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The Molecular Mechanism of Adhesion Improvement of 3-Aminopropyltriethoxysilane in Glass Reinforced Nylon Modelcomposites

  • L. W. Jenneskens
  • H. Angad Gaur
  • A. Venema
  • H. E. C. Schuurs
  • W. G. B. Huysmans
  • T. P. Huijgen
  • T. L. Weeding
  • W. S. Veeman

Abstract

Selectively 13C-enriched 3-(3-13C)aminopropyltriethoxysilane ((3-13C)-APS) is used to investigate silane-polymer reactions and/or interactions in glassbead reinforced Nylon (PA-6) modelcomposites. With 13C MAS NMR and Pyrolysis GC/MS evidence is obtained for amide formation between -C00H PA-6 endgroups and -NH2 groups of APS and interpenetration of PA-6 chains into the poly-APS network.

Keywords

Glass Bead Silane Coupling Agent Interpenetrate Polymer Network Inorganic Filler Adhesion Mechanism 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Elsevier Science Publishers Ltd 1990

Authors and Affiliations

  • L. W. Jenneskens
    • 1
  • H. Angad Gaur
    • 1
  • A. Venema
    • 1
  • H. E. C. Schuurs
    • 1
  • W. G. B. Huysmans
    • 1
  • T. P. Huijgen
    • 2
  • T. L. Weeding
    • 2
  • W. S. Veeman
    • 2
  1. 1.Akzo Research Laboratories ArnhemCorporate ResearchArnhemThe Netherlands
  2. 2.Department of Molecular SpectroscopyUniversity of NijmegenNijmegenThe Netherlands

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