Skip to main content

Structure of ϵ 16 Phase in Al–Pd–Co System Studied by HREM and X-Ray Diffraction

  • Conference paper
Aperiodic Crystals
  • 961 Accesses

Abstract

A variety of orthorhombic approximant ϵ n (n=6, 16, 22, and 28)-phases exist in Al–Pd–(Mn, Fe, Co, Rh) systems. HREM images and the corresponding electron diffraction patterns show that the ϵ 16 phase in an annealed Al80Pd11Co9 alloy exhibits a locally disordered structure consisting of pentagonal and banana-shaped tiles with an edge length of 0.76 nm. This paper demonstrates a feasible structural model for the ϵ 16 phase in the Al–Pd–Co system by single-crystal X-ray diffraction coupled with HREM.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Smontara A, Smiljanić I, Bilušić A, Grushko B, Balanetskyy S, Jagličić Z, Vrtnik S, Dolinšek J (2008) Complex ϵ-phases in the Al–Pd–transition-metal systems: towards a combination of an electrical conductor with a thermal insulator. J Alloys Compd 450:92–102

    Article  CAS  Google Scholar 

  2. Balanetskyy S, Grushko B, Urban K, Velikanova TY (2005) A new rhombic approximant in the Al–Pd–Fe system. Powder Metall Met Ceram 44:282–286

    Article  Google Scholar 

  3. Balanetskyy S, Grushko B, Velikanova TY (2004) Orthorhombic ϵ-phases and transitional structures in Al–Pd–(Fe). Z Kristallogr 219:548–553

    Article  CAS  Google Scholar 

  4. Balanetskyy S, Grushko B, Velikanova TY, Urban K (2004) An investigation of the Al–Pd–Fe phase diagram between 50 and 100 at.% Al: phase equilibria at 750 C. J Alloys Compd 376:158–164

    Article  CAS  Google Scholar 

  5. Matsuo Y, Hiraga K (1994) The crystal structure of Al3Pd: close relationship to decagonal quasicrystal. Philos Mag Lett 70:155–161

    Article  CAS  Google Scholar 

  6. Boudard M, Klein H, de Boissieu M, Audier M, Vincent H (1996) Mag A 74:939–956

    Article  CAS  Google Scholar 

  7. Hiraga K, Ohsuna T, Kawasaki M (2000) The structure of an Al3Pd-based modulated structure studied by atomic-scale electron microscopy observations. J Electron Microsc 49:729–733

    Article  CAS  Google Scholar 

  8. Li M, Sun J, Oleynikov P, Hovmöller S, Zou X, Grushko B (2010) A complicated quasicrystal approximant ϵ 16 predicted by the strong-reflections approach. Acta Crystallogr, Sect B 66:17–26

    Article  CAS  Google Scholar 

  9. Yurechko M, Grushko B (2000) A study of the Al–Pd–Co alloy system. Mater Sci Eng 294–296:139–142

    Google Scholar 

  10. Yurechko M, Grushko B, Velikanova TY, Urban K (2002) Isothermal sections of the Al–Pd–Co alloy system for 50–100 at.% Al. J Alloys Compd 337:172–181

    Article  CAS  Google Scholar 

  11. Sheldrick GM (2008) A short history of SHELX. Acta Crystallogr, Sect A 64:112–122

    Article  CAS  Google Scholar 

Download references

Acknowledgements

A part of this work was supported by a Grant-in-Aid for Challenging Exploratory Research (22656152) from the Japan Society for the Promotion of Science (JSPS).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to K. Yubuta .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer Science+Business Media Dordrecht

About this paper

Cite this paper

Yubuta, K., Suzuki, S., Simura, R., Sugiyama, K. (2013). Structure of ϵ 16 Phase in Al–Pd–Co System Studied by HREM and X-Ray Diffraction. In: Schmid, S., Withers, R., Lifshitz, R. (eds) Aperiodic Crystals. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6431-6_31

Download citation

Publish with us

Policies and ethics