Abstract
Billions tons of particulate matter, made up of inorganic and organic compounds, are released every year into the atmosphere, from both anthropogenic and natural sources. The latter, which include geogenic material from erosion, agriculture, sea spray and volcanic activity, account for about 97% of the total mass of particles. The contribution of anthropogenic sources, about 3%, is more pronounced in industrialised and also in urban areas, where vehicular traffic is one of the most important sources. When examining the health impact, in addition to mass level and size, two other main characteristics of particulate matter need to be considered: its nature and chemical composition. These parameters appear intrinsically related to one another. Presence, abundance and behaviour of trace metals in air are also closely related to atmospheric particulate matter, as most metals in the lower atmosphere are present in association with particles. Most of these aspects are presented and discussed in this present chapter as only a better knowledge of atmospheric particulate matter, its composition, metal content and some implications on the human health, may aid to select correct actions and appropriate control strategies.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Andreae MO, Rosenfeld D (2008) Aerosol–cloud–precipitation interactions. Part 1. The nature and sources of cloud-active aerosols. Earth Sci Rev 89:13–41
Ashraf W, Jaffar M, Mohammad D (1994) Trace metal contamination study on scalp hair of occupationally exposed workers. Bull Environ Contam Toxicol 53:516–523
Bache CA, Lisk DJ, Scarlett JM, Carbone LG (1991) Epidemiologic study of cadmium and lead in the hair of ceramists and dental personnel. J Toxicol Environ Health 34:423–431
Batzevich VA (1995) Hair trace element analysis in human ecology studies. Sci Total Environ 164:89–98
Berner EK, Berner RA (1996) Global environment: water, air and geochemical cycles. Prentice Hall, Old Tappan, p 376
Breysse P, Lees PSJ (2006) Particulate matter. The Johns Hopkins University http://ocw.jhsph.edu/courses/PrinciplesIndustrialHygiene/PDFs/Lecture4.pdf. Accessed 30 May 2012
Buseck PR, Adachi K (2008) Nanoparticles in the atmosphere. Elements 4:389–394
CEC (2005) Communication from the Commission to the Council and the European Parliament. Thematic Strategy on air pollution. Commission of the European Communities
CEN (1993) Workplace atmospheres. Size fraction definitions for measurement of airborne particles European Committee for Standardization, British Standard Institute, Great Britain, BS EN 481:1993
Chester R (2000) Marine geochemistry. Blackwell Publishing, New York, p 506
Chiarenzelli J, Aspler L, Dunnet L (2001) Multi-element and rare earth element composition of lichens, mosses and vascular plants from the central Barrenlands, Nunavut, Canada. Appl Geochem 16:245–270
Chojnacka K, Górecka H, Chojnacki A, Górecki H (2005) Inter-element interactions in human hair. Environ Toxicol Pharmacol 20:368–374
Chojnacka K, Górecka H, Chojnacki A, Górecki H (2006a) The effect of age, sex, smoking habit, hair color on the composition of hair. Environ Toxicol Pharmacol 22:52–57
Chojnacka K, Górecka H, Górecki H (2006b) The influence of living habits and family relationships on element concentrations in human hair. Sci Total Environ 366:612–620
Chojnacka K, Michalak I, Zieńliska A, Górecka H, Górecki H (2010a) Inter-relationship between elements in human hair: the effect of gender. Ecotoxicol Environ Saf 73:2022–2028
Chojnacka K, Zieńliska A, Dobrzanski HGZ, Górecki H (2010b) Reference values for hair minerals of Polish students. Environ Toxicol Pharmacol 29:314–319
D’Ilio S, Violante N, Senofonte O, Caroli S (2000) Occupational exposure of goldsmith workers of the area of Rome to potentially toxic metals as monitored through hair analysis. J Microchem 67:343–349
De Prisco PP, Volpe MG, Petitto F, Palladino C, Saturnino C, Capasso A, Di Stasio M, De Prisco R (2010) Level of essential and toxic metals in urban adolescents hair: preliminary study. Biomed Res 21:131–140
Dongarrà G, Varrica D (1998) The presence of heavy metals in air particulate at Vulcano island (Italy). Sci Total Environ 212:1–9
Dongarrà G, Ottonello D, Sabatino G, Triscari M (1995) Use of lichens in detecting environmental risk and in geochemical prospecting. Environ Geol 26:139–146
Dongarrà G, Sabatino G, Triscari M, Varrica D (2003) The effects of anthropogenic particulate emissions on roadway dust and Nerium oleander leaves in Messina (Sicily, Italy). J Environ Monit 5:766–773
Dongarrà G, Manno E, Varrica D, Vultaggio M (2007) Mass levels, crustal component and trace elements in PM10 in Palermo, Italy. Atmos Environ 41:7977–7986
Dongarrà G, Manno E, Varrica D (2009) Possible markers of traffic-related emissions. Environ Monit Assess 154:117–125
Dongarrà G, Manno E, Varrica D, Lombardo M, Vultaggio M (2010) Study on ambient concentrations of PM10, PM10–2.5, PM2.5 and gaseous pollutants. Trace elements and chemical speciation of atmospheric particulates. Atmos Environ 44:27–34
Dongarrà G, Varrica D, Tamburo E, D’Andrea D (2012) Trace elements in scalp hair of children living in differing environmental contexts in Sicily (Italy). Environ Toxicol Pharmacol 34:160–169
Doucet FJ, Carignan J (2001) Atmospheric isotopic composition and trace metal concentration as revealed by epiphytic lichens. Atmos Environ 35:3681–3690
Durant AJ, Bonadonna C, Horwell CJ (2010) Atmospheric and environmental impacts of volcanic particulates. Elements 6:235–240
EPA (2005) Final staff paper recommends stronger particle pollution standards. http://yosemite.epa.gov/opa/admpress.nsf/d9bf8d9315e942578525701c005e573c/7a82ddc6d0b37f65852570310065bdfc. Accessed 30 May 2012
Ercal N, Gurer-Orhan H, Aykin-Burns N (2001) Toxic metals and oxidative stress part I: mechanisms involved in metal-induced oxidative damage. Curr Top Med Chem 1:529–539
Erel Y, Axelrod T, Veron A, Mahrer Y, Katsafados P, Dayan U (2002) Transboundary atmospheric lead pollution. Environ Sci Technol 36:3230–3233
Erel Y, Dayan U, Rabi R, Rudich Y, Stein M (2006) Trans boundary transport of pollutants by atmospheric mineral dust. Environ Sci Technol 40:2996–3005
Feng XD, Dang Z, Huang WL, Yang C (2009) Chemical speciation of fine particle bound trace metals. Int J Environ Sci Technol 6:337–346
Gierè R, Querol X (2010) Solid particulate matter in the atmosphere. Elements 6:215–222
Goldoni M, Caglieri A, Poli D, Vettori M, Corradi M, Apostoli P, Mutti A (2006) Determination of hexavalent chromium in exhaled breath condensate and environmental air among chrome plating workers. Anal Chim Acta 562:229–235
Gomez DR, Ginè MF, Sánchez Bellato AC, Smichowski P (2005) Antimony: a traffic-related in the atmosphere of Buenos Aires, Argentina. J Environ Monit 7:1162–1168
Grousset FE, Biacaye PE (2005) Tracing dust sources and transport patterns using Sr, Nd and Pb isotopes. Chem Geol 222:149–167
Güllü G, Doğan G, Tuncel G (2005) Atmospheric trace element and major ion concentrations over the eastern Mediterranean Sea: identification of anthropogenic source regions. Atmos Environ 39:6376–6387
Heal MR, Hibbs LR, Agius RM, Beverland IJ (2005) Total and water-soluble trace metal content of urban background PM10, PM2.5 and black smoke in Edinburgh, UK. Atmos Environ 39:1417–1430
Hess M, Koepke P, Schult I (1998) Optical properties of aerosols and clouds. Bull Am Meteorol Soc 79:831–844
Houghton JT, Meira Filho LG, Callander BA, Harris N, Kattenberg A, Maskell K (1996) Climate change 1995. The Science of Climate Change, Contribution of working Group I to the second Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge University Press, Cambridge
Huggins FE, Shah N, Huffman GP, Robertson JD (2000) XAFS spectroscopic characterization of elements in combustion ash and fine particulate matter. Fuel Process Technol 65–66:203–218
ICRP (1994) International Commission on Radiological Protection: human respiratory model for radiological protection. Ann ICRP 24:1–300
Junge C (1979) The importance of mineral dust as an atmospheric constituent. In: Morales C (ed) Saharan dust. Wiley, New York, pp 243–266
Kawata K, Yokoo H, Shimazaki R, Okabe S (2007) Classification of heavy metal toxicity by human DNA microarray analysis. Environ Sci Technol 41:3769--3777
Kempson IM, Lombi E (2011) Hair analysis as a biomonitor for toxicology, disease and health status. Chem Soc Rev 40:3915–3940
Komárek M, Ettler V, Chrastný V, Mihaljevič M (2008) Lead isotopes in environmental sciences: a review. Environ Int 34:562–577
Lahd Geagea M, Stille P, Gauthier-Lafaye F, Millet M (2008) Tracing of industrial aerosol sources in an urban environment using Pb, Sr, and Nd isotopes. Environ Sci Technol 42:692–698
Lee WC, Lee MJ, Lee SM, Kim JS, Bae CS, Park TK (2000) An observation on the mercury contents of scalp hair in the urban residents of South Korea. Environ Toxicol Pharmacol 8:275–278
Lippmann M, Ito K, Hwang J-S, Maciejczyk P, Chen L-C (2006) Cardiovascular effects of nickel in ambient air. Environ Health Perspect 114:1662–1669
Manders AMM, Schaap M, Querol X, Albert MFMA, Vercauteren J, Kuhlbusch TAJ, Hoogerbrugge R (2010) Sea salt concentrations across the European continent. Atmos Environ 44:2434–2442
Manno E, Varrica D, Dongarrà G (2006) Metal distribution in road dust samples collected in an urban area close to a petrochemical plant at Gela, Sicily. Atmos Environ 40:5929–5941
Marconi A (2003) Materiale particellare aerodisperso: definizioni, effetti sanitari, misura e sintesi delle indagini ambientali effettuate a Roma. Ann Ist Super Sanita 39:329–342
Nieboer E, Thomassen Y, Chashchin V, Odland JO (2005) Occupational exposure assessment of metals. J Environ Monit 7:411–415
Nordberg M, Cherian MG (2005) Biological responses of elements. In: Selinus O (ed) Essential of medical geology. Elsevier Academic Press, San Diego
Nowak B, Chmielnicka J (2000) Relationship of lead and cadmium to essential elements in hair, teeth, and nails of environment exposed people. Ecotoxicol Environ Saf 46:265–274
Nriagu JO (1979) Global inventory of natural and anthropogenic emissions of trace metals to the atmosphere. Nature 279:409–411
Nriagu JO (1990) Global metal pollution. Environment 32:7–33
Penner-Hahn JE (1999) X-ray absorption spectroscopy in coordination chemistry. Coord Chem Rev 190–192:1101–1123
Plant JA, Kinniburg DG, Smedley PL, Fordyce FM, Klinck BA (2005) Arsenic and selenium. In: Holland HD, Turekian KK (eds) Treatise on geochemistry, vol 9. Elsevier Ltd, Amsterdam, pp 17–66
Pöschl U (2005) Atmospheric aerosols: composition, transformation, climate and health effects. Angew Chem Int Ed 44:7520–7540
Putaud JP, Raes F, Van Dingenen R et al (2004) A European aerosol phenomenology – 2: chemical characteristics of particulate matter at kerbside, urban, rural and background sites in Europe. Atmos Environ 38:2579–2595
Putaud JP, Van Dingenen R, Alastuey A et al (2010) A European aerosol phenomenology – 3: Physical and chemical characteristics of particulate matter from 60 rural, urban, and kerbside sites across Europe. Atmos Environ 44:1308–1320
Rao CRM, Sahuquillo A, Lopez Sanchez JF (2008) A review of the different methods applied in environmental geochemistry for single and sequential extraction of trace elements in soils and related materials. Water Air Soil Pollut 189:291–333
Rasmussen PE (1998) Long-range atmospheric transport of trace metals: the need for geosciences perspectives. Environ Geol 33:96–108
Reimann C, De Caritat P (2000) Intrinsic flaws of element enrichment factors (Efs) in environmental geochemistry. Environ Sci Technol 34:5084–5091
Samontha A, Waiyawat W, Shiowatana J, McLarenb RG (2007) Atmospheric deposition of metals associated with air particulate matter: fractionation of particulate-bound metals using continuous-flow sequential extraction. Sci Asia 33:421–428
Sanna E, Liguori A, Palmas L, Renata Soro M, Floris G (2003) Blood and hair lead levels in boys and girls living in two Sardinian towns at different risks of lead pollution. Ecotoxicol Environ Saf 35:248–252
Sanna E, Floris G, Vallascas E (2008) Town and gender effects on hair lead levels in children from three Sardinian towns (Italy) with different environmental backgrounds. Biol Trace Elem Res 124:52–59
Sanna E, De Micco A, Vallascas E (2011) Evaluation of association between biomarkers of lead exposure in Sardinian children (Italy). Biol Trace Elem Res 143:1383–1392
Seinfeld JH, Pandis SN (1998) Atmospheric chemistry and physics: from air pollution to climate change. Wiley, New York
Smichowski P (2008) Antimony in the environment as a global pollutant: a review on analytical methodologies for its determination in atmospheric aerosols. Talanta 75:2–14
Smichowski P, Polla G, Gómez D (2005) Metal fractionation of atmospheric aerosols via sequential chemical extraction: a review. Anal Bioanal Chem 381:302–316
Spurny KR (2000) Aerosol chemistry and its environmental effects. In: Spurny KR (ed) Aerosol chemical processes in the environment. Lewis Publishers, Boca Raton/London/New York/Washington, DC
Sternbeck J, Sjödin A, Andréasson K (2002) Metal emissions from road traffic and the influence of resuspension-results from two tunnel studies. Atmos Environ 36:4735–4744
Templeton DM, Ariese F, Cornelis R, Danielsson LG, Muntau H, Van Leeuwen HP, Łobiński R (2000) Guidelines for terms related to chemical speciation and fractionation of elements. Definitions, structural aspects, and methodological approaches (Iupac Recommendations 2000). Pure Appl Chem 72:1453–1470
Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51:844–851
Valko M, Morris H, Cronin MTD (2005) Metals, toxicity and oxidative stress. Curr Med Chem 12:1161–1208
Varrica D, Aiuppa A, Dongarrà G (2000) Volcanic and anthropogenic contribution to heavy metal content in lichens from Mt. Etna and Vulcano island (Sicily). Environ Pollut 108:153–162
Varrica D, Bardelli F, Dongarrà G, Tamburo E (2013) Speciation of Sb in airborne particulate matter, vehicle brake linings, and brake pad wear residues. Atmos Environ 64:18--24
Vincent JH (2007) Aerosol sampling: science, standards, instrumentation and applications. Wiley, New York
Violante N, Senofonte O, Marsili G, Meli P, Soggiu ME, Caroli S (2000) Human hair as a marker of pollution by chemical elements emitted by a thermoelectric power plant. J Microchem 67:397–405
Wang Y, Li A, Zhan Y, Wei L, Li Y, Zhang G, Xie Y, Zhang J, Zhang Y, Shan Z (2007) Speciation of elements in atmospheric particulate matter by XANES. J Radioanal Nucl Chem 273:247–251
WHO (1999) Air quality guidelines for Europe, 2nd edn. WHO Regional Office for Europe, Copenhagen, 1999
Wiseman CLS, Zereini F (2010) Airborne particulate matter: sources, composition and concentration. In: Zereini F, Wiseman CLS (eds) Urban airborne particulate matter origin, chemistry, fate and health impacts. Springer, Berlin/Heidelberg, pp 1–2, 26, part I
Zereini F, Alt F (2000) Anthropogenic platinum-group-element emissions: their impact on man and environment. Springer, Berlin/Heidelberg/New York
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer Science+Business Media Dordrecht.
About this chapter
Cite this chapter
Dongarrà, G., Tamburo, E., Varrica, D. (2013). Dust, Metals and Metalloids in the Environment: From Air to Hair. In: Censi, P., Darrah, T., Erel, Y. (eds) Medical Geochemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-4372-4_8
Download citation
DOI: https://doi.org/10.1007/978-94-007-4372-4_8
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-4371-7
Online ISBN: 978-94-007-4372-4
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)