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Ionic and Molecular Transport Through Graphene Membranes

  • Rohit Karnik
Conference paper
Part of the NATO Science for Peace and Security Series C: Environmental Security book series (NAPSC)

Abstract

New membrane materials have the potential to address some of the persistent challenges in water purification to improve the flux of water, selectivity to ions or contaminants, and fouling resistance. With its atomistic thickness and the ability to sustain nanometer-scale holes, graphene promises significant enhancement in the flux of water while offering potentially novel transport properties. In this work, the transport of ions and molecules through a single layer of graphene were measured as a first step towards realizing practical graphene membranes. Graphene grown by chemical vapor deposition (CVD) was transferred to a porous polycarbonate support membrane, and the diffusion of different salts and molecules was examined. While pressure-driven flow measurements revealed that the graphene covered the polycarbonate support membrane, diffusion experiments showed that it was permeable to salts, but not to larger molecules. This behavior was attributed to intrinsic defects in graphene in the 1–15 nm size range.

Keywords

Reverse Osmosis Scan Transmission Electron Microscopy Membrane Material Water Desalination Graphene Lattice 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

The author thanks the organizers and NATO for the opportunity to attend the NATO Advanced Research Workshop on Alternative Water Resources in Arid Areas by Retrieving Water from Secondary Sources held at the Daniel Dead Sea Hotel, Israel, from May 7–11, 2012. The author would like to thank students and collaborators involved in the research, especially Sean O’Hern. The work discussed here was funded by King Fahd University of Petroleum and Minerals in Dhahran, Saudi Arabia through the Center for Clean Water and Clean Energy at MIT and KFUPM under project number R10-CW-09. Part of the research was performed at ORNL’s Shared Research Equipment (ShaRE) User Program sponsored by DOE, the Center for Nanoscale Systems (CNS) at Harvard, and the Center for Materials Science and Engineering at MIT.

References

  1. 1.
    Humplik T et al (2011) Nanostructured materials for water desalination. Nanotechnology 22(29):292001CrossRefGoogle Scholar
  2. 2.
    Allen MJ, Tung VC, Kaner RB (2010) Honeycomb carbon: a review of graphene. Chem Rev 110(1):132–145CrossRefGoogle Scholar
  3. 3.
    Lee C et al (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388CrossRefGoogle Scholar
  4. 4.
    Bunch JS et al (2008) Impermeable atomic membranes from graphene sheets. Nano Lett 8(8):2458–2462CrossRefGoogle Scholar
  5. 5.
    Sint K, Wang B, Kral P (2008) Selective ion passage through functionalized graphene nanopores. J Am Chem Soc 130(49):16448–16449CrossRefGoogle Scholar
  6. 6.
    Jiang DE, Cooper VR, Dai S (2009) Porous graphene as the ultimate membrane for gas separation. Nano Lett 9(12):4019–4024CrossRefGoogle Scholar
  7. 7.
    Schrier J (2010) Helium separation using porous graphene membranes. J Phys Chem Lett 1:2284–2287CrossRefGoogle Scholar
  8. 8.
    Cohen-Tanugi D, Grossman JC (2012) Water desalination across nanoporous graphene. Nano Lett 12(7):3602–3608CrossRefGoogle Scholar
  9. 9.
    Suk ME, Aluru NR (2010) Water transport through ultrathin graphene. J Phys Chem Lett 1(10):1590–1594CrossRefGoogle Scholar
  10. 10.
    Koenig SP et al (2012) Selective molecular sieving through porous graphene. Nat Nanotechnol 7(11):728–732CrossRefGoogle Scholar
  11. 11.
    O’Hern SC et al (2012) Selective molecular transport through intrinsic defects in a single layer of CVD graphene. ACS Nano 6(11):10130–10138CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  1. 1.Department of Mechanical EngineeringMassachusetts Institute of TechnologyCambridgeUSA

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