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Pyrolysis and Thermal Oxidative Decomposition of Timber

  • Roza Aseeva
  • Boris Serkov
  • Andrey Sivenkov
Chapter
Part of the Springer Series in Wood Science book series (SSWOO)

Abstract

This chapter summarizes the data on pyrolysis and thermal oxidative decomposition of solid timber as well as its main components at various thermal and fire loads. The effects of speed and intensity of heating and oxygen content are discussed. The chapter presents comprehensive data for understanding thermal and fire resistance of natural timber, including kinetic parameters of thermal decomposition of timber and its components, effects of various specious and thermal loads on volatile products, charring formation, thickness of char, effective heat of gasification for various species, etc. Some numerical models for thermal decomposition and calculation and charring of timber are discussed.

Keywords

Mass Loss Rate Pyrolysis Product Wood Specimen Char Residue Effective Activation Energy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. ASTM E 1641-2004. Standard test method for decomposition kinetics by thermogravimetryGoogle Scholar
  2. Bradbury AGW, Sakai Y, Shafizadeh F (1979) Kinetic model for pyrolysis of cellulose. J Appl Polym Sci 23:3271–3280CrossRefGoogle Scholar
  3. Branca C, Di Blasi C (2004) Global intrinsic kinetics of wood oxidation. Fuel 83(1):81–87CrossRefGoogle Scholar
  4. Branca C, Albano A, Di Blasi C (2005) Critical evaluation of wood devolatilization mechanisms. Thermochim Acta 429:133–141CrossRefGoogle Scholar
  5. Chen Y, Delichatsios MA, Motevalli MA (1993) Material properties. Part 1: an integral model for one-dimensional transient pyrolysis of charring and non-charring materials. Combust Sci Technol 88:309–328CrossRefGoogle Scholar
  6. Cordero T, Rodriguez- Maroto JM, Garcia F, Rodriguez JJ (1991) Thermal decomposition of wood in oxidizing atmosphere. A kinetic study from non-isothermal TGA experiments. Thermochim Acta 191:161–178CrossRefGoogle Scholar
  7. Di Blasi C (1993) Modeling and simulation of combustion processes of charring and non-charring solid fuels. Prog Energy Combust Sci 19:71–104CrossRefGoogle Scholar
  8. Di Blasi C (2000) The state of the art of transport models for charring solid degradation. Polym Int 49:1133–1146CrossRefGoogle Scholar
  9. Di Blasi C (2008) Modeling chemical and physical processes of wood and biomass pyrolysis. Prog Energy Combust Sci 34:47–90CrossRefGoogle Scholar
  10. Di Blasi C, Branca C (2001) Kinetics of primary product formation from wood pyrolysis. Ind Eng Chem Res 40:5547–5556CrossRefGoogle Scholar
  11. Di Blasi C, Branca C, Fumo E (1999) Non-isothermal kinetics of wood degradation and combustion. In: Proceedings of the 8-th international conference on fire science and engineering, interflam’99, vol 2. Edinburgh, Scotland, pp 873–884Google Scholar
  12. Di Blasi C, Branca C, Santoro A, Gonzales Hernandez E (2001) Pyrolytic behavior and products of some wood varieties. Combust Flame 124:165–177CrossRefGoogle Scholar
  13. Fang MX et al (2006) Kinetic study on pyrolysis and combustion of wood under different oxygen concentrations by using TG-FTIR analysis. J Anal Appl Pyrolysis 77(1):22–27CrossRefGoogle Scholar
  14. Golova OP (1975) Chemical effects of heat on cellulose. Russ Chem Rev 44(8):1454–1474Google Scholar
  15. Gronli MG, Varhegyi G, Di Blasi C (2002) Thermogravimetric analysis and devolatilization kinetics of wood. Ind Eng Chem Res 41:4201–4208CrossRefGoogle Scholar
  16. Himoto K, Tanaka T (2004) A burning model for charring materials and its application to the compartment fire development. Fire Sci Technol 23(3):170–190CrossRefGoogle Scholar
  17. ISO 11358-2005. Plastics. Thermogravimetry of polymers, Part 2. Determination of kinetic parametersGoogle Scholar
  18. Jia F, Galea ER, Patel MK (1999) Numerical simulation of the mass loss process in pyrolizing char materials. Fire Mater 23:71–78CrossRefGoogle Scholar
  19. Kanury AM, Holve DJ (1982) Transient conduction with pyrolysis (approximate solutions for charring of wood slabs). J Heat Transf 104:338–343CrossRefGoogle Scholar
  20. Kashiwagi T, Nambu H (1992) Global kinetic constants for thermal oxidative degradation of cellulosic paper. Combust Flame 88:345–368CrossRefGoogle Scholar
  21. Kashiwagi T, Ohlemiller TJ, Werner K (1987) Effects of external radiative flux and ambient oxygen concentration on nonflaming gasification rates and evolved products of white pine. Combust Flame 69:331–345CrossRefGoogle Scholar
  22. Kawamoto H et al (2007a) Pyrolysis behaviour of wood and its constituent polymers at gasification temperature. J Anal Appl Pyrolysis 78:328–336CrossRefGoogle Scholar
  23. Kawamoto H et al (2007b) Cellulose-hemicellulose and cellulose-lignin interaction in wood pyrolysis at gasification temperature. J Anal Appl Pyrolysis 80:118–125CrossRefGoogle Scholar
  24. Konkin АА (1974) Carbon and other heat-resistant fiber materials, Moscow, Chemistry, 375 pGoogle Scholar
  25. Kung HC (1972) A mathematical model of wood pyrolysis. Combust Flame 18:185–195CrossRefGoogle Scholar
  26. Kunury AM (1972) Rate of burning of wood. Combust Sci Тechnol 5:135–146Google Scholar
  27. Lautenberger C, Fernandez-Pello C (2009) A model for the oxidative pyrolysis of wood. Combust Flame 156:1503–1513CrossRefGoogle Scholar
  28. Lee CK, Chaiken RF, Singer JM (1976) Charring pyrolysis of wood in fires by laser simulation. In: Proceedings of 16-th symposium (international) on combustion. The Combustion Institute, Pittsburgh, pp 1459–1469Google Scholar
  29. Liden A, Berruti F, Scott D (1988) A kinetic model for the production of liquids from the flash pyrolysis of biomass. Chem Eng Commun 65:207–221CrossRefGoogle Scholar
  30. Mamleev V, Bourbigot S, Le Bras M, Yvon J (2009) The facts and hypothesis relating to the phenomenological model of cellulose pyrolysis. Independence of the steps. J Anal Appl Pyrolysis 84(1):1–17CrossRefGoogle Scholar
  31. Mikkola E (1991) Charring of wood based materials. In: Proceeding of 3rd international symposium on fire safety science. Elsevier, pp 547–556Google Scholar
  32. Miller RS, Bellan J (1996) A generalized biomass pyrolysis model based on superimposed cellulose, hemicellulose and lignin kinetics. Combust Sci Technol 126:97–137CrossRefGoogle Scholar
  33. Miller CA, Ramohalli KNR (1986) A theoretical heterogeneous model of wood pyrolysis. Combust Sci Technol 46:249–265CrossRefGoogle Scholar
  34. Moghtadery B, Novozhilov V, Fletcher D, Kent JH (1997) An integral model for the transient pyrolysis of solid materials. Fire Mater 21:7–16CrossRefGoogle Scholar
  35. Nakamura T, Kawamoto H, Saka S (2008) Pyrolysis behaviour of Japanese cedar wood lignin studied with varies model dimmers. J Anal Appl Pyrolysis 81:173–182CrossRefGoogle Scholar
  36. Roberts AF (1970) A review of kinetics data for the pyrolysis of wood and related substances. Combust Flame 14:261–272CrossRefGoogle Scholar
  37. Rogers FE, Ohlemiller TJ (1981) Pyrolysis kinetics of a polyurethane foam by thermogravimetry. A general kinetic method. J Macromol Sci Chem A 15(1):169–185CrossRefGoogle Scholar
  38. Serkov BB, Sivenkov AB, Tkhan BD, Aseeva RM (2005a) Thermal decomposition of tropical wood species. Lesn Vestn (Russ) 2(38):70–76Google Scholar
  39. Serkov BB, Sivenkov AB, Than BD, Aseeva RM (2005b) Thermal decomposition of tropical wood species, No 2(38). Moscow State Forest University Publishing House, Lesnoy Vestnik, pp70–76Google Scholar
  40. Serkov BB, Sivenkov AB, Souleikin EV, Degtyaryov RV, Tarasov NI (2009) Fire hazard features of archaeological wood. Fires and emergencies: prevention, response. Moscow, ASFS, No 1, pp 4–28Google Scholar
  41. Shafizadeh F, McGinnis GD (1971) Chemical composition and thermal analysis of cotton wood. Carbohydr Res 16:273–277CrossRefGoogle Scholar
  42. Shestak Ya (1987) Theory of thermal analysis. Mir, Moscow, 456pGoogle Scholar
  43. Spearpoint MJ, Quintiere JG (2000) Predicting the burning of wood using an integral model. Combust Flame 123:308–324CrossRefGoogle Scholar
  44. Thurner F, Mann U (1981) Kinetic investigation of wood pyrolysis. Ind Eng Chem Process Des Dev 20:482–488CrossRefGoogle Scholar
  45. Varhegyi G, Gronli MG, Di Blasi C (2004) Effects of sample origin, extraction, and hot-water washing on the devolatilization kinetics of chestnut wood. Ind Eng Chem Res 43:2356–2367CrossRefGoogle Scholar
  46. Ward SM, Braslaw J (1985) Experimental weight loss kinetics of wood pyrolysis under vacuum. Combust Flame 61:261–269CrossRefGoogle Scholar
  47. Wichman IS, Atreya A (1987) A simplified model for the pyrolysis of charring materials. Combust Flame 68:231–247CrossRefGoogle Scholar
  48. Zickler GA et al (2007) In situ X-ray diffraction investigation of thermal decomposition of wood cellulose. J Anal Appl Pyrolysis 80:134–140CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  • Roza Aseeva
    • 1
  • Boris Serkov
    • 1
  • Andrey Sivenkov
    • 1
  1. 1.Fire Safety in BuildingsState Fire Academy Ministry of Civil Protection and EmergencyMoscowRussia

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