. 89, 4181(1985).
H. Sumi, and R.A. Marcus, J. Chem. Phys. 84, 4272(1986).
P.G. Wolynes, J. Chem. Phys. 86, 5133(1987).
S.R. Flom, and R.F. Barbara, J. Phys. Chem. 89, 4489(1985).
D.F. Calef, and P.G. Wolynes, J. Chem. Phys. 78, 4145(1983).
Y.T. Mazurenko, and N.G. Bakhshiev, Opt. Spectrosc., 28, 490(1970).
D.F. Calef, and P.G. Wolynes, J. Phys. Chem. 87, 3387(1983).
G. Van der Zwan, and J.T. Hynes, Chem. Phys. Lett. 101, 367(1983).
E.W. Castner Jr., M. Maroncelli, and G.R. Fleming, J. Chem. Phys. 86(3), 1090(1987).
A. Safarzadeh-Amiri, Chem. Phys. Lett., 125(3), 272(1986).
S.W. Yeh, L.A. Philips, S.P. Webb, L.F. Buhse, and J.H. Clark, in Ultrafast Phenomena IV, ed. D.H.Auston and K.B.Eisenthal (Springer-Verlag), Berlin, 359(1984).
M. Maroncelli, and G.R. Fleming, J. Chem. Phys. 86(11), 6221(1987).
V. Nagarajan, A.M. Brearley, T.J. Kang, and P.F. Barbara, J. Chem. Phys. 86, 3183(1983).
A. Einstein, Ann. Phys. 19, 289(1906).
C.M. Hu, and R. Zwanzig, J. Chem. Phys. 60, 4354(1974).
A. Gierer, and K.Z. Wertz, Naturforsch A 8, 532(1953).
A. Von Jena, and H.E. Lessing, Chem. Phys. Lett. 78, 187(1981).
L.A. Philips, S.P. Webb, S.W. Yeh, and J.H. Clark, J. Phys. Chem. 89, 17(1985).
F.J. Perrin, Phys. Radium 5, 497(1934).
T. Tao, Biopolymers 8, 609(1969).
E.F. Gudgin Templeton, and G.A. Kenney-Wallace, The Journal of Phy3. Chem.90, 5441(1986).
D. Waldeck, A.J. Cross Jr., D. McDonald, and G.R. Fleming, J. Chem. Phy3. 74, 3381(1981).
A. Von Jena, and H.E. Lessing, Chem. Phys. 40(3), 245(1979).
D. Kivelson, and P.A. Madden, Annu. Rev. Phys. Chem. 31, 523(1980).
B. Kowert, and D. Kivelson, J. Chem. Phys. 64, 5206(1976).
K.B. Eisenthal, Ace. Chem. Res. 8, 62(1975).
T.J. Chuang, and K.B. Eisenthal, J.Chem.Phys.57, 5094(1972).
G.J. Blanchard, J. Chem. Phys. 87(12), 6802(1987).
J.T. Hynes, R. Kapral, and M. Weinberg, J. Chem. Phys. 69, 2725(1978).
M.J. Sanders, and M.J. Wirth, Chem. Phys. Lett. 101, 361(1983).
G.R. Fleming, A.E.W. Knight, J.M. Morris, and R.J. Robinson, Chem. Phys. Lett.51, 399(1978).
D.H. Waldeck, W.T. Lotshaw, D.B. McDonald, and G.R. Fleming, Chem. Phys. Lett. 88, 297(1982).
R.S. Moog, M.D. Ediger, S.G. Boxer, and M.D. Fayer, J. Phys. Chem. 85, 4694(1982).
K.G. Spears, and L.E. Cramer, Chem. Phys. 30, 1(1978).
D.H. Waldeck, and G.R. Fleming, J. Phys. Chem. 85, 2614(1981)
E.F. Gudgin, and G.A. Kenney-Wallace AIP Conf. Proc. 1986, 146 (Adv. Laser Sci.-1), 600–3.
Y.K. Lau, P.P.S. Saluja, and P. Kebarle, J. Am. Chem. Soc. 102, 7429(1980).
R.R. Hentz, and G.A. Kenney-Wallace, J.Phys.Chem.78, 514(1974).
K.G. Spears, and K.M. Steinmetz, J.Phys.Chem.89, 3623(1985).
D.P. Millar, R. Shah, and A.H. Zewail, Chem.Phys.Lett.66, 435(1979).
D. Waldeck, A.J. Cross Jr., D.B. McDonald, and G.R. Flemirg, J.Chem.Phys.74, 3381(1891).
D. Reiser, and A. Laubereau, Ber Bunsenges, Phys. Chem. 86, 1106(1982).
D. Reiser, and A. Laubereau, Opt. Commun. 42, 329(1982).
D. Reiser, and A. Laubereau, Chem. Phys. Lett. 92, 297(1982).
G.J. Blanchard, and M.J. Wirth, J. Chem. Phys. 82(1), (1985).
P. Madden, and D. Kivelson, J. Phys. Chem. 86, 4244(1982).
T.W. Nee, and R. Zwanzig, J. Chem. Phys. 52, 6353(1970).
J.B. Hubbard, and P.G. Wolynes, J. Chem. Phys. 69, 998(1979).
P.A. Madden, and D. Kivelson, Adv. Chem. Phys. 56, 467(1984).
E.F. Gudgin Templeton, and G.A. Kenney-Wallace, J. Phys. Chem. 90
L.A. Philips, S.P. Webb, S.W. Yeh, and J.H. Clark, J. Phys. Chem. 89, 17(1985).
L.A. Philips, S.P. Webb, and J.H. Clark, J. Chem. Phys. 83(11), 5810(1985).
G.A. Kenney-Wallace, S. Paone and C. Kalpouzos, Farad. Discuss. Chem. Soc. 85, 1 (1988)
E.J. Hart, M. Anbar, The Hydrated Electron, Wiley, N.Y. (1970).
J. Jortner, and N.R. Kestner eds., Electrons in Fluids, (Springer-Verlag), N.Y. (1973); L.Kevan, and B.C.Webster eds. Electron - Solvent and Anion - Solvent Interactions, Elsevier, N.Y.(1976).
Liquid State and its Electrical Properties, ed. L.Luessen and L.Christophoron NATO ASI in press, 1988.
G.A. Kenney-Wallace, Adv. Chem. Phys. 57, 535(1981).
G.A. Kenney-Wallace, and C.D. Jonah, J. Phys. Chem. 86, 2572(1982).
G.A. Kenney-Wallace, Can. J. Chem. 55, 2009 (1977)
G.A. Kenney-Wallace, and C.D. Jonah, Chem. Phys. Lett. 39, 596(1976).
G.A. Kenney-Wallace, G.E. Hall, L.A. Hunt, and K. Sarantidis, J. Phys. Chem. 84, 1145(1980).
G.A. Kenney-Wallace, C. Kalpouzos and W.T. Lotshaw, Int. J. Radiat. Phys. Chem. 32, 573 (1988).
A. Migus, Y. Gauduel, J.L. Martin, and A. Antonetti, Phys. Rev. Lett. 58(15), 1559(1987).
J.P. Thornber, R.J. Cogdell, B.K. Pierson, and R.E.B. Seftor, J.Cellular Biochemistry 23, 159(1983).
R.M. Pearlstein, Photochem.Photobio1.35, 835(1982).
A. Yu Borisov, Energy - Migration Mechanisms in Antenna Chlorophylls in The Photosynthetic Bacteria, eds. R.K.Clayton, and W.R.Sistrom, N.Y., London 323(1978).
J.L. Martin, J. Breton, A.J. Hoff, A. Migus, and A. Antonetti, Proc. Natl. Acad. Sci. USA 83, 957(1986).
J. Breton, J.L. Martin, A. Migus, A. Antonetti, and A. Orzag, in Ultrafast Phenomena V, eds. G.R.Fleming, A.E.Siegman, (Springer-Verlag), Berlin 393(1986).
S.V. Chekalin, Y.A. Matveets, A.Y. Shkuropatov, V.A. Shuralov, and A. P. Yartsev, Febs. Lett. 216, 245(1987).
N.W.T. Woodbury, M. Becker, D. Middendorf, and W.W. Parson, Biochemistry 24, 7516(1985).
J. Breton, J.L. Martin, A. Migus, A. Antonetti, and A. Otszag, Proc. Natl. Acad. Sci. USA 83, 5121(1986).
J. Breton, J.L. Martin, J. Petrich, A. Migus, and A. Antonetti, FEBS Lett. 20, 37(1986).
W. Zinth, M. C. Nuss, M. A. Franz, W. Kaiser, and H. Michel, in Antennas and Reaction Centers of Photosynthetic Bacteria, ed. M. E. Michel-Beyerle (Springer-Verlag), Berlin, 286(1985).
W. Zinth, J. Dobler, and W. Kaiser in Ultrafast Phenomena V (Springer -Verlag) 379(1986).
S. R. Meech, A. J. Hoff, and D. A. Wiersma in Ultrafast Phenomena V (Springer-Verlag) 384(1986).
S.V. Chekalin, Yu.A. Matveets, and A.P. Yartsev, Rev. Phys. Appl. 22, 1761(1987).
J. Deisenhofer, O. Epp, K. Miki, R. Huber, and H. Michel, J. Mol. Biol. 180, 385(1984).
S.R. Meech, A.J. Hoff, and D.A. Wiersma, Chem. Phys. Lett. 121, 287(1985.
S.R. Meech, A.J. Hoff and D.A. Wiersma, Proc. Natl. Acad. Sci. USA 83(24) 9464(1986).
J.M. Fang, J.D. Carriker, V. Balogh-Nair, and K. Nakanishi, J. Am. Chem. Soc. 105, 5162(1983).
B. Aton, A.G. Doukas, R. H. Callender, B. Becher, and T.G. Ebrey, Biochemistry 16, 29(1977).
C.L. Hsieh, M.A. EI-Sayed, M. Nicol, M. Nagumo and J.H. Lee, Photochem. Photobiol.38, 83(1983).
M.S. Braiman and R.A. Mathies, Proc. Natl. Acad. Sci. USA 79, 403(1982).
S.O. Smith, J. Lugtenburg, and R.A. Mathies, J. Membrane Bio1.85, 95(1985).
S.O. Smith, I. Hornung, R. Van der Steen, M.S. Braiman, J. Lugtenburg, J.A. Pardoen, and R.A. Mathies, Proc. Natl. Acad. Sci. USA 83 967(1986).
K. Gerwert and F. Siebert, EMBO J.5, 805(1986).
H.J. Polland, M.A. Franz, W. Zinth, W. Kaier, E. Koelling and D. Oesterhelt, Biophys. J. 49, 651(1986).
R.A. Mathies, C.H. Brito Cruz, W.T. Polland, and C.V. Shank, Reports 777(1988).
J.W. Petrich, J. Breton, J.L. Martin, and A. Antonetti, Chem. Phys. Lett. 137(4), 369(1987).
J. Dobler, W. Zinth, W. Kaiser, and D. Oesterhelt, Chem. Phys. Lett. 144(2), 215(1988).
M.C. Nuss, W. Zinth, W. Kaiser, E. Koelling, and D. Oesterhelt, Chem. Phys. Lett. 117, 1(1985).
A.V. Sharkov, A.V. Pakulev, S.V. Chekalin, and Y.A. Matveets, Biochim. Biophys. Acta. 808, 94(1985).
R.H. Lozier, R.A. Bogomolni, and W. Stoeckenius, biophys. J. 15, 955(1975).
M.C. Kung, D. Devault, B. Hess, and D. Oesterhelt, Biophys. J. 15, 907(1975).
H.W. Trissl and W. Gartner, Biochemistry, to be published.
S. Ruhman, L.R. Williams, and K.A. Nelson, J. Phys. Chem.91, 2237 (1987).
S. Rhuman, B. Kohler, A.G. Joly and K.A. Nelson, Chem. Phys. Lett. 141, 16(1987).
P.A. Madden, and D. Tildesley, Mol. Phys. 49, 193 (1983) and P.A. Madden in ref. 1 (p 431–474).
S. Rhuman, A.G. Jolly and K.A. Nelson, J. Chem. Phys. 86, 6563 (1987).
M.J. Rosker, F.W. Wise and C.L. Tang, Phys. Rev. Lett. 57, 321(1986)
M.J. Rosker, F.W. Wise and C.L. Tang J. Chem. Phys. 86, 2827 (1987).
R. Leonhardt, W. Holzapfel, W. Zinth and W. Kaiser, Chem. Phys. Lett. 133, 373 (1987).
G.A. Kenney-Wallace in ref. 1, (p 139–162).
D. McMorrow, W.T. Lotshaw, and G.A. Kenney-Wallace, Chem. Phys. Lett. 145, 309 (1988).
C. Kalpouzos, D. McMorrow, W.T. Lotshaw and G.A. Kenney-Wallace, Chem. Phys. Lett. 150, 138 (1988)
C. Kalpouzos, D. McMorrow, W.T. Lotshaw and G.A. Kenney-Wallace ibid, J. Phys. Chem. 91, 2082 (1987).
W.T. Lotshaw, D. McMorrow, C. Kalpouzos, and G.A. Kenney-Wallace, Chem. Phys. Lett. 136, 323 (1987).
D.R. Demmer, J.W. Hager, G.W. Leach, and S.C. Wallace, Chem. Phys. Lett., 136, 329 (1987).
G.A. Bickel, D. R. Demmer, G.W. Leach, and S.C. Wallace, Chem. Phys. Lett. 145, 423 (1988).
P.M. Felker and A.H. Zewail, J. Chem. Phys. 82, 3003 (1985).
P.M. Felker and A.H. Zewail J. Chem. Phys. 82, 2994 (1985);
P.M. Felker and A.H. Zewail J. Chem. Phys. 82, 2961 (1985).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1989 Kluwer Academic Publishers
About this chapter
Cite this chapter
Carpenter, K., Kenney-Wallace, G. (1989). Femtosecond Laser Spectroscopy and Dynamics in Dense Media. In: DorfmĂĽller, T. (eds) Reactive and Flexible Molecules in Liquids. NATO ASI Series, vol 291. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1043-0_21
Download citation
DOI: https://doi.org/10.1007/978-94-009-1043-0_21
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6961-8
Online ISBN: 978-94-009-1043-0
eBook Packages: Springer Book Archive