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The Molecular Mechanism of Adhesion Improvement of 3-Aminopropyltriethoxysilane in Glass Reinforced Nylon Modelcomposites

  • L. W. Jenneskens
  • H. Angad Gaur
  • A. Venema
  • H. E. C. Schuurs
  • W. G. B. Huysmans
  • T. P. Huijgen
  • T. L. Weeding
  • W. S. Veeman
Chapter

Abstract

Selectively 13C-enriched 3-(3-13C)aminopropyltriethoxysilane ((3-13C)-APS) is used to investigate silane-polymer reactions and/or interactions in glassbead reinforced Nylon (PA-6) modelcomposites. With 13C MAS NMR and Pyrolysis GC/MS evidence is obtained for amide formation between -C00H PA-6 endgroups and -NH2 groups of APS and interpenetration of PA-6 chains into the poly-APS network.

Keywords

Glass Bead Silane Coupling Agent Interpenetrate Polymer Network Inorganic Filler Adhesion Mechanism 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References

  1. 1.
    Plueddemann, E.P., Silane Coupling Agents, Plenum Press, New York, 1982.Google Scholar
  2. 2.
    Plueddemann, E.P., Interfaces in Polymer, Ceramic and Metal Matrix Composites, ed. Ishida, H., Elsevier Science Publishing Co., Inc., 1988, pp. 17-33.Google Scholar
  3. 3.
    Ishida, H. and Suzuki, Y., Composite Interfaces, eds. Ishida, H. and Koenig, J.L., Elsevier Science Publishing Co., Inc., 1986, pp. 317-27.Google Scholar
  4. 4.
    Weeding, T.L., Veeman, W.S., Jenneskens, L.W., Angad Gaur, H., Schuurs, H.E.C. and Huysmans, W.G.B., Macromolecules, 1989, 22, 706–14.CrossRefGoogle Scholar
  5. 5.
    Rosen, M.J., J. Coatings Technol., 1978, 50, 70–82.Google Scholar
  6. 6.
    Plueddemann, E.P. and Stark, G.C., SPI 35th Ann. Tech. Conf. Reinf. Plasty, 1980, 20-B, 264–69.Google Scholar
  7. 7.
    Jenneskens, L.W., Van den Berg, E.M.M., Heemskerk, B. and Lugtenburg, J., Recl. Trav. Chim. Pays Bas, 1988, 107, 627–30.CrossRefGoogle Scholar
  8. 8.
    Huijgen, T.P., Angad Gaur, H., Weeding, T.L., Jenneskens, L.W., Schuurs H.E.C., Veeman, W.S. and Huysmans, W.G.B., manuscript in preparation.Google Scholar
  9. 9.
    Fischer, M. and Djerassi, C., Chem. Ber., 1966, 99, 1541–57.CrossRefGoogle Scholar
  10. 10.
    Jenneskens, L.W. and Venema, A., to be published.Google Scholar

Copyright information

© Elsevier Science Publishers Ltd 1990

Authors and Affiliations

  • L. W. Jenneskens
    • 1
  • H. Angad Gaur
    • 1
  • A. Venema
    • 1
  • H. E. C. Schuurs
    • 1
  • W. G. B. Huysmans
    • 1
  • T. P. Huijgen
    • 2
  • T. L. Weeding
    • 2
  • W. S. Veeman
    • 2
  1. 1.Akzo Research Laboratories ArnhemCorporate ResearchArnhemThe Netherlands
  2. 2.Department of Molecular SpectroscopyUniversity of NijmegenNijmegenThe Netherlands

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