Abstract
In this chapter, several aspects of the ageing phenomena induced by water in organic matrix composites are examined, essentially from the physico-chemical point of view. It is first important to recognize that there are two main categories of humid ageing. First there are physical processes, mainly linked to the stress state induced by matrix swelling and sometimes matrix plasticization. This kind of ageing can occur in matrices of relatively high hydrophilicity (affinity with water). Highly crosslinked amine cured epoxies are typical examples of this behavior. The second category of humid ageing involves a chemical reaction (hydrolysis) between the material and water. Unsaturated polyesters are typical examples of this category. They display a low to moderate hydrophilicity, swelling and plasticization have minor effects, but hydrolysis induces a deep polymer embrittlement and, eventually, osmotic cracking. Whatever the ageing mechanism, it needs the water to penetrate into the material and depends on the water concentration and its distribution in the sample thickness. This is the reason why the first and second sections are respectively dedicated to water solubility and diffusivity in matrices, interphases and composites. In each case, the elementary processes are distinguished, to examine the effects of temperature and stress state and to establish structure–property relationships. It is shown that, in most of these aspects, research remains largely open. The last section is devoted to hydrolysis, its kinetic modeling, including the case of diffusion controlled hydrolysis, and its consequences on polymer properties. Structure reactivity relationships are briefly presented. The very important case of osmotic cracking, which can be considered as a consequence of hydrolysis, is also examined.
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References
Lubin G, Donohue P (1980) Real life ageing of composites. In: 31st ANTEC, reinforced plastics/composites section, The Society of the Plastics Industry, paper 17E
McCall DW, Douglass DC, Blyler LL Jr, Johnson GE, Jelinski LW, Bair HE (1984) Solubility and diffusion of water in low-density polyethylene. Macromolecules 17(9):1644–1649
MKacher I (2012) Vieillissement thermique des gaines PE et PVC de câbles électriques, PhD Thesis, ARTS ET METIERS ParisTech Paris, France
Li SZ, Chen RS (1995) NMR studies of water in polyimide films. J Polym Sci Part B Polym Phys Ed 33(3):403–409
Zhou J, Lucas JP (1999) Hygrothermal effects of epoxy resin. Part I: the nature of water in epoxy. Polymer 40:5505–5512
Popineau S, Rondeau-Mouro C, Sulpice-Gaillet C, Shanahan MER (2005) Free/bound water absorption in an epoxy adhesive. Polymer 46:10733–10740
Reid JD, Lawrence WH, Buck RP (1986) Dielectric properties of an epoxy resin and its composite I. Moisture effects on dipole relaxation. J Appl Polym Sci 31(6):1771–1784
Grave C, McEwan I, Pethrick RA (1998) Influence of stoichi- ometric ratio on water absorption in epoxy resins. J Appl Polym Sci 69(12):2369–2376
Lim RS, Nowick AS, Lee KW, Viehbeck A (1993) Sorption of water and organic solutes in polyimide films and Its effects on dielectric properties. J Polym Sci Polym Phys Ed 31:545–555
Illinger JL, Schneider NS (1980) Water vapor transport in an epoxy resin based on TGMDA and DICY. Polym Eng Sci 20:310–314
Cotugno S, Larobina D, Mensitieri G, Musto P, Ragosta G (2001) A novel spectroscopic approach to investigate transport processes in polymers: the case of water–epoxy system. Polymer 42(15):6431–6438
Brunauer S, Emmett PH, Teller E (1938) Adsorption of gasses in multimolecular layers. J Amer Chem Soc 60(2):309–319
Barrett EP, Joyner LG, Halenda PP (1951) The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Amer Chem Soc 73:373–380
Desvaux H, Gautier T, Le Goff G, Petro M, Berthault P (2000) Direct evidence of a magnetization transfer between laser-polarized xenon and protons of a cage-molecule in water. Eur Phys J D 12:289–296
Zimm BH, Lundberg JL (1956) Sorption of vapours by high polymers. J Phys Chem 60(4):425–428
Barrer R, Barrie J, Slater J (1958) Sorption and diffusion in ethyl cellulose. Part III. Comparison between ethyl cellulose and rubber. J Polym Sci 27:177–197
Merdas I, Thominette F, Tcharkhtchi A, Verdu J (2002) Factors governing water absorption by composite matrices. Compos Sci Technol 62:487–492
Tcharkhtchi A, Bronnec Y, Verdu J (2000) Water absorption characteristics of diglycidylether of butane diol-3,5-2,4-diaminotoluene networks. Polymer 41(15):5777–5785
Derrien K, Gilormini P (2007) The effect of applied stresses on the equilibrium moisture content in polymers. Scr Mater 56(4):297–299
Weitsman YJ (1987) Stress assisted diffusion in elastic and viscoelastic materials. J Mech Phys Solids 35(1):73–93
Weitsman YJ (2000) Effects of fluids on polymeric composites—a review. Compre Compos Mater 2:369–401
Adamson MJ (1980) Thermal expansion and swelling of cured epoxy resin used in graphite/epoxy composite materials. J Mater Sci 15:1736–1745
Enns JB, Gilham JK (1983) Effect of the extent of cure on the modulus, glass transition, water absorptio, and density of an amine-cured epoxy. J Appl Polym Sci 28(9):2831–2846
Gupta VB, Drzal LT, Rich M (1985) The physical basis of moisture transport in a cured epoxy resin system. J Appl Polym Sci 30(11):4467–4693
Johncock P, Tudgey GF (1986) Some effects of structure, composition and cure on the water absorption and glass transition temperature of amine-cured epoxies. Brit Polym J 18(5):292–302
Barrie JA (1968) Water in polymers. In: Crank J, Park GS (eds) Diffusion in polymers, 4th edn. Academic Press, London, pp 259-313
Morel E, Bellenger V, Verdu J (1985) Structure-water absorption relationships for amine cured epoxy resins. Polymer 26:1719–1724
Van Krevelen DW, Te Nijenhuis K (2009) Properties of polymers. Their correlation with chemical structure. Their numerical estimation and prediction from additive group contributions, 4th edn. Elsevier, Amsterdam
Bellenger V, Verdu J, Morel E (1989) Structure properties relationships for densely crosslinked epoxy-amine system based on epoxide or amine mixtures. J Mater Sci 24:63–68
Bellenger V, Mortaigne B, Verdu J (1990) Water sorption in styrene crosslinked polyesters. J Appl Polym Sci 41:1225–1233
Bellenger V, Verdu J, Ganem M, Mortaigne B (1994) Styrene crosslinked vinylesters. II: water sorption, water diffusion and cohesive properties. Polym Polym Compos 2(1):17–25
Gaudichet-Maurin E, Thominette F, Verdu J (2008) Water sorption characteristics in moderately hydrophilic polymers. Part 1: effect of polar groups concentration and temperature in water sorption in aromatic polysulphones. J Appl Polym Sci 109(5):3279–3285
Pethrick RA, Hollins EA, McEwan L, Pollock A, Haymard D, Johncock P (1996) Effect of cure temperature on the structure and water absorption of epoxy/amine thermosets. Polym Int 39(4):228–275
Pimentel GC, McClellan AL (1960) Methods of detection: infrared and Raman Spectroscopy. In: Freeman WH (ed) The hydrogen bond. San Francisco, pp 67–141
Razumovskii LP, Zaikov GE (1985) Determination of the solubility and diffusion coefficients of water in aliphatic polyamides as a step to studying their hydrolytic stability. Polym Degrad Stab 12(1):1–12
Maxwell ID, Pethrick RA (1983) Dielectric studies of water in epoxy resins. J Appl Polym Sci 28:2363–2379
Muller-Plathe F (1998) Diffusion of water in swollen poly(vinyl alcohol) membranes studied by molecular dynamics simulation. J Membrane Sci 141(2):147–154
Starkweather HW (1975) Some aspects of water clusters in polymers. Macromolecules 8(4):476–479
Marais S, Métayer M, Nguyen QT, Labbé M, Saiter JM (2000) Difusion and permeation of water through unsaturated polyester resins-influence of of resin curing. Europ Polym J 36:453–462
Pitkethly MJ, Favre JP, Gaur U, Jakubowski J, Mudrich SF, Caldwell DL, Drzal LT, Nardin M, Wagner HD, Di Landro L, Hampe A, Armistead JP, Desaeger M, Verposet I (1993) A round-robin program on interfacial test methods. Compos Sci Technol 48:205–214
Elberaïchi A, Daro A, David C (1999) Water vapour transport in polyethylene oxide/polymethyl methacrylate blends. Europ Polym J 35(7):1217–1228
Marque G, Neyertz S, Verdu J, Prunier V, Brown D (2008) Molecular dynamics simulation study of water in amorphous kapton. Macromolecules 41(9):3349–3362
Henderson SM (1952) A basic concept of equilibrium moisture content. Agric Eng 33(1):29–32
Peleg M (1993) Assessment of a semi-empirical four parameter general model for sigmoid moisture sorption isotherms. J Food Proc Eng 16:21–37
Timmermann EO, Chirife J, Iglesias HA (2001) Water sorption isotherms of foods and foodstuffs: BET or GAB parameters? J Food Eng 48:19–31
Detallante V, Langevin D, Chappey C, Metayer M, Mercier R, Pineri M (2002) Kinetics of water vapor sorption in sulfonated polyimide membranes. Desalination 148(1):333–339
Dewimille B, Bunsell AD (1982) The modelling of hydrothermal aging in glass fibre reinforced epoxy composites. J Phys D Appl Phys 15(10):2079–2091
Wong TC, Broutman LJ (1985) Moisture diffusion in epoxy resins. Part I: non-fickian sorption processes. Polym Eng Sci 25:521–528
Walter E, Ashbee KHG (1982) Osmosis in composites materials. Composites 13(4):365–368
McKague L (1977) The thermal spike effect on wet composites. In: Proceedings of conference on environental degradation of engineering materials, Blacksburg, USA, pp. 353-362
Thomason JL (1990) Investigation of composite interphase using dynamic mechanical analysis: artifacts and reality. Polym Compos 11(2):105–113
Chiang CH, Koenig JL (1984) Fourier transform infrared spectroscopic study of the adsorption of multiple amino silane coupling agents on glass surfaces. J Colloïd Interf Sci 83(2):361–370
Hoh KP, Ishida H, Koenig JL (1986) The diffusion of epoxy resin into a silane coupling agent interphase. In: Koenig JL, Ishida H (eds) Composite interfaces, Elsevier, New York
Ishida H, Koenig JL (1978) Fourier transform infrared spectroscopic study of the silane coupling agent/porous silica interface. J Colloïd Interf Sci 64(3):555–564
Ishida H, Koenig JL (1980) A fourier-transform infrared spectroscopic study of the hydrolytic stability of silane coupling agents on E-glass fibers. J Polym Sci Part B Polym Phys 18:1931–1943
Serier A, Pascault JP, Lam TH (1989) Modeling of interphase in composite materials: characterization of epoxy resin/aminosilane system. Makromol Chem Macromol Symp 25(1):85–90
Wolff V (1996) Influence de l’ensimage sur les propriétés mécaniques de tissus de verre enduits de résine phénolique ou de latex, PhD Thesis, University of Lille I, Lille, France
Salmon L, Thominette F, Pays M-F, Verdu J (1997) Hydrolytic aging of polysiloxane networks modelling the glass fiber epoxy-amine interphase. Compos Sci Technol 57:1119–1127
Flory PJ, Rehner J Jr (1943) Statistical mechanics of cross-linked polymer networks. II. swelling. J Chem Phys 11(11):521–526
Belan F, Bellenger V, Mortaigne B, Verdu J (1997) Relationship between the structure and hydrolysis rate of unsaturated polyester prepolymers. Polym Degrad Stab 56:301–309
McKague EL Jr, Reynolds JD, Halkias JE (1978) Swelling and glass transition relations for epoxy matrix material in humid environments. J Appl Polym Sci 22(6):1643–1654
Marque G, Verdu J, Prunier V, Brown D (2010) A molecular dynamics simulation study of three polysulfones in dry and hydrated states. J Polym Sci Part B Polym Phys 48:2312–2336
Hahn HT (1987) Hygrothermal damage in graphite/epoxy laminates. J Eng Mater Technol 109(1):3–11
Delasi R, Whiteside JB (1978) Effect of moisture on epoxy resins and composites. In: Vinson JR (ed) Advanced composite materials. Environmental effects, ASTM-STP 658, American Society for Testing and Materials, Philadelphia, pp 2–20
Hahn HT, Kim RY (1978) Swelling of composite laminates. In: Vinson JR (ed) Advanced composite materials. Environmental effects, ASTM-STP 658, American Society for Testing and Materials, Philadelphia, pp 98–120
Xiao GZ, Shanahan MER (1997) Water absortion and desorption in an epoxy resin with degradation. J Polym Sci, Part B: Polym Phys 35:2659–2670
Cohn D, Marom G (1978) A proposal for a coefficient of hygroelasticity. Polyym Eng Sci 18:1001–1005
Gazit S (1978) Dimensional changes in glass-filled epoxy resins as a result of absorption of atmospheric moisture. J Appl Polym Sci 22:3547–3558
Ishai O (1975) Environmental effects on deformation, strength, and degradation of unidirectional glass-fiber reinforced plastics. I. Survey. Polym Eng Sci 15(7):486–490
Kelley FN, Bueche F (1961) Viscosity and glass temperature relations for polymer-diluent systems. J Polym Sci 50:549–556
Zhou J, Lucas JP (1999) Hygrothermal effects of epoxy resin. Part II: variations of glass transition temperature. Polymer 40:5513–5522
Carfagna C, Apicella A, Nicolais L (1982) The effect of the prepolymer composition of amino-hardened epoxy resins on the water sorption behavior and plasticization. J Appl Polym Sci 27(1):105–112
Sandorff PE, Tajima YA (1979) The experimental determination of moisture distribution in carbon-epoxy laminates. Composites 1:37–62
Ghi P, Hill DJT, Maillet D, Whittaker AK (1997) NMR imaging of the diffusion of water into poly(tetrahydrofurfuryl methacrylate-co-hydroxyethyl methacrylate). Polymer 38:3985–3989
Braun J, Klein MO, Bernarding J, Leitner MB, Mika HD (2003) Non-destructive, three-dimensional monitoring of water absorption in polyurethane foams using magnetic resonance imaging. Polym Test 22(7):761–767
Shen CH, Springer GS (1976) Moisture absorption and desorption of composite materials. J Compos Mater 10(1):2–20
Jacquemet R, Lagrange A (1990) Aspects de la diffusion de l’eau de mer dans le vieillissement de matériaux composites à base de résines polyester. Composites 30(1):17–25
Belan F (1995) Amélioration de la résistance à l’hydrolyse de résines polyester, PhD Thesis, ENSAM Paris, France
Crank J (1990) The mathematics of diffusion. Clarendon Press, London
Derrien K, Gilormini P (2006) Interaction between stress and diffusion in polymers. In: Proceedings of DSL 2006 conference, defect and diffusion forum 258/260, Lisbon, Portugal, pp. 447-452
Vaddadi P, Nakamura T, Singh RP (2003) Transient hygrothermal stresses in fiber-reinforced composites: a heterogeneous characterization approach. Compos A 34:719–730
Vaddadi P, Nakamura T, Singh RP (2003) Inverse analysis for transient moisture diffusion through fiber-reinforced composites. Acta Mater 51:177–193
Valançon C, Roy A, Grandidier JC (2006) Modelling of coupling between mechanics and water diffusion in bonded assemblies. Oil Gas Sci. Technol (IFP) 61(6):759–764
Wu CH (2001) The role of Eshelby stress in composition-generated and stress-assisted diffusion. J Mech Phys Sol 49(8):1771–1794
Fahmy AA, Hurt JC (1980) Stress dependence of water diffusion in epoxy resin. Polym Compos 1:77–80
Neumann S, Marom G (1986) Free volume dependent moisture diffusion under stress in composite materials. J Mater Sci 21(1):26–30
Barrie JA, Machin D, Nunn A (1975) Transport of water in synthetic cis-1,4-polyisoprenes and natural rubber. Polymer 16:811–814
Hopfenberg HB, Frisch HL (1969) Transport of organic micromolecules in amorphous polymers. Polym Lett 7:405–409
Koros WJ, Paul DR (1978) CO2 sorption in poly(ethylene terephthalate) above and below the glass transition. J Polym Sci Part B Polym Phys 16(11):1947–1963
Stern SA (1994) Polymers for the gas separation: the next decade. J Membr Sci 94:1–65
Yang DK, Koros WJ, Hopfenberg HB, Stannet VT (1985) Sorption and transport studies of water in Kapton polyimide. J Appl Polym Sci 30(3):1035–1047
Cohen HH, Turnbull D (1959) Molecular transport in liquids and glasses. J Chem Phys 31:1164–1169
Bellenger V, Dahoui W, Morel E, Verdu J (1988) Packing density of the amine-crosslinked stoichiometric epoxy networks. J Appl Polym Sci 35:563–571
Thominette F, Gaudichet-Maurin E, Verdu J (2006) Effect of structure on water diffusion in moderately hydrophilic polymers. In: Proceedings of DSL 2006 conference on defect and diffusion forum 258/260, Lisbon, Portugal, pp 442–446
Carter HG, Kibler KG (1978) Langmuir-type model for anomalous moisture diffusion in in composite resins. J Compos Mater 12:118–131
Morgan RJ, O’Neal JE (1978) The durability of epoxies. Polym Plast Technol Eng 10(1):49–116
Alfrey T, Gurnee EF, Lloyd WG (1966) Diffusion in glassy polymers. J Polym Sci Part C Polym Symp 12:249–261
Thomas NL, Windle AH (1982) A theory of case II diffusion. Polymer 23(4):529–542
Argon AS, Cohen RE, Patel AC (1999) A mechanistic model of case II diffusion of a diluent into a glassy polymer. Polymer 40(25):6991–7012
Barrer RM (1968) Diffusion and permeation in heterogeneous media. In: Crank J, Park GS (eds) Diffusion in polymers, 4th edn, Academic Press, London, pp 165–217
Kondo K, Taki T (1982) Moisture diffusivity of unidirectional composites. J Compos Mater 16(2):82–93
Roy S, Singh S (2009) Analytical modelling of orthotropic diffusivities in a fiber reinforced composite with discontinuities using homogenization. Compos Sci Technol 69(11–12):1962–1967
Roy S (2012) Moisture-induced degradation. In: Pochiraju KV, Tandon GP, Schoeppner GA (eds) Long term durability of polymeric matrix composites. Springer, New York, pp 181–236
Jacques B, Werth M, Merdas I, Thominette F, Verdu J (2002) Hydrolytic ageing of polyamide 11. I. Hydrolysis kinetics in water. Polymer 43(24):6439–6447
Ravens DAS (1960) The chemical reactivity of poly(ethyelene terephthalate). Heterogeneous hydrolysis by hydrochloric acid. Polymer 1:375–383
Serpe G, Chaupart N, Verdu J (1997) Ageing of polyamide 11 in acid solutions. Polymer 38(8):1911–1917
McMahon W, Birdsall HA, Johnson GA, Camilli CJ (1959) Degradation studies of polyethylene terephthalate. J Chem Eng Data 4:57–79
Merdas I, Thominette F, Verdu J (2003) Hydrolytic ageing of polyamide 11. Effect of carbon dioxide on polyamide 11 hydrolysis. Polym Degrad Stab 79:419–425
Ballara A, Verdu J (1989) Physical aspects of the hydrolysis of polyethylene terephthalate. Polym Degrad Stab 26:361–374
Saito O (1958a) On the effects of high energy radiation to polymers. I. Crosslinking and degradation J Phys Soc (Japan) 13(2):198–206
Saito O (1958b) On the effects of high energy radiation to polymers. II. End-linking and gel fraction. J Phys Soc (Japan) 13(12):1451–1464
Launay A, Thominette F, Verdu J (1994) Hydrolysis of po1y(ethy1ene terephthalate): a kinetic study. Polym Degrad Stab 46(3):319–324
Fayolle B, Richaud E, Colin X, Verdu J (2008) Review: Degradation-induced embrittlement in semi-crystalline polymers having their amorphous phase in rubbery state. J Mater Sci 43:6999–7012
Miyagi A, Wunderlich B (1972) Etching of crystalline poly(ethylene terephthalate) by hydrolysis. J Polym Sci Part A2 Polym Phys 10:2073–2083
Pascault J-P, Sautereau H, Verdu J, Williams RJJ (2002) Thermosetting polymers. Marcel Dekker, New York
Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, New York
Di Marzio EA (1964) On the second-order transition of rubber. J Res Nat Bur Stand Sect A Phys Chem 68:611–617
Rivlin RS (1948a) Large elastic deformations of isotropic materials. I, II and III. Phil Trans Roy Soc (London) A240:459–525
Rivlin RS (1948) Large elastic deformations of isotropic materials. IV. Further developments of the general theory. Phil Trans Roy Soc (London) A241:379–397
Bellenger V, Mortaigne B, Grenier-Loustalot MF, Verdu J (1992) Structure–property relationships for styrene crosslinked polyesters. I. Network structure and rubbery elastic modulus. J Appl Polym Sci 44(4):643–651
Bellenger V, Ganem M, Mortaigne B, Verdu J (1995) Lifetime prediction in the hydrolytic ageing of polyesters. Polym Degrad Stab 49(1):91–97
Derombise G, Schoors V, Vouyovitch L, Davies P (2010) Degradation of aramid fibers under alkaline and neutral conditions: relations between the chemical characteristics and mechanical properties. J Appl Polym Sci 116(5):2504–2514
Golike RC, Lasoski SW (1960) Kinetics of hydrolysis of polyethylene terephthalate films. J Phys Chem 64:895–898
Ashbee KHG, Franck FL, Wyatt RC (1967) Water damage in polyester resins. Proc Roy Soc A300:415–419
Ashbee KHG, Wyatt RC (1969) Water damage in glass fibre/resin composites. Proc Roy Soc A312:553–564
Steel DJ (1967) Trans J Plast Inst 35:429
Van’t Hoff J (1888) The function of osmotic pressure in the analogy between solutions and gases. Philos Mag 26(5):81–105
Gautier L, Mortaigne B, Bellenger V, Verdu J (1999) Osmotic cracking nucleation in hydrothermal-aged polyester matrix. Polymer 41(7):2481–2490
Burrell PP, Herzog DJ, McCabe RT (1987) A study of permeation barriers to prevent blisters in marine composites and a novel technique for evaluating blister formation. In: Proceedings of 42nd annual conference of composite institute, the society of the plastics industry, paper 15E, Feb 2-6
Curry B (1987) The effect of gel coat composition on osmotic blister formation. In: Proceedings of 42nd annual conference of composite institute, the society of the plastics industry, paper 15A, Feb 2–6
Mortaigne B, Bellenger V, Verdu J (1991) Vieillissement hygrothermique de composites verre/polyester insaturés réticulés par le styrène, Rev Sci Techn Defense (Paris) 4ème trim., 76
Robeson LM, Crisafull ST (1983) Microcavity formation in engineering polymers exposed to hot water. J Appl Polym Sci 28:2925–2936
Rasoldier N, Colin X, Verdu J, Bocquet M, Olivier L, Chocinski-Arnault L, Lafarie-Frenot MC (2008) Model systems for thermo-oxidised epoxy composite matrices. Compos Part A 39:1522–1529
Vincent PI (1972) A correlation between critical tensile strength and polymer cross-sectional area. Polymer 13:558–560
Seitz JT (1993) The estimation of mechanical properties of polymers from molecular structure. J Appl Polym Sci 49:1331–1351
Morgan RJ, Pruneda CO, Butler N, Kong FM, Caley L, Moore RL (1984) The hydrolytic degradation of Kevlar 49 fibers. In: Proceedings of 29th national sampe symposium, Society for the Advancement of Material and Process Engineering, Reno, Nevada, , pp 891–900, April 3–5
Ghorbel I, Akélé N, Thominette F, Spiteri P, Verdu J (1995) Hydrolytic aging of polycarbonate 2: hydrolysis kinetics, effect of static stresses. J Appl Polym Sci 55(1):173–179
Philips MG (1983) Prediction of long term stress-rupture life for glass fiber-reinforced polyester composites in air and in aqueous evironements. Composites 14(3):270–275
Theberge JE (1970) In: Proceedings of 25th Annual technical conference on reinforced plastics, composites division, The Society of the Plastics Industry, paper 2D, Washington DC
Wu WL, Orts WJ, Majkrzak CJ, Hunston DL (1995) Water-adsorption at a polyimide/silicon wafer interface. Polym Eng Sci 35(12):1000–1004
Mortaigne B (1989) Vieillissement hydrolytique de polyesters insaturés réticulés par le styrène, PhD Thesis, ENSAM Paris, France
Kaelble DH, Dynes PJ, Maus L (1976) Hygrothermal ageing of composite materials. Part 1: Interfacial aspects. J Adhes 8(2):121–144
Joshi OK (1983) The effect of moisture on the shear properties of carbon fibre composites. Composites 14(3):196–200
Woo M, Piggott M (1987) Water absorption of resins and composites, Part II: diffusion in carbon and glass reinforced epoxies. J Compos Technol Res 9:162–166
Woo M, Piggott M (1988) Water absorption of resins and composites: IV. Water transport in fiber rein- forced plastics. J Compos Technol Res 10:20–24
Di Benedetto AT, Lex PJ (1989) Evaluation of surface treatments for glass fibers in composite materials. Polym Eng Sci 29(8):543–555
Serier A, Pascault JP, My LT (1991) Reactions in aminosilane-epoxy prepolymer systems. I. Kinetics of epoxy-amine reactions. J Polym Sci, Part A: Polym Chem 29:209–218
Ishida H (1984) A review of recent progress in the studies of molecular and microstructure of coupling agents and their functions in composites, coatings and adhesive joints. Polym Compos 5(2):101–123
Ishida H (1985) Structural gradient in the silane coupling agent layers and its influence on the mechanical and physical properties of composites. In: Ishida H, Kumar G (eds) Molecular characterization of composite interfaces. Plenum Press, New York, pp 25–51
Hoh KP, Ishida H, Koenig JL (1990) Multi-nuclear NMR spectroscopic and proton NMR imaging studies on the effect of water on the silane coupling agent/matrix resin interface in glass fiber-reinforced composites. Polym Compos 11(3):192–199
Johanson OK, Stark FO, Vogel GE, Fleishman RM, Flaningham OL (1968) The physical chemical nature of the matrix—glass fiber interface. In: Schwatrz E (ed) Fundamental aspects of fiber reinforced plastic composites. Interscience Publisher, New York
Rosen MR, Goddard ED (1980) FDT: a technique for direct study of water attack at the silane-fiber interface. Polym Eng Sci 20:413–425
Schradder ME, Block A (1971) Tracer study of kinetics and mechanism of hydrolytically induced interfacial failure. J Polym Sci Part C Polym Lett 34:281–291
Husman G (1976) Characterization of wet composite laminates. In: Proceedungs of Mechanical Composite., Air Force Materials Laboratory, Non Metallic Materials Division, Dayton, Ohio
McKague EL Jr, Halkias JE, Reynolds JD (1975) Moisture in composites: the effect of supersonic service on diffusion. J Compos Mater 9:2–9
Damian C, Escoubès I, Espuche E (2001) Gas and water transport properties of epoxy-amine networks: influence of crosslink density. J Appl Polym Sci 80(11):2058–2066
Sacher E, Susko JR (1979) Water permeation of polymer films. I. Polyimide. J Appl Polym Sci 23:2355–2364
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Colin, X., Verdu, J. (2014). Humid Ageing of Organic Matrix Composites. In: Davies, P., Rajapakse, Y. (eds) Durability of Composites in a Marine Environment. Solid Mechanics and Its Applications, vol 208. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-7417-9_3
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