Abstract
Due to the presence of interatomic interactions, any alloy should eventually order or segregate at low temperature. This is observed in many systems. When the ordering interactions are strong, the alloy may remain ordered up to the melting point (Ni3Al for instance). When they are very weak, the solid solution may be the only observable phase since at low temperature atomic diffusion is no longer efficient (Cu-Ni). In the intermediate regime we have the most interesting situation for our present purpose, i.e. the occurrence of one or several ordered phases at low temperature which disorder at a critical temperature before melting (Cu-Au, Pd-V, Ni-Fe,…). In the simplest situation all phases have a single simple underlying lattice (fcc, bcc,…), but more frequently several structures are involved and some compounds display structures different from those of the pure metals (Laves phases, σ phases, A15 phases,…).
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Ducastelle, F. (1989). Electronic Structure, Effective Pair Interactions and Order in Alloys. In: Stocks, G.M., Gonis, A. (eds) Alloy Phase Stability. NATO ASI Series, vol 163. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0915-1_22
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DOI: https://doi.org/10.1007/978-94-009-0915-1_22
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