Abstract
In this work the Cu0.91Fe0.09O nanocrystalline system was prepared via the co-precipitation method. Using Mössbauer Spectrometry, X-Ray Diffraction, Vibrating Sample Magnetometry, Thermogravimetry and Differential Scanning Calorimetry, we study the magnetic behavior, and the structural and calorimetric properties of this system. X-ray diffraction shows only the presence of the CuO structural monoclinic phase, suggesting that Cu atoms are substituted by Fe ones. This hypothesis was confirmed by Mössbauer spectrometry at room temperature, because it shows that the spectrum is formed by two doublets, which correspond to Fe+2 and Fe+3 sites. Hysteresis cycles obtained by vibrating sample magnetometry detect a soft ferromagnetic behavior at room temperature with coercive fields between 8 and 20 Oe. At T = 20 K the sample shows a hard-magnetic behavior. The thermogravimetry results show a Néel temperature (T N > 440 °C). The differential scanning calorimetry curve show two endothermic peaks in the 90–120 °C range.
Proceedings of the Thirteenth Latin American Conference on the Applications of the Mössbauer Effect, (LACAME 2012), Medellín, Columbia, 11–16 November 2012.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Batlle, X., Labarta, A.: J. Phys. D 35, R15 (2012)
Zhang, J., Liu, J., Peng, Q., Wang, X., Li, Y.: Chern. Mater. 18(4), 867–871 (2006)
Teng, F., Yao, W., Zheng, Y., Ma, Y., Teng, Y., et al.: Sens. Actuators B, Chern. 134, 761–768 (2008)
Anandan, S., Wen, X., Yang, S.: Mater. Chern. Phys. 93, 35–40 (2005)
Hsieh, C.-T., Chen, J.-M., Lin, H.-H., Shih, H.-C.: Appl. Phys. Lett. 83, 3383–3385 (2003)
Roden, B., Braun, E., Freimuth, A.: Solid State Commun. 64, 1051–1052 (1987)
Borzi, R.A., Stewart, S.J., Punte, G., et al.: J. Appl. Phys. 87, 4870–4872 (2000)
Bishta, V., Rajeeva, K.P., Banerjee, S.: arXiv:0911.1838v2 (2011)
Wolf, S.A., Awschalom, D.D., Buhrman, R.A., et al.: Sci., 294, 1488–1495 (2001)
Fukimura, T., Yamada, Y., Toyosaki, H., et al.: Appl. Surf. Sci. 223, 62–67 (2004)
Punnoose, A., Magnone, H., Seehra, M.S., Bonevich, J.: Phys. Rev. B. 64, 174420 (2001)
Rao, G.N., Yao, Y.D., Chen, J.W.: IEEE Trans. Magn. 41, 3409–3411 (2005)
Crystal lattice structures [On-Line]. http://cst-www.nrl.navy.mil/lattice/spcgrp/index.html. Accessed 5 Jan 2012
Li, Y., Xu, M., Pan, L., Zhang, Y., Guo, Z., Bi, C.: J. Appl. Phys. 107, 113908 (2010)
Yin, S.Y., Yuan, S.L., Tian, Z.M., Liu, L., Wang, C.H., Zheng, X.F., Duan, H.N., Huo, S.X.: J. Appl. Phys. 107, 043909 (2010)
Jing, Z., Qinglin, Z., Jinmin, L.: 33(013001), 1–3 (2012)
Colorado, H.D., Pérez Alcázar, G.A.: Hyperfine Interact. 202, 139–144 (2011)
Joseph, D.P., Venkateswaran, C., Vennila, R.S.: Adv. Mater. Sci. Eng. 2010, 1–4 (2010)
Teillet, J., Varret, F.: MosfitProgramm, University du Maine, unpublished, (1976)
Larson, A.C., Von Dreele, R.B.: General Structure Analysis System (GSAS), Los Alamos National Laboratory Report LAUR, pp. 86–748 (1994)
O’Handley, R.C.: Modern Magnetic Materials. Wiley, New York (1999)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Colorado, H.D., Hernandez, J.S.T., Alcázar, G.A.P., Bolaños, A. (2013). Structural, calorimetric and magnetic properties study of the Cu0,91Fe0,09O system. In: Meneses, C.A.B., Caetano, E.P., Torres, C.E.R., Pizarro, C., Alfonso, L.E.Z. (eds) LACAME 2012. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6482-8_20
Download citation
DOI: https://doi.org/10.1007/978-94-007-6482-8_20
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-6481-1
Online ISBN: 978-94-007-6482-8
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)