Abstract
The role of activation/termination sequences on the efficiency of electron transfer chain catalysis is discussed and illustrated by two examples related to transition metal catalysis of organic reactions.
Keywords
- Oxidative Coupling
- Nickel Complex
- Nickel Concentration
- Termination Step
- Aromatic Nucleophilic Substitution
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References
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The proximity of a negative charge, should enhance the lability of the α CH bond as observed e.g. for alcoolates: C. Amatore, J. Badoz-Lambling, C. Bonnel-Huyghes, J. Pinson, J.M. Savéant and A. Thiébault, J. Am. Chem. Soc., 104, 1982, 1979.
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Compare with ref.15.
This phenomenon is similar to “Redox Catalysis” in terms of kinetic behavior. Compare: (a) R.S. Nicholson and I. Shain, Anal. Chem., 36, 1964, 706
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All three effects are observed by Colon and Kelsey. Compare figs. 1–4 in ref.14.
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© 1989 Kluwer Academic Publishers
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Amatore, C., Jutand, A., Verpeaux, J.N. (1989). Role of Termination Steps on the Efficiency of Electron Transfer Chain Catalysis. In: Chanon, M., Julliard, M., Poite, J.C. (eds) Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis. NATO ASI Series, vol 257. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0877-2_15
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DOI: https://doi.org/10.1007/978-94-009-0877-2_15
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