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Phase Relations of Metal Oxides by Coulometric Titration

  • Chapter
Non-Stoichiometric Compounds

Part of the book series: NATO ASI Series ((ASIC,volume 276))

Abstract

The purpose of this paper is to summarize the results on the phase relations and nonstoichiometry in V2O5- x , BaBiO3-x and PrO x investigated by the present authors. The equilibrium oxygen partial pressures over the above oxides have been measured by coulometric titration using yttria-stabilized zirconia as a solid electrolyte. Nonstoichiometry in these oxides has been determined as a function of the oxygen partial pressure. The maximum oxygen deficiency in V2O5- x is 0.055 at 920K. The BaBiO3-x has three distinct phases in 0<x<0.5. The existence of the PrO1.667 is suggested in the PrO x . Detailed discussions have been made on the defect structures of the nonstoichiometric oxides based on the relation between the deviation from the stoichiometric composition and the oxygen partial pressure. The results prove that coulometric titration is one of the powerful tool to study the phase relation particularly in the oxides with the small deviation from the stoichiometric dcomposition.

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References

  1. K. Kiukkola and C. Wagner, J. Electrochem. Soc. 104 (1957) 379.

    Article  Google Scholar 

  2. R.A. Gidding and R.S. Gordon, J. Electrochem, Soc. 121 (1974) 793.

    Article  Google Scholar 

  3. I. Riess and D.S. Tannhauser, ‘Transport in Nonstoichiometric Compounds’, Elseviev Sci. Publ., Amsterdam, pp. 503–517 (1982).

    Google Scholar 

  4. R.A. Rapp and D.A. Shores, ‘Physicochemical Measurements in Metals Research ‘, Part 2, ed. by R.A. Rapp, Wiley-Interscience, New York, pp. 123–192 (1970).

    Google Scholar 

  5. T.L. Markin and R.J. Bones, Atomic Energy Research Establishment Report, AERE-4178 (1962).

    Google Scholar 

  6. K. Kiukkola, Acta Chem. Scand. 16 (1962) 327.

    Article  CAS  Google Scholar 

  7. A. Nakamura and T. Fujino, J. Nucl. Mater. 149 (1987) 80.

    Article  CAS  Google Scholar 

  8. Y.D. Tretyakov and R.A. Rapp, Trans. Met. Soc. AIME 242 (1969) 1235.

    Google Scholar 

  9. H.G. Sockel and H. Schmalzried, Ber. Bunsenges. Phys. Chem. 72 (1968) 745.

    CAS  Google Scholar 

  10. F.E. Rizzo and J.V. Smith, J. Phys. Chem. 72 (1968) 485.

    Article  CAS  Google Scholar 

  11. H.F. Rizzo, R.S. Gordon and J.B. Cutler, J. Electrochem. Soc. 116 (1969) 267.

    Article  Google Scholar 

  12. B.E.F. Fender and F.D. Riley, J. Phys. Chem. Solids 30 (1969) 793.

    Article  CAS  Google Scholar 

  13. A.D. Wadsley, Acta Cryst. 10 (1957) 261.

    Article  CAS  Google Scholar 

  14. F. Aebi, Helv. Chim. Acta 31 (1948) 8.

    Article  CAS  Google Scholar 

  15. G. Anderson, Acta Chem. Scand. 8 (1954) 1559.

    Article  Google Scholar 

  16. F. Theobald, R. Cabala and J. Bernard, Compt. Rend. C266 (1968) 1534.

    Google Scholar 

  17. K. Wilhemi, K. Waltersson and L. Kihelborg, Acta Chem. Scand. 25 (1971) 2675.

    Article  Google Scholar 

  18. T. Tudo and G. Tridot, Compt. Rend. C261 (1965) 2911.

    Google Scholar 

  19. G. Tridot and J. Tudo, Compt. Rend. C263 (1966) 421.

    Google Scholar 

  20. K. Waltersson, B. Forslund and K. Wilhelmi, Acta Cryst. B30 (1974) 2644.

    CAS  Google Scholar 

  21. k. kosuge, J. Phys. Chem, Solids 28 (1967) 1613.

    Article  CAS  Google Scholar 

  22. S. Kachi, K. Kosuge, M. Shiotani and N. Nakanishi, Shokubai [Catalysis] 10 (1968) 103.

    Google Scholar 

  23. M. Taniguchi, A. Miyazaki and H. Yokomizo, Shokubai 10 (1968) 99.

    Google Scholar 

  24. M. Taniguchi, S. Kato and T. Nanao, Shokubai 14 (1972) 53.

    Google Scholar 

  25. M. Taniguchi, in Proc. 4th Intern. Conf. Thermal Analysis, Vol. 1 (1974) 727.

    Google Scholar 

  26. F. Theobald, R. Cabala and J. Bernard Compt. Rend. C269 (1969) 1209.

    Google Scholar 

  27. K. Wilhelmi and K. Waltersson, Acta Chem, Scand. 24 (1970) 3409.

    Article  CAS  Google Scholar 

  28. T. Sata, E. Komada and Y. Ito, Kogyo Kagaku Zasshi 71 (1968) 643.

    CAS  Google Scholar 

  29. T. Sata and Y. Ito, Kogyo Kagaku Zasshi 71 (1968) 647.

    CAS  Google Scholar 

  30. T. Sata and Y. Ito, Bull. Tokyo Inst. Technol. 98 (1970) 1.

    Google Scholar 

  31. K. Iwase and N. Nasu, Sci. Rept. Tohoku Imp, Univ., Honda Aniversary (1936) 476.

    Google Scholar 

  32. H. Flood and J. Kleppa, J. Am. Chem. Soc. 69 (1947) 998.

    Article  CAS  Google Scholar 

  33. A.A. Fotiev and V.L. Volkov, Zh. Fiz. Khim. 45 (1971) 2610.

    Google Scholar 

  34. H. Endo, M. Wakihara and M. Taniguchi, Chem. Letters (Chem. Soc. Japan) (1974) 905.

    Google Scholar 

  35. R. Dziembaj and J. Piwowarczyk, J. Solid State Chem. 21 (1977) 387.

    Article  CAS  Google Scholar 

  36. D.E. Cox, J.L. Gillson and P.E. Bierstedt, Solid State Commun. 17 (1975) 27.

    Article  Google Scholar 

  37. M. Suzuki and T. Murakami, Solid State Commun. 53 (1985) 691.

    Article  CAS  Google Scholar 

  38. D.E. Cox and A.W. Sleight, Acta Crystallogr. B35 (1979) 1.

    CAS  Google Scholar 

  39. C. Chaillout and J.P. Remeika, Solid State Commun. 56 (1985) 833.

    Article  CAS  Google Scholar 

  40. R.A. Beyerlein, A.J. Jacobson and L.N. Yacullo, Mat. Res. Bull. 20 (1985) 877.

    Article  CAS  Google Scholar 

  41. Y. Saito, T. Maruyama and A. Yamanaka, Thermochim. Acta 115 (1987) 199.

    Article  CAS  Google Scholar 

  42. J.D. McCullough, J. Am. Chem. Soc. 72 (1950) 1386.

    Article  CAS  Google Scholar 

  43. R.E. Ferguson, E.D. Guth and L. Eyring, J. Am. Chem. Soc. 76 (1954) 3890.

    Article  CAS  Google Scholar 

  44. E.D. Guth, J.R. Holden, N.C. Baenziger and L. Eyring, J. Am. Chem. Soc. 76 (1954) 5239.

    Article  CAS  Google Scholar 

  45. E.D. Guth and L. Eyring, J. Am. Chem. Soc. 76 (1954) 5245.

    Google Scholar 

  46. C.T. Stubblefield, H. Eick and L. Eyring, J. Am. Chem. Soc. 78 (1956) 3018.

    Article  CAS  Google Scholar 

  47. B.G. Hyde, D.J.M. Bevan and L. Eyring, Phil. Trans. Roy. Soc. London 259A (1966) 583.

    Article  Google Scholar 

  48. J. Kordis and L. Eyring, J. Phys. Chem. 72 (1968) 2030.

    Article  CAS  Google Scholar 

  49. J. Kordis and L. Eyring, J, Phys. Chem. 72 (1968) 2044.

    Article  CAS  Google Scholar 

  50. D.A. Burnham and L. Eyring, J. Phys. Chem. 72 (1968) 4415.

    Article  CAS  Google Scholar 

  51. R.P. Turcott, J.M. Warmkessel, R.J.D. Tilley and L. Eyring, J. Solid State Chem. 3 (1971) 265.

    Article  Google Scholar 

  52. R.P. Turcott, M.S. Jenkins and L. Eyring, J. Solid State Chem. 7 (1973) 454.

    Article  Google Scholar 

  53. A.T. Lowe, K.H. Lau and L. Eyring, J. Solid State Chem. 15 (1975) 9.

    Article  CAS  Google Scholar 

  54. E. Summerville, R.T. Tunge and L. Eyring, J. Solid State Chem. 24 (1978) 21.

    Article  CAS  Google Scholar 

  55. R.T. Tunge and L. Eyring, J. Solid State Chem. 29 (1979) 165.

    Article  Google Scholar 

  56. Y. Ito, T. Maruyama and Y. Saito, Solid State Ionics 25 (1987), 199.

    Article  CAS  Google Scholar 

  57. T. Maruyama, A. Yamanaka and Y. Saito, Unpublished

    Google Scholar 

  58. Y. Watanabe, T. Maruyama and Y. Saito, Unpublished

    Google Scholar 

  59. E. Gills and E. Boesman, Phys. Status Solidi 14 (1966), 337.

    Article  Google Scholar 

  60. K. Endo, S. Yamauchi, K. Fueki and T. Mukaibo, Bull. Chem. Soc. Japan 49 (1976) 2379.

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Research Laboratory of Engineering Materials, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, 227, Japan

    Y. Saito

  2. Department of Metallurgical Engineering, Tokyo Institute of Technology, 1-12-1 O-okayama, Meguro-ku, Tokyo, 152, Japan

    T. Maruyama

Authors
  1. Y. Saito
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  2. T. Maruyama
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Editor information

Editors and Affiliations

  1. Max-Planck-Institut für Festkörperforschung, Stuttgart 80, Germany

    J. Nowotny  & W. Weppner  & 

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© 1989 Kluwer Academic Publishers

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Saito, Y., Maruyama, T. (1989). Phase Relations of Metal Oxides by Coulometric Titration. In: Nowotny, J., Weppner, W. (eds) Non-Stoichiometric Compounds. NATO ASI Series, vol 276. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0943-4_2

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  • DOI: https://doi.org/10.1007/978-94-009-0943-4_2

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6914-4

  • Online ISBN: 978-94-009-0943-4

  • eBook Packages: Springer Book Archive

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