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Environmental Chemistry for a Sustainable World pp 47–81Cite as

Cyclodextrins for Remediation Technologies

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Part of the book series: Environmental Chemistry for a Sustainable World ((ECSW))

Abstract

Human activity and the modern way of life are responsible for the increase of environmental pollution. Industrial processes generate many substances that pollute air, water and soils with negative impacts for ecosystems and humans. The development of innovative remediation technologies has thus emerged as a significant environmental priority. Supramolecular chemistry can provide promising remediation methods to solve pollution issues. In particular, cyclodextrins (CDs) are a family of cyclic oligosaccharides that are composed of α-1,4-linked glucopyranose subunits. Cyclodextrins have thus a low-polarity cavity in which organic pollutants of appropriate shape and size can form inclusion complexes. This unique property makes cyclodextrins suitable for application in environmental protection by pollutant trapping. Accordingly, the present review lists the advantages of using cyclodextrins in soil, groundwater, wastewater and atmosphere remediation. The inclusion mechanism have been used in soil, water and air, either as solubilizing agent when the cyclodextrin is diluted in aqueous solution, or as trapping agent when cyclodextrin is immobilized on various supports. Resulting processes are highly versatile, since the complexing ability of cyclodextrins includes a wide range of pollutants. Remediation using cyclodextrins is a green processe due to cyclodextrins innocuity. Moreover, since inclusion involves reversible equilibriums, a major trend in the cyclodextrin environmental application field is to develop methods that combine both supramolecular chemistry and irreversible processes such as advanced oxidation or biodegradation. Such processes could lead to a complete remediation of pollutants and to cyclodextrin recycling.

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    David Landy, Isabelle Mallard & Sophie Fourmentin

  2. Unité de Catalyse et de Chimie du solide (UMR 8181), Université d’Artois, Faculté Jean Perrin, Rue Jean Souvraz - SP 18, 62307, Lens Cedex, France

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Landy, D., Mallard, I., Ponchel, A., Monflier, E., Fourmentin, S. (2012). Cyclodextrins for Remediation Technologies. In: Lichtfouse, E., Schwarzbauer, J., Robert, D. (eds) Environmental Chemistry for a Sustainable World. Environmental Chemistry for a Sustainable World. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-2442-6_2

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