Abstract
Spectral manifestations in isotropic Raman Spectra of fast pre-reactive, reactive and post-reactive motions in the liquid phase are examined theoretically. The kinetics of the reaction process is analysed in the frame of a one-dimensional Smoluchowski equation. The resulting correlation function exibits two chemical modes and two modes generated by the pre-reactive and post-reactive processes. The possibilities of Raman spectroscopy to detect these latter motions are critically evaluated.
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© 1989 Kluwer Academic Publishers
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Bratos, S., Viot, P. (1989). Isotropic Raman Study of Pre-reactive, Reactive and Post-reactive Processes in Liquids. In: Dorfmüller, T. (eds) Reactive and Flexible Molecules in Liquids. NATO ASI Series, vol 291. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1043-0_2
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DOI: https://doi.org/10.1007/978-94-009-1043-0_2
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6961-8
Online ISBN: 978-94-009-1043-0
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