Abstract
The surface chemistry of SiC and Si3N4 prepared by laser-driven gas-phase reactions has been characterized by transmission/absorption FT-IR spectroscopy. Different surface sites, such as surface silanols, silyl amino- and imido- groups, alkyl groups, silane bonds, surface carbonyls and siloxanes bridges have been evidenced. Their amounts depend on surface treatments: evacuation, oxidation, surface nitridation.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
W. R. Cannon, S. C. Danforth, J. H. Flint, J. S. Haggerty and R. A. Marra, “Sinterable Ceramic Powders from Laser-Driven Reactions: I, Process Description and Modeling”, J. Am. Ceram. Soc., 65 (7) 324–330 (1982)
M. Cauchetier, O. Croix, M. Luce, M. Michon, J. Paris and S. Tistchenko, “Laser Synthesis of Ultrafine Powders”, Ceram. Intern., 13 13–17 (1987)
M. Cauchetier, O. Croix and M. Luce, “Laser Synthesis of Silicon Carbide Powders from Silane-Hydrocarbon Mixtures”, J. Amer Ceram. Soc. in press
R. B. Levy, “Properties of Carbides, Nitrides and Borides: Implications for Catalysis” in Advanced Materials in Catalysis (J.J. Burton and R.L. Garten ed.), Academic Press, New York, 1977, p. 101.
A. Zecchina, E. Garrone and E. Guglielminotti, “Structural Characterization of Surface Species and Surface Sites by Conventional Optical Spectroscopies” in Catalysis Royal Society of Chemistry, London, Vol. 6, 1983, p. 90.
J. B. Peri, “Infrared Spectroscopy in Catalytic Research”, Catalysis Science and Technology, Vol. 5, 171–220, J. R. Anderson and M. Boudart eds., Springer-Verlag (1984)
J.P. Luongo, “Infrared Characterization of α- and β- Crystalline Silicon Nitride”, J. Electrochem. Soc. 130, 1560 (1983)
J. P. Luongo, “IR study of Amorphous Silicon Nitride”, Appl. Spectrosc. 38, 195 (1984)
W. W. Pultz and W. Hertl, “Perturbations in the Infrared Spectra of Submicroscopic Size, Single Crystal, Fibrous SiC”, Spectrochim. Acta, 22, 573 (1966)
G. Busca, V. Lorenzelli, G. Porcile, M. I. Baraton, P. Quintard and R. Marchand, “FT-IR Study of the Surface Properties of Silicon Nitride”, Mater. Chem. Phys., 14 123–140 (1986)
J. B. Peri, “Infrared Study of OH and NH2 Groups on the Surface of Dry Silica Aerogel”, J. Phys. Chem. 70, 2937 (1966)
S. Kondo, H. Yamagouchi, Y. Kajiyama and T. Ishikawa, J. Chem. Soc. Faraday Trans. I, 80, 2033 (1984
M. Sorlino, G. Busca, V. Lorenzelli, R. Marchand, M.I. Baraton and P. Quintard, “Propriétés de la Surface de l’Oxynitrure de Silicium Si2 ON2: Etude Preliminaire par Spectrométrie infrarouge par Transformée de Fourier”, Ann. Chim. Sci. Mater. 10, 105 (1985)
L. Patrick and W. J. Choyke, “Lattice Absorption Bands in SiC”, Phys. Rev., 123 813–815 (1961)
C. Morterra and M. J. D. Low, “Chemisorption of Molecular Hydrogen on Highly Dehydrated Silica”, Chem. Comm. 1491 (1968)
M.J.D. Low, “Reactive Silica. XVII: The nature of Reaction Center”, J. Catal. 103, 496 (1987)
L. Smith, “Infrared Group Frequencies for Structure Determination in Organosilicon Compounds”, in Chemical, Biological and Industrial Applications of Infrared Spectroscopy (J.R. Durig ed.), wiley, New York, 1985, p. 73.
FT Quintard, G. Ramis, M. Cauchetier, G. Busca and V. Lorenzelli, “FT-IR Characterization of Si-H Bands on the Surface of Silicon Carbide”, J. Mol. Struct., 174, 369 (1988)
H.J. Stein and H.A.R. Wegener, “Chemically Bound Hydrogen in CVD Si3N4: Dependence on NH3/SiH4. Ratio and on Annealing”, J. Electrochem. Soc. 124, 908 (1977)
M. H. Rahaman, Y. Boiteux and L. C. De Jonghe, “Surface Characterization of Silicon Nitride and Silicon Carbide Powders”, Am. Ceram. Soc. Bull., 65 1171–1176 (1986)
V. Lorenzelli, G. Ramis, G. Busca and P. Quintard, “Surface Structure and Stability of Advanced Engineering Ceramics: Fourier Transform Infrared Study of High-surface Silicon Nitride and Carbide Powders in Different Atmospheres”, Proc. 31st International Congress of Pure and Applied Chemistry, Invited Lectures Section 5, 40–52, Sofia, Bulgaria (1987)
H. M. Jennings, J.O. Edwards and M.H. Richman, “Molecular Structure, Microstructure, Macrostracture and Properties of Silicon Nitride”, Inorg. Chim. Acta 20, 167 (1976)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1989 Kluwer Academic Publishers
About this chapter
Cite this chapter
Ramis, G., Busca, G., Lorenzelli, V., Baraton, M.I., Merle-Mejean, T., Quintard, P. (1989). FT-IR Characterization of High Surface Area Silicon Nitride and Carbide. In: Dufour, LC., Monty, C., Petot-Ervas, G. (eds) Surfaces and Interfaces of Ceramic Materials. NATO ASI Series, vol 173. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1035-5_11
Download citation
DOI: https://doi.org/10.1007/978-94-009-1035-5_11
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6957-1
Online ISBN: 978-94-009-1035-5
eBook Packages: Springer Book Archive