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Abstract

Approximately 5.2 million pounds (2.36 million kg) of pesticides were used worldwide in 2008. In the United States alone, there are sales of more than 1,055 registered active ingredients found in 16,000 pesticides. There are negative environmental and human health consequences from the use of pesticides.

In the Mediterranean region strawberries and grapes are grown and wines produced with the use of irrigation and pesticides to maximize yields and profits. Pesticide residuals including the metals they contain, have been detected in food, fruit, juices and wines. The organic chemical architecture of pesticides is quite complex and variable. Activated carbon adsorption is the best broad-spectrum treatment available for the removal of pesticides from, fruit, juices wines as well as contaminated irrigation water. Also, activated carbon is employed in wine fining protocols to produce positive quality changes.

Environmental regulations are in place or being promulgated that will necessitate the use of activated carbon treatment in the future. The viability of activated carbon use depends on the economical regeneration of the spent adsorbent. In this paper a Low Energy Chemical Regeneration Process (LECRP) will be described. The process involves the adsorption of contaminants on activated carbon followed by regeneration of the adsorbent via Fenton based oxidations. The operational parameters of the LECRP, adsorbent selection, iron amendment protocol and optimum dose, hydrogen peroxide dose and reaction temperature are discussed.

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References

  1. Analyte categories: Pesticides/herbicides. http://www.chromatography-online.org/directory/analcat-24/page.html

  2. Gilden RC, Huffling K, Sattler B (2010) Pesticides and health risks. J Obstet Gynecol Neonatal Nurs 39(1):103–110

    Article  Google Scholar 

  3. Grube A, Donaldson D, Kiely T, Wu L (2011) Pesticides industry sales and usage: 2006 and 2007 market estimates. Biological and Economic Analysis Division. Office of Pesticide Programs. Office of Chemical Safety and Pollution Prevention

    Google Scholar 

  4. CDC (2007) CDC 24/7: Saving lives. Protection people. Saving money through prevention pesticide illness & injury surveillance. http://www.cdc.gov/niosh/topics/pesticides

  5. Bkwineblog (2010) World wine production in stable in 2009. http://bkwineblog.blogspot.com_/2010/07/world-wine-productio-is-stable-in-2009.html

    Google Scholar 

  6. Morganstern A (2008) Pesticide residues found in conventional European wines. http://www.organicwinejournal.com/index.php/2008/03/pesticide-residues-found-in-conventional-european-wines/

  7. Punzi JS, Lamont M, Haynes D, Epstein RL (2005) USDA pesticide data program: pesticide residues on fresh and processed fruit and vegetables, grains, meats, milk, and drinking water. Outlooks Pestic Manag 16:131–137

    Article  Google Scholar 

  8. Harbertson JF (2008) A guide to the fining of wine. Washington State University Extension Manual EM016. Prosser IAREC

    Google Scholar 

  9. Castellari M, Versari A, Fabiani A, Parpinelli GP, Galassi S (2001) Removal of ochration A in red wines by means of adsorption treatments with commercial fitting agents. J Agric Chem 49:3917–3921

    Article  CAS  Google Scholar 

  10. EFSA (2006) European Food Safety Authority. Opinion of scientific panel contaminants in the food chain of EFSA on a request from the committee related to ochration A in food. EFSA J 365:1–56

    Google Scholar 

  11. European Commission (2006) Commision regulation (EC) No 1881/2006 December 2006 setting maximum levels for certain contaminants in foodstuck official J of the European Union 364: 5–24

    Google Scholar 

  12. Rotter RG, Frohlich AA, Marquardt RR (1989) Influence of dietary charcoal on ochratoxin, A toxicity in leghorn chicks. Can J Vet Res 53:449–453

    CAS  Google Scholar 

  13. Galvano F, Piva A, Riteni A, Galvano G (2001) Dietary strategies to counteract the effects of mycotoxins: a review. J Food Prot 64:120–131

    CAS  Google Scholar 

  14. Var I, Kabak B, Erginkaya Z (2008) Reduction in ochratoxin A levels in white wine, following treatment with activated carbon and sodium bentonite. Food Control 19(6):592–598

    Article  CAS  Google Scholar 

  15. Barron J (2008) Heavy metals and pesticides in wine. Heavy metals detox natural health Blog.http:www.jonbarron.org/detox/bl081104/naturalhealth-blog-heavy-metal-cleanse

    Google Scholar 

  16. Toles CA, Marshall WE, Johns MM (1999) Surface functional groups on acid-activated nutshell carbon. Carbon 37:1207–1214

    Article  CAS  Google Scholar 

  17. Goni R (2011) Strawberry boom in a drain on Spain. BBC News. http://www.bbc.co.uk/news/world-europe-13546715

  18. Mazzoleni V, Caldentey P, Silva A (1998) Phenolic compounds in cork used for production of wine stoppers as affected by storage and boiling cork slabs. Amer J Enol Vitic 49: 6–10. View Record in Scopus|Cited By in Scopus (13)

    Google Scholar 

  19. Vilar VJ, Maldonado MI, Oller I, Malato S, Boaventure RA (2009) Solar treatment of cork boiling and bleaching wastewaters in a pilot plant. Water Res 43(16):4052–4062, Epub 2009 Jun 16

    Article  Google Scholar 

  20. Carvalho AP, Gomes M, Mstre AS, Pires J, Carvalho MB (2004) _Carbon 667–691

    Google Scholar 

  21. Carvalho AP, Cardosa B, Pires J, Carvalho MB (2003) Carbon 41:2873–2882

    Article  CAS  Google Scholar 

  22. Huling SG, Jones PK, Lee TR (2007) Iron optimization for Fenton-driven oxidation of MTBE-spent granular activated carbon. Environ Sci Technol 41:4090–4096

    Article  CAS  Google Scholar 

  23. Kan E, Huling SG (2009) Effects of temperature and acidic pre-treatment on Fenton-driven oxidation of MTBE-spent granular activated carbon. Environ Sci Technol 43(5):1493–1499

    Article  CAS  Google Scholar 

  24. Huling SG, Kan E, Wingo C (2009) Fenton-driven regeneration of MTBE-spent granular activated carbon-effects of particle size and iron amendment procedures. J Appl Catal B Environ 89:651–657

    Article  CAS  Google Scholar 

  25. Hwang S, Huling SG, Ko S (2010) Fenton-like degradation of MTBE: effects of iron counter anion and radical scavengers. Chemosphere 78(5):563–568

    Article  CAS  Google Scholar 

  26. Pardieck DL, Bouwer EJ, Stone AT (1992) Hydrogen peroxide use to increase oxidant capacity for insitu-bioremediation of contaminated soils and aquifers: a review. J Contam Hydrol 9(3):221–224

    Article  CAS  Google Scholar 

  27. Huling SG, Arnold RG, Jones PK, Sierka RA (2000) Predicting the rate of Fenton-driven 2-chlorophe-nol transformation using a contaminant analog. J Environ Eng 126(4):348–353

    Article  CAS  Google Scholar 

  28. Huling SG, Arnold RG, Sierka RA, Miller MA (1998) Measurement of hydroxyl radical activity in a soil slurry using the spin trap a-(4-Pyridyl-1-oxide)-N-tert-butylnitrone. Environ Sci Technol 32(21):3436–3441

    Article  CAS  Google Scholar 

  29. Huling SG, Arnold RG, Sierka RA, Miller MA (2001) Influence of peat on Fenton oxidation. Water Res 35(7):1687–1694

    Article  CAS  Google Scholar 

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Correspondence to Raymond A. Sierka .

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Sierka, R.A. (2013). Activated Carbon Adsorption and Chemical Regeneration in the Food Industry. In: Coca-Prados, J., Gutiérrez-Cervelló, G. (eds) Economic Sustainability and Environmental Protection in Mediterranean Countries through Clean Manufacturing Methods. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-5079-1_5

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