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Cooperative Vibronic Effects: Electron Transfer in Solution and the Solid State

Part of the NATO ASI Series book series (ASIC, volume 288)

Abstract

Vibronic interactions are discussed for systems comprising more than a single metal ion surrounded by ligands. The cases of two sites and one transferable electron, and two sites and two electrons are considered in detail. The case of N sites and N electrons illustrates the distinction between spin density wave and charge density wave ground states. Brief mention is made of superconductivity as a vibronic phenomenon.

Keywords

Potential Energy Surface Charge Density Wave Mixed Valency Spin Density Wave Adiabatic Limit 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. Cannon, R. D. (1977) Electron Transfer Reactions, Butterworth (overview of facts and theories about solution reactions)Google Scholar
  2. Robin, M. B. and Day, P. (1967) Adv. l:norg. Chem. Radiochem. 10, 247 (static model of mixed valency and survey of Periodic Table)Google Scholar
  3. Allen, G. C. and Hush, N. S. (1967) Prog. Inorg. Chem. 8, 357 (mixed valency theory)CrossRefGoogle Scholar
  4. Brown, D. B. (1980) Mixed Valency Compounds, D. Reidel Publishing Co. (NATO ASI Proceedings, many aspects covered)Google Scholar
  5. Day, P. (1981) Int. Rev. Phys. Chem. 1, 149 (review of mixed valency including vibronic aspects)CrossRefGoogle Scholar
  6. Wong, K. Y. and Schatz, P. N. (1981) Prog. Inorg. Chem. 28, 369 (thorough review of the PKS vibronic model)CrossRefGoogle Scholar
  7. Prassides, K. and Day, P. (1984) J. Chem. Soc., Faraday Trans. 2, 80, 85 (PKS model for 2-site, 2-electron systems)Google Scholar
  8. Prassides, K., Schatz, P. N., Wong, K. Y. and Day, P. (1986) J. Phys. Chem. 90, 5588 (v_bronic coupling for 2-sites and 2-electrons)CrossRefGoogle Scholar
  9. Day, P. (1987) Ch. in ‘Organic and Inorganic Low-Dimensional Crystalline Materials’, ed. P. Delhaes & M. Drillon, Plenum, p.33 (N-site, N-electron chains with vibronic coupling)Google Scholar
  10. Nasu, K., (1985) J. Phys. Soc. Japan, 54, 1933 (electron-electron vs. electron-phonon coupling giving CDW, SDW and superconducting ground states in N-site, N-electron chains)CrossRefGoogle Scholar

Copyright information

© Kluwer Academic Publishers 1989

Authors and Affiliations

  • P. Day
    • 1
  1. 1.Institut Laue-Langevin 156XGrenobleFrance

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