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Strain Release in Aromatic Molecules: The [2n] Cyclophanes

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Strain and Its Implications in Organic Chemistry

Part of the book series: NATO ASI Series ((ASIC,volume 273))

Abstract

The chemical behavior of the [2n] cyclophanes is determined to a large extent by strain effects.This is shown by a systematic study of isomerisation and addition reactions, respectively. In particular, the paper describes thermal, photochemical and ionic isomerisations of various [2n] cyclophanes, as well as their behavior in Diels-Alder additions, epoxidations and carbene addition reactions.

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Authors and Affiliations

  1. Institute of Organic Chemistry, University of Braunschweig, Hagenring 30, D-3300, Braunschweig, Federal Republic of Germany

    Henning Hopf & Claudia Marquard

Authors
  1. Henning Hopf
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  2. Claudia Marquard
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Editors and Affiliations

  1. Institut für Organische Chemie, Universität Hamburg, Hamburg, Germany

    Armin de Meijere

  2. Institut für Organische Chemie, Universität Bonn, Bonn, Germany

    Siegfried Blechert

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© 1989 Kluwer Academic Publishers

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Hopf, H., Marquard, C. (1989). Strain Release in Aromatic Molecules: The [2n] Cyclophanes. In: de Meijere, A., Blechert, S. (eds) Strain and Its Implications in Organic Chemistry. NATO ASI Series, vol 273. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0929-8_21

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  • DOI: https://doi.org/10.1007/978-94-009-0929-8_21

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6907-6

  • Online ISBN: 978-94-009-0929-8

  • eBook Packages: Springer Book Archive

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