Abstract
Measurements of reactive nitrogen species in Antarctica are briefly reviewed and their links to ozone depletion are summarized. Observations of NO, NO2, HNO3, particulate nitrate, and total NOy demonstrate that the composition of the Antarctic stratosphere is greatly perturbed by the presence of clouds. Further, measurements have shown that the clouds themselves are composed in part of HNO3, and that sedimentation of cloud particles apparently can remove reactive nitrogen from the gas phase altogether. These processes reduce the abundance of stratospheric NO2, a primary requirement for elevated ClO densities and attendant ozone loss.
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Anderson, J. G., W. H. Brune, S. A. Lloyd, W. L. Starr, M. Loewenstein and J. R. Podolske, Kinetics of ozone destruction by ClO and BrO within the Antarctic vortex: an analysis based on in-situ ER-2 data, J. Geophys. Res., AAOE special issue, 1989.
Arnold, F., and G. Knop, Stratospheric nitric acid vapour measurements in the cold arctic vortex-implications for nitric acid condensation, Nature, 338, 746, 1989.
Austin, J., E. E. Remsberg, R. L. Jones, and A. F. Tuck, Polar stratospheric clouds inferred from satellite data, Geophys. Res. Lett., 13, 1256, 1986a.
Austin, J., R. R. Garcia, J. M. Russell, S. Solomon and A. F. Tuck, On the atmospheric photochemistry of nitric acid, J. Geophys. Res., 91, 5477–5485, 1986b.
Barrett, J. W., P. M. Solomon, R. L. DeZafra, M. Jaramillo, L. Emmons, and A. Parrish, Formation of the antarctic ozone hole by the GlO dimer mechanism, Nature, 336, 455, 1988.
Callis, L. B., and M. Natarajan The antarctic ozone minimum: relationship to odd nitrogen, odd chlorine, the final warming, and the 11-year solar cycle, J. Geophys. Res., 91, 10771, 1986.
Coffey, M. T., and W. G. Mankin, Airborne measurements of stratospheric constituents over Antarctica in the austral spring 1987, 2, Halogen and nitrogen trace gases, J. Geophys. Res., AAOE special issue, 1989.
Crutzen, P. J., The influence of nitrogen oxide on the atmospheric ozone content, Q. J. R. Meteorol. Soc., 96, 320, 1970.
Crutzen, P. J., and F. Arnold, Nitric acid cloud formation in the cold antarctic stratosphere: a major cause for the springtime “ozone hole”, Nature, 324, 651–655, 1986.
Elokhov, A. S., and A. N. Gruzdev, Total ozone and NO2 observations at Molodeznaja and Mirny stations, Antarctica, in spring 1987 and in summer and fall, 1988, Middle Atmosphere Symposium, Dushanbe, USSR, 1989.
Fahey, D. W., D. M. Murphy, C. S. Eubank, K. K. Kelly, M. H. Proffit, G. V. Ferry, M. K. W. Ko, M. Loewenstein, and K. R. Chan, Measurements of nitric oxide and total reactive nitrogen in the Antarctic stratosphere: observations and chemical implications, J. Geophys. Res., AAOE special issue, 1989a.
Fahey, D.W., Kelly K.K., Ferry G.V., Poole L.R., Wilson J.C., Murphy D.M. and Chan K.R., In situ measurements of total reactive nitrogen, total water and aerosols in Polar Stratospheric Clouds in the Antarctic Stratosphere, J. Geophys. Res, AAOE special issue, 1989b.
Farman, J. C., B. G. Gardiner, and J. D. Shanklin, Large losses of total ozone in Antarctica reveal seasonal ClOx/NOx interaction, Nature, 315, 207, 1985.
Farmer, C. B., G. C. Toon, P. W. Shaper, J. F. Blavier, and L. L. Lowes, Ground-based measurements of the composition of the antarctic atmosphere during the 1986 spring season, I. Stratospheric trace gases, Nature, 329, 126, 1987.
Gandrud, B. W., P. D. Sperry, L. Sanford, K. K. Kelly, G. V. Ferry and K. R. Chan, Filter measurement results from the Airborne Antarctic Ozone Experiment, J. Geophys. Res., AAOE special issue, 1989.
Hamill, P., R. P. Turco, and O. B. Toon, On the growth of nitric and sulfuric acid aerosol particles under stratospheric conditions. J. Atmos. Chem., 7, 287–315, 1988.
Hanson, D. R. and K. Mauersberger, Laboratory studies of the nitric acid trihydrate: Implications for the South Polar stratosphere, Geophys. Res. Lett., 15, 855–858, 1988a.
Hanson, D. R. and K. Mauersberger, Vapor Pressures of HN03/H2O solutions at low temperatures, J. Phys. Chem., 92, 6167–6170, 1988b.
Hofmann, D. J., Direct ozone depletion in springtime Antarctic lower stratospheric clouds., Nature, 337, 447, 1989a.
Hofmann, D. J., Comparison of stratospheric clouds in the Antarctic and in the Arctic, submitted to Geophys. Res. Lett., 1989b.
Johnston, H. S., Reduction of stratospheric ozone by nitrogen oxide catalysts from supersonic transport exhaust, Science, 173, 517, 1971.
Jones, R. L., J. Austin, D. S. McKenna, J. G. Anderson, D. W. Fahey, C. B. Farmer, L. E. Heidt, K. K. Kelly, D. M. Murphy, M. H. Proffit and A. F. Tuck, Lagrangian photochemical modelling studies of the 1987 Antarctic spring vortex: comparison with observations, J. Geophys. Res., AAOE special issue, 1989.
Karcher, F., M. Amodei, G. Armand, C. Besson, B. DuFour, G. Froment, and J. P. Meyer, Simultaneous measurements of HNO3, NO2, HCl, O3, N2O, CH4, H2O and CO, and their latitudinal variations as deduced from airborne infrared spectrometry, Ann. Geophysicae, 4, 425, 1988.
Kelly, K. K., A. F. Tuck, D. M. Murphy, M. H. Proffitt, D. W. Fahey, R. L. Jones, D. S. McKenna, M. Loewenstein, J. R. Podolske, S. E. Strahan, G. V. Ferry, K. R. Chan, J. F. Vedder, G. L. Gregory, W. D. Hypes, M. P. McCormick, E. V. Browell, and L. E. Heidt, Dehydration in the lower Antarctic stratosphere during late winter and early spring, 1987, J. Geophys. Res., AAOE special issue, 1989.
Keys, J. G., and P. V. Johnston, Stratospheric NO2 and O3 in Antarctica: dynamic and chemically controlled variations, Geophys. Res. Lett., 13, 1260, 1986.
Keys, J. G., and P. V. Johnston, Stratospheric NO2 column measurements from three Antarctic sites, Geophys. Res. Lett., 15, 898, 1988.
Mahlman, J. D., and S. B. Fels, Antarctic ozone decreases: a dynamical cause, Geophys. Res. Lett., 13, 1316, 1986.
McElroy, M. B., R. J. Salawitch, S. C. Wofsy and J. A. Logan, Antarctic ozone: reductions due to synergistic interactions of chlorine and bromine, Nature, 321, 759, 1986a.
McElroy, M. B., R. J. Salawitch, and S. C. Wofsy, Antarctic O3: chemical mechanisms for the spring decrease, Geophys. Res. Lett., 13, 1296, 1986b.
McKenzie, R. L., and P. V. Johnston, Springtime stratospheric NO2 in Antarctica, Geophys. Res. Lett., 11, 73, 1984.
Molina, L. T. and M. J. Molina, Production of Cl2O2 from the self-reaction of the ClO radical, J. Phys. Chem. 91, 433–436, 1987.
Molina, M. J., T.L. Tso, L. T. Molina, and F. C.Y. Wang, Antarctic stratospheric chemistry of chlorine nitrate, hydrogen chloride, and ice: Release of active chlorine, Science, 238, 1253–1257, 1987.
Mount, G. H., R. W. Sanders, A. L. Schmeltekopf, and S. Solomon, Visible spectroscopy at McMurdo Station, Antarctica, 1. Overview and daily variations of NO2 and O3 during austral spring, 1986, J. Geophys. Res., 92, 8320, 1987.
Noxon, J. F., Stratospheric NO2 in the Antarctic winter, Geophys. Res., Lett., 5, 1021, 1978.
Noxon, J. F., Stratospheric NO2: 2, Global behavior, J. Geophys. Res., 84, 5067, 1979.
Ozone Trends Panel (R.T. Watson, M.J. Prather and M.J. Kurylo et al.), Present state of knowledge of the upper atmosphere 1988: an assessment report. NASA reference publ. 1208, available from the National Technical Information Service, Springfield, VA 22161, USA, 1989.
Poole, L. R., Airborne lidar studies of Arctic polar stratospheric clouds, Ph.D. dissertation, University of Arizona, 1987.
Poole, L. R., and M. P. McCormick, Polar stratospheric clouds and the Antarctic ozone hole, J. Geophys. Res., 93, 8423–8430, 1988.
Poole, L. R., M. T. Osbom, and W. H. Hunt, Lidar observations of Arctic polar stratospheric clouds: Signature of small, solid particles above the frost point, Geophys. Res. Lett., 15, 867–870 1988a
Poole, L. R., M. P. McCormick, E. V. Browell, C. T. Trepte, D. W. Fahey, K. K. Kelly, G. V. Ferry, R. Pueschel, and R. L. Jones, Extinction and backscatter measurements of Antarctic PSCs, 1987: Implications for particle and vapor removal, NASA CP-10014, 77–79, 1988b.
Pueschel, R. F., K. G. Snetsinger, J. K. Goodman, O. B. Toon, G. V. Ferry, V. R. Oberbeck, J. M. Livingston, S. Verma, W. Fong, W. L. Starr and K. R. Chan, Condensed nitrate, sulfate and chloride in Antarctic stratospheric aerosols, J. Geophys. Res., In press, AAOE special issue, 1989.
Ramaswamy, V., Dehydration mechanism in the Antarctic stratosphere during winter. Geophys. Res. Lett., 15, 863, 1988.
Rosen, J. M., D. J. Hofmann, and J. W. Harder, Aerosol measurements in the winter/spring Antarctic stratosphere, 2, Impact on polar stratospheric cloud theories, J. Geophys. Res., 93, 677–686, 1988.
Salawitch, R. J., G. P. Gobbi, S. C. Wofsy and M. B. McElroy, Dentrification in the Antarctic stratosphere, Nature, 339, 525, 1989.
Solomon, S., R. R. Garcia, F. S. Rowland, and D. J. Wuebbles, On the depletion of antarctic ozone, Nature, 321, 755, 1986.
Solomon, S., The mystery of the Antarctic ozone hole, Rev. Geophys., 26, 131, 1988.
Solomon, S., R. W. Sanders, M. A. Carroll, and A. L. Schmeltekopf, Visible and near-ultraviolet spectroscopy at McMurdo Station, Antarctica, 5. Observations of the diurnal variations of OClO and BrO, J. Geophys. Res., AAOE special issue, 1989.
Thomas, R. J., K. H. Rosenlof, R. T. Clancy, and J. M. Zawodny, Stratospheric NO2 over Antarctica as measured by the solar mesosphere explorer during austral spring, 1986, J. Geophys. Res., 93, 12561, 1988.
Tolbert, M. A., M. J. Rossi, R. Malhotra, and D. M. Golden, Reaction of chlorine nitrate with hydrogen chloride and water at Antarctic stratospheric temperatures, Science, 238, 1258, 1987.
Toon, G.C., C.B. Farmer, L.L. Lowes, P.W. Schaper, J.-F. Blavier and R.H. Norton, Infrared measurements of stratospheric composition over Antarctica during September 1987, J. Geophys. Res., AAOE special issue, 1989.
Toon, O. B., P. Hamill, R. P. Turco, and J. Pinto, Condensation of HNO3 and HCl in the winter polar stratosphere, Geophys. Res. Lett., 13, 1284, 1986.
Toon, O. B., R. P. Turco, J. Jordan, J. Goodman, and G. Ferry, Physical processes in polar stratospheric ice clouds, J. Geophys. Res., AAOE special issue, 1989.
Tung, K. K., M. K. W. Ko, J. M. Rodriguez and N. D. Sze, Are antarctic ozone variations a manifestation of dynamics or chemistry?, Nature, 333, 811, 1986.
Wanner, A., R. O. Jakoubek, G. H. Mount, A. R. Ravishankara and A. L. Schmeltekopf, Remote sensing of daytime column NO2 during the airborne Antarctic ozone experiment, J. Geophys. Res., AAOE special issue, 1989.
Williams, W. J., J. J. Kosters, and D. G. Murcray, Nitric acid column densities over Antarctica, J. Geophys. Res., 87, 8976, 1982.
Wofsy, S. C., Temporal and latitudinal variations of stratospheric trace gases: a critical comparison between theory and experiment, J. Geophys. Res., 83, 364, 1978.
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Solomon, S. (1990). Nitrogen Chemistry in Antarctica: A Brief Review. In: O’Neill, A. (eds) Dynamics, Transport and Photochemistry in the Middle Atmosphere of the Southern Hemisphere. NATO ASI Series, vol 321. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0693-8_13
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DOI: https://doi.org/10.1007/978-94-009-0693-8_13
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