Abstract
High concentrations of manganese were found in dew water on grass which are believed to be catalytically active in the oxidation of sulfite. In order to describe this oxidation the reaction was studied in a fog chamber. In the concentration and pH range, normally found in dew on grass, the formation of sulfate is linearly dependent on the concentration of manganese and on the square root of the concentration of sulfite. The results indicate that the manganese catalysed sulfite oxidation is an important reaction in dew on grass.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Arends, B.G., Mallant, R.K.A.M., van Wensveen, E., Gouman, J.M. (1988) ‘A fog chamber for the study of chemical reactions.’ Netherlands Energy Research Foundation, ECN-210.
Erickson, R.E., L.M. Yates, R.L. Clark, D. McEven (1977) ‘The reaction of sulfur dioxide with ozone in water and its possible atmospheric significance’. Atmos. Environ. 11, 813–817.
Gärtner, E. (1985) ‘Mangangehalte in Altfichten, Boden und Kronendurchlass an jeweils gleichen Standorten.’ VDI-Berichte 560, VDI Kommission Reinhaltung der Luft: Waldschaden, Einflussfaktoren und ihre Bewertung, 559–573.
Hoffmann, M.R., D.C. Jacob. (1984) ‘Kinetics and mechanisms of the catalytic oxidation of dissolved sulfur dioxide in aqueous solution: an application to nighttime fog water chemistry.’ In J.G.Calvert (ed.), SO2, NO and NO2 oxidation mechanisms: Atmospheric considerations. Butterworth Publishers, Boston, London.
Ibusuki, T., H.M. Barnes. (1984) ‘Manganese(II) catalysed sulfur dioxide oxidation in aqueous solution at environmental concentrations.’ Atmos. Environ. 18, 145–151.
Ibusuki, T., K. Takeuchi. (1987) ‘Sulfur dioxide oxidation by oxygen catalyzed by mixtures of manganese II and iron III in aqueous solutions at environmental reaction conditions.’ Atmos. Environ. 21, 1555–1560.
Martin, L.R. (1984) ‘Kinetic studies of sulfite oxidation in aqueous solution.’ In J.G. Calvert (ed.), SO2, NO and NO2 oxidation mechanisms: Atmospheric considerations. Butterworth Publishers, Boston, London.
Martin, L.R., M.W.Hill. (1987) ‘The effect of ionic strength on the manganese catalyzed oxidation of sulfur (IV).’ Atmos. Environ. 21, 2267–2270.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1989 Kluwer Academic Publishers
About this chapter
Cite this chapter
Arends, B.G., Eenkhoorn, S. (1989). The Influence of Manganese on the Oxidation of Sulfite in Dew Water. In: Georgii, HW. (eds) Mechanisms and Effects of Pollutant-Transfer into Forests. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1023-2_26
Download citation
DOI: https://doi.org/10.1007/978-94-009-1023-2_26
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6951-9
Online ISBN: 978-94-009-1023-2
eBook Packages: Springer Book Archive