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Catalytic Incorporation of CO2 for the Synthesis of Organic Compounds

  • Pierre H. Dixneuf
  • Christian Bruneau
  • Jean Fournier
Part of the NATO ASI Series book series (ASIC, volume 314)

Abstract

The direct incorporation of CO2 into alkynes in the presence of nucleophiles has been investigated. Vinylcarbamates and dienylcarbamates can be regioselectively produced in one-step from terminal alkynes or isopropenylacetylene, CO2 and secondary amines with ruthenium catalysts. Reactions of propargyl alcohol derivatives and CO2 can lead selectively to β-oxopropylcarbamates, with ruthenium catalysts, and to α-methylene cyclic carbonates or functional α-methylene oxazolidinones with phosphines catalysts.

Keywords

Cyclic Carbonate Secondary Amine Terminal Alkyne Ruthenium Catalyst Propargyl Alcohol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Kluwer Academic Publishers 1990

Authors and Affiliations

  • Pierre H. Dixneuf
    • 1
  • Christian Bruneau
    • 1
  • Jean Fournier
    • 1
  1. 1.Unité de recherche CNRS DO415, Campus de BeaulieuUniversité de RennesRennesFrance

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