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Arrhenius Parameters for the Gas-Phase Reaction of Ozone with a Series of 1-Alkenes over the Temperature Range 240–324k

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Physico-Chemical Behaviour of Atmospheric Pollutants

Summary

Rate constants for the gas-phase reaction of ozone with ethene, propene, 1-butene, 1-pentene and 1-hexene have been determined at 298 ± 1K and 1 atm total pressure using two different experimental procedures. The rate constants obtained were (in units of 10-18 cm3 molecule-1 s-1): ethene, 1.37 ± 0.04; propene 9.71 ± 0.43; 1-butene, 9.57 ± 0.52; 1-pentene, 9.20±0.53; 1-hexene, 10.2 ±0.4.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Dublin Institute of Technology, Dublin, Ireland

    M. Donlon, D. J. O’Farrell & J. J. Treacy

  2. Department of Chemistry, University College Dublin, Dublin, Ireland

    H. W. Sidebottom

Authors
  1. M. Donlon
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  2. D. J. O’Farrell
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  3. J. J. Treacy
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  4. H. W. Sidebottom
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Editor information

Editors and Affiliations

  1. Joint Research Centre, Environment Institute, Ispra, Italy

    G. Restelli

  2. Commission of the European Communities, Directorate-General Science, Research and Development, Italy

    G. Angeletti

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© 1990 ECSC, EEC, EAEC, Brussels and Luxemberg

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Donlon, M., O’Farrell, D.J., Treacy, J.J., Sidebottom, H.W. (1990). Arrhenius Parameters for the Gas-Phase Reaction of Ozone with a Series of 1-Alkenes over the Temperature Range 240–324k. In: Restelli, G., Angeletti, G. (eds) Physico-Chemical Behaviour of Atmospheric Pollutants. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0567-2_55

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  • DOI: https://doi.org/10.1007/978-94-009-0567-2_55

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6743-0

  • Online ISBN: 978-94-009-0567-2

  • eBook Packages: Springer Book Archive

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