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Laboratory Kinetic Studies of Reactions of Iodine Species Occurring in Marine Atmosphere

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Physico-Chemical Behaviour of Atmospheric Pollutants

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Summary

The reactions I + HO2 ---> HI + O2 (1) and OH + HI---> H2O + I (2) have been studied at 298 K using the Discharge Flow- EPR method. Reaction (2) was also studied by the Laser Photolysis-Resonance Fluorescence technique. The rate constants were found to be k1 = (3.1 ± 1.2) x 10-13 and k2 = (3.0 ± 0.5) x 10-11 (units are cm3 molecule-1s-1). These data allow for assessing the importance of HI as a reservoir of active iodine in atmospheres such as the marine boundary layer.

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Author information

Authors and Affiliations

  1. CRCCHT/CNRS, 45071, ORLEANS-Cedex 2, France

    J. L. Jourdain, G. Laverdet, G. Le Bras, H. MacLeod, A. Mellouki & G. Poulet

Authors
  1. J. L. Jourdain
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  2. G. Laverdet
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  3. G. Le Bras
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  4. H. MacLeod
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  5. A. Mellouki
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  6. G. Poulet
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Editor information

Editors and Affiliations

  1. Joint Research Centre, Environment Institute, Ispra, Italy

    G. Restelli

  2. Commission of the European Communities, Directorate-General Science, Research and Development, Italy

    G. Angeletti

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© 1990 ECSC, EEC, EAEC, Brussels and Luxembourg

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Jourdain, J.L., Laverdet, G., Le Bras, G., MacLeod, H., Mellouki, A., Poulet, G. (1990). Laboratory Kinetic Studies of Reactions of Iodine Species Occurring in Marine Atmosphere. In: Restelli, G., Angeletti, G. (eds) Physico-Chemical Behaviour of Atmospheric Pollutants. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0567-2_24

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  • DOI: https://doi.org/10.1007/978-94-009-0567-2_24

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6743-0

  • Online ISBN: 978-94-009-0567-2

  • eBook Packages: Springer Book Archive

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