Self-Assemblies in Ion-Containing Polymers

  • A. R. Khokhlov
  • O. E. Philippova
Part of the NATO ASI Series book series (NSSE, volume 327)

Abstract

Polyelectrolytes are macromolecules containing electrically charged monomer units . Ionization is normally a result of dissociation of electrically neutral onomer unit i n t o charged unit and counterion. Therefore, counterions re always present in polyelectrolyte systems, and the number of charged monomer links is equal to the number of counterions.

Keywords

Monomer Unit Critical Micelle Concen Microphase Separation Neutral Polymer Macroscopic Phase Separation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Landau, L.D. and Lifshits, E.M. (1976) Statisticheskaya Fizika (Statistical Physics), Nauka, Moscow, v.5.Google Scholar
  2. 2.
    Manning, G.S. (1972) Polyelectrolytes, Annu. Rev. Phys. Chem. 23, 117–140.CrossRefGoogle Scholar
  3. 3.
    Oosawa, F. (1971) Polyelectrolytes, Marcel Dekker, New York.Google Scholar
  4. 4.
    Grosberg, AYu. and Khokhlov, A.R. (1994) Statistical Physics of Macromolecules, AIP Press, New York.Google Scholar
  5. 5.
    Odijk, T. (1977) Polyelectrolytes near the rod limit, J. Polym. Sci., Part B: Polym. Phys. 15, 477–483.Google Scholar
  6. 6.
    Skolnick, J. and Fixman, M. (1977)Electrostatic persistence length of a wormlike polyelectrolyte Macromolecules 10, 944–948.Google Scholar
  7. 7.
    Khokhlov, A.R., Starodubtzev, S.G., and Vasilevskaya, V.V. (1993) Conformational transitions in polymer gels: theory and experiment, Adv. Polym. Sci. 109, 123–171.Google Scholar
  8. 8.
    Eisenberg, A. (1970) Clustering of ions in organic polymers. A theoretical approach, Macromolecules 3, 147–154.Google Scholar
  9. 9.
    Eisenberg, A., Hird, B., and Moore, M. (1990) A new multiplet-cluster model for the morphology of random ionomers, Macromolecules 23, 4098–4107.CrossRefGoogle Scholar
  10. 10.
    Mauritz, K.A. (1988) Review and critical analyses of theories of aggregation in ionomers, J. Macromol. Sci. - Rev. Macromol. Chem. PhysC28, 65–98.Google Scholar
  11. 11.
    Nyrkova, I.A., Khokhlov, A.R., and Doi, M. (1993) Microdomains in blockcopolymers and multiplets in ionomers: parallels in behavior, Macromolecules 26, 3601–3610.CrossRefGoogle Scholar
  12. 12.
    Starodubtsev, S.G., Khokhlov, A.R., and Vasilevskaya V.V. (1985) Collapse of polyacrylamide networks: influence of mechanical deformation of a sample and of type of solvent, Dokl. Akad. Nauk SSSR 282, 392–395.Google Scholar
  13. 13.
    Khokhlov, A.R. and Kramarenko, E.Yu. (1994) Polyelectrolyte/ionomer behavior in polymer gel collapse, Makromol. Chem., Theory Simul. 3, 45–59.Google Scholar
  14. 14.
    Khokhlov, A.R., Makhaeva, E.E., Philippova, O.E., and Starodubtzev, S.G. (1994) Supramolecular structures and conformational transitions in polyelectrolyte gels, Makromol. Chem., Macromol. Symp. 87, 69–91.Google Scholar
  15. 15.
    Philippova, O.E., Pieper, T.G., Sitnikova, N.L., Starodoubtsev, S.G., Khokhlov, A.R., and Kilian, H.G. (in press) Conformational transitions in polyelectrolyte networks in binary solvents: microheterogeneities in the collapsed state, Macromolecules Google Scholar
  16. 16.
    Khokhlov, A.R. XANDXKramarenko, E.Yu. (in press) Weakly charged polyelectrolytes: Collapse induced by extra ionization, Macromolecules Google Scholar
  17. 17.
    Starodoubtsev, S.G., Khokhlov, A.R., Sokolov, E.L., and Chu, B. (in press) Evidence for polyelectrolyte/ionomer behavior in the collapse of polycationic gels, Macromolecules Google Scholar
  18. 18.
    Philippova, O.E. XANDXSitnikova, N.L. (in press) Conformational behavior of ionic gels in nonpolar media, in Abstracts of the First International Symposium on Polyelectrolytes Polyelectrolytes in Solution and at InterfacesSeptember 18–22, 1995, Potsdam.Google Scholar
  19. 19.
    Semenov, A.N., Joanny, J.F., and Khokhlov, A.R. (1994) Associating polymers: equilibrium and linear viscoelasticity, Macromolecules 28, 1066–1075.CrossRefGoogle Scholar
  20. 20.
    Semenov, A.N., Nyrkova, I.A., and Khokhlov, A.R. (in press) Polymers with strongly interacting groups: theory for non-spherical multiplets, Macromolecules Google Scholar
  21. 21.
    Paul, D.R. and Newman, S. (1978) Polymer Blends, Academic Press, New York.Google Scholar
  22. 22.
    Olabisi, D., Robeson, L.M., and Shaw, M.T. (1979) Polymer-Polymer Miscibility, Academic Press, New York.Google Scholar
  23. 23.
    Vasilevskaya, V.V., Starodubtzev, S.G., and Khokhlov, A.R. (1987) Miscibility enhancement of polymer mixtures at charging of one of the components, Vysokomol. Soedin., Ser. B 29, 930–933.Google Scholar
  24. 24.
    Nyrkova, I.A., Khokhlov, A.R., and Kramarenko. E.Yu. (1990) Possibility of microphase separation in polyelectrolyte systems, Polym. Sci. (USSR) 32, 852–861.CrossRefGoogle Scholar
  25. 25.
    Khokhlov, A.R. and Nyrkova, I.A. (1992) Compatibility enhancement and microdomain structuring in weakly charged polyelectrolyte mixtures, Macromolecules 25, 1493–1502.CrossRefGoogle Scholar
  26. 26.
    Nyrkova, I.A., Khokhlov, A.R., and Doi, M. (1994) Microdomain structures in polyelectrolyte systems: calculation of the phase diagrams by direct minimization of thefree energy, Macromolecules 27, 4220–4230.CrossRefGoogle Scholar
  27. 27.
    Piculell, L. and Lindman, B. (1992) Adv. Colloid Interface Sci41, 149–178.CrossRefGoogle Scholar
  28. 28.
    Philippova, O.E. and Starodubtzev, S.G. (1993) Miscibility enhancement of polymers n polar media by incorporation of a small amount of charged groups into the olymer chains, Makromol. Chem., Rapid Commun. 14, 421–425.CrossRefGoogle Scholar
  29. 29.
    Dusek, K. and Patterson, D. (1968) Transitions in swollen polymer networks induced y intramolecular condensation, J. Polym. Sci., Part A-2 6, 1209–1216.CrossRefGoogle Scholar
  30. 30.
    Tanaka, T. (1978) Collapse of gels and the critical endpoint, Phys. Rev. Lett. 40, 20–823.CrossRefGoogle Scholar
  31. 31.
    Khokhlov, A.R. (1980) Swelling and collapse of polymer networks, Polymer 21, 76–380.CrossRefGoogle Scholar
  32. 32.
    Tanaka, T., Fillmore, D.J., Sun, S.-T., Nishio, J., Swislow, G., and Shah, A. (1980) hase transitions in ionic gels, Phys. Rev. Lett. 45, 1636–1639.CrossRefGoogle Scholar
  33. 33.
    Stejskal, J., Gordon, M., and Torkington, J.A. (1980) Collapse of polyacrylamide els, Polym. Bull. 3, 621–625.CrossRefGoogle Scholar
  34. 34.
    Vasilevskaya, V.V. and Khokhlov, A.R. (1986) Influence of low molecular weight alt on the collapse of polymer networks, Vysokomolek. Soed., Ser.A 28, 316–320.Google Scholar
  35. 35.
    Ptytsyn, O.B. and Eizner, Yu.E. (1965)Theory of coil-globule transitions in macromolecules, iofizika 10, 3–9.Google Scholar
  36. 36.
    de Gennes, P.G. (1975) Collapse of a polymer chain in poor solvents, J. Phys. France ett. 36, 55–57.Google Scholar
  37. 37.
    Lifshitz, I.M., Grosberg, A.Yu., and Khokhlov, A.R. (1976) Structure of polymer globule formed by saturated bonds, Sov. Phys. JETP 71, 1634–1643.Google Scholar
  38. 38.
    Lifshitz, I.M., Grosberg, A.Yu., and Khokhlov, A.R. (1978) Some problems of the statistical physics of polymer chains with volume interactions, Rev. Mod. Phys. 50, 683–713.CrossRefGoogle Scholar
  39. 39.
    Lifshitz, I.M., Grosberg, A.Yu., and Khokhlov, A.R. (1979) Volume interactions in the statistical physics of a polymer macromolecule, Usp. Fiz. Nauk 127, 353–389.CrossRefGoogle Scholar
  40. 40.
    Flory, P.J. (1953) Principles of Polymer Chemistry Cornell University Press, Ithaca, New York.Google Scholar
  41. 41.
    Borue, V.Yu. and Erukhimovich, I.Ya. (1986) Structural phase transitions in solutions of weakly charged polyelectrolytes, Dokl. Akad. Nauk USSR 286, 1373–1376.Google Scholar
  42. 42.
    Borue, V.Yu. and Erukhimovich, I.Ya. (1988) A statistical theory of weakly chargedpolyelectrolytes: fluctuations, equation of state, and microphase separation, Macromolecules 21, 3240–3249.CrossRefGoogle Scholar
  43. 43.
    Joanny, J.F. and Leibler, L. (1990) Weakly charged polyelectrolytes in a poor solvent, J. Phys. France51, 545–557.CrossRefGoogle Scholar
  44. 44.
    Brereton, M.G. and Vilgis, T.A. (1990) Compatibility and phase behavior in charged polymer systems and ionomers, Macromolecules 23, 2044–2049.CrossRefGoogle Scholar
  45. 45.
    Dobrynin, A.V. and Erukhimovich, I.Ya. (1991) Weak crystallization and structuralphase transitions in weakly charged polyelectrolyte systems, Zh. Eksp. Teor. Fiz. 99, 1344–1359.Google Scholar
  46. 46.
    Moussaid, A., Munch, J.P., Schosseler, F., and Candau, S.J. (1991) Light scattering study of partially ionized poly (acrylic acid) systems: comparison between gels and solutions, J. Phys. France II1, 637–650.Google Scholar
  47. 47.
    Schosseler, F., Moussaid, A., Munch, J.P., and Candau, S.J. (1991) Weakly charged polyelectrolyte gels: temperature and salt effects on the statics and the dynamics, J. Phys. II France 1, 1197–1219.CrossRefGoogle Scholar
  48. 48.
    Schosseler, F., Ilmain, F., and Candau, S.J. (1991) Structure and properties of partially neutralized poly(acrylic acid) gels, Macromolecules 24, 225–234.CrossRefGoogle Scholar
  49. 49.
    4Moussaid, A., Candau, S.J., and Joosten, J.G.H. (1994) Structural and dynamic properties of partially charged poly(acrylic acid) gels: nonergodicity and inhomogeneities, Macromolecules 27, 2102–2110.CrossRefGoogle Scholar
  50. 50.
    Schosseler, F., Skouri, R., Munch, J.P., and Candau, S.J. (1994) Swelling and crosslinking density effects on the structure of partially ionized gels, J. Phys. II Franc 4, 1221–1239.CrossRefGoogle Scholar
  51. 51.
    Shibayama, M., Tanaka, T., and Han, C.C. (1992) Small angle neutron scattering study on weakly charged temperature sensitive polymer gels, J. Chem. Phys. 97, 6842–6854.CrossRefGoogle Scholar
  52. 52.
    Leibler, L. (1980) Theory of microphase separation in block copolymers, Macromolecules 13, 1602–1617.CrossRefGoogle Scholar
  53. 53.
    Erukhimovich, I.Ya. (1982) Fluctuations and the formation of domain structure in heteropolymers, Vysokomol. Soedin., Ser.A 24, 1942–1949.Google Scholar
  54. 54.
    Lifshitz, I.M. (1968) Some questions of statistical theory of biopolymers, Zh. Eksp. Teor. Fiz. 55, 2408–2422.Google Scholar
  55. 55.
    Nyrkova, I.A., Doi, M., and Khokhlov, A.R. (1993) Microdomain structures in polyelectrolyte mixtures, Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 34, 926– 927.Google Scholar
  56. 56.
    Dormidontova, E.E., Erukhimovich, I.Ya., and Khokhlov, A.R. (1994) Microphase separation in poor solvent polyelectrolyte solution: phase diagram, Makromol. Chem., Theory Simul. 3, 661–675.Google Scholar
  57. 57.
    Ryabina, V.R., Starodubtsev, S.G., and Khokhlov, A.R. (1990) Interaction of polyelectrolytenetworks with oppositely charged micelle-forming surfactants, Vysokomol. Soedin., Ser.A 32, 969–974.Google Scholar
  58. 58.
    Starodoubtzev, S.G. (1990) Influence of topological structure of polyelectrolyte networks on their interaction with oppositely charged micelle-forming surfactants, Vysokomol. Soedin., Ser.B 31, 925–930.Google Scholar
  59. 59.
    Vasilevskaya, V.V., Kramarenko, E.Yu., and Khokhlov, A.R. (1991) Theory of collapse of polyelectrolyte networks in solutions of ionic surfactants, Vysokomol. Soedin., Ser.A 33, 1062–1069.Google Scholar
  60. 60.
    Khokhlov, A.R., Kramarenko, E.Yu., Makhaeva, E.E., and Starodubtzev, S.G. (1992) Collapse of polyelectrolyte networks induced by their interaction with oppositely charged surfactants. Theory, Makromol. Chem., Theory Simul. 1, 105–118.CrossRefGoogle Scholar
  61. 61.
    Khokhlov, A.R., Kramarenko, E.Yu., Makhaeva, E.E., and Starodubtsev, S.G. (1992) Collapse of polyelectrolyte networks induced by their interaction with oppositelycharged surfactants, Macromolecules 25, 4779–4783.CrossRefGoogle Scholar
  62. 62.
    Bisenbaev, A.K., Makhaeva, E.E., Saletskii, A.M., and Starodubtsev, S.G. (1992) Complexes between sodium polyacrylate networks and cetyltrimethylammoniumbromide. A fluorescent probe investigation, Polym. Sci. (USSR) 34, 1059–1062.Google Scholar
  63. 63.
    Philippova, O.E. and Starodoutzev, S.G. (1993) Interaction of slightly cross-linked gels of poly(diallyldimethylammonium bromide) with sodium dodecyl sulfate. Diffusion of surfactant ions in gel, J. Polym. Sci., Part B: Polymer Physics 31, 1471–1476.CrossRefGoogle Scholar
  64. 64.
    Makhaeva, E.E. and Starodubtzev, S.G. (1993) Swelling of a polyelectrolyte network of sodium methacrylate/acrylamide copolymer in water-2-propanol mixtures in the presence of cetylpyridinium bromide, Makromol. Chem., Rapid Commun. 14, 105–107.CrossRefGoogle Scholar
  65. 65.
    Machaeva, E.E. and Starodubtzev, S.G. (1993) Reentrant conformational transition of polyelectrolyte network in water alcohol mixtures in the presence of oppositely charged surfactant, Polym. Bull. 30, 327–331.CrossRefGoogle Scholar
  66. 66.
    Karib’yants, N.S., Starodubtsev, S.G., and Filippova, O.E. (1993) Interaction of the low-cross-linked gel of poly(methacrylic acid) with poly(ethylene glycol) and cetylpyridinium chloride, Polym. Sci. (USSR) 35, 471–475.Google Scholar
  67. 67.
    Le Minh Thanh, Makhaeva, E.E., and Starodubtzev, S.G. (1993) Interaction of sodium dodecyl sulfate and salts of Cu — C n carboxylic acids with poly(diallyldimethylammonium bromide) gel, Vysokomol. Soedin., Ser.A 35, 408–412.Google Scholar
  68. 68.
    Khandurina, Yu.V., Rogacheva, V.B., Zezin, A.B., and Kabanov, V.A. (1994) Interaction of cross-linked polyelectrolytes with oppositely charged surfactants, Polym. Sci. (USSR) 36, 184–188.Google Scholar
  69. 69.
    Okuzaki, H. and Osada, Y. (1994) Effects of hydrophobic interaction on the cooperative binding of a surfactant to a polymer network, Macromolecules 27, 502–506.CrossRefGoogle Scholar
  70. 70.
    Sasaki, S., Fujimoto, D., and Maeda, H. (1995) Effects of salt concentration anddegree of ionization on the hydrophobic counterion binding to ionic gel and thecontraction of the gel volume, Polymer Gels and Networks 3, 145–158.CrossRefGoogle Scholar
  71. 71.
    Starodubtzev, S.G., Le Thi Minh Thanh, Makhaeva, E.E., Philippova, O.E., and Pieper, T.G. (in press) Interaction of slightly crosslinkedgel of poly(diallyldimethylammonium bromide) with sodium dodecyl sulfate and cetylpyridinium bromide, Makromol. Chem. Google Scholar
  72. 72.
    Chu, B., Yeh, F., Sokolov, E.L., Starodoubtsev, S.G., and Khokhlov, A.R. (in press) Interaction of poly(diallyldimethylammoniurn chloride) gels with sodium dodecyl sulfate. Phase transitions and structure of polymer-surfactant complexes, Macromolecules Google Scholar
  73. 73.
    Khandurina, Yu.V., Dembo, A.T., Rogacheva, V.B., Zezin, A.B., and Kabanov, V.A. (1994) Structure of poly complexes composed of cross-linked sodium polyacrylate and cationic micelle-forming surfactants, Polym. Sci. (USSR) 36, 189–194Google Scholar

Copyright information

© Springer Science+Business Media B.V. 1996

Authors and Affiliations

  • A. R. Khokhlov
    • 1
  • O. E. Philippova
    • 1
  1. 1.Physics DepartmentMoscow State UniversityMoscowRussia

Personalised recommendations