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Interface Transport in Monoxides

  • M. Déchamps
  • F. Barbier
Part of the NATO ASI Series book series (ASIC, volume 276)

Abstract

Recent experimental data concerning bulk and grain boundary diffusion in MgO and NiO have been collected together. An attempt has been made to summarize the cross interpretation of the authors of the different works. There is a large spreading of the results which might be due to uncontrolled grain boundary chemistry and/or to artifacts. The most recent data indicate, for MgO, an enhanced cation and oxygen boundary diffusion, independent of dopes, with αD′ δ/D ≈ 10−3 for chromium and oxygen diffusion. In the case of NiO, quantitative results obtained on oxide scales indicate an important enhanced cation diffusion (αD′ δ/D ≈ 10−2). It was not possible to confirm these results on bicrystals, where αD′ δ/D was found to be less than 10−4. In our opinion, these controversial results are due to oxide scale artifacts.

Keywords

Oxide Scale Boundary Diffusion Oxygen Diffusion Lattice Diffusion Bulk Diffusion 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Kluwer Academic Publishers 1989

Authors and Affiliations

  • M. Déchamps
    • 1
  • F. Barbier
    • 1
  1. 1.Laboratoire de Chimie des Solides, UA CNRS 446Université Paris-SudOrsay CedexFrance

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