Abstract
A theory of electronic transitions from a non-degenerated to a two-fold degenerated or quasi-degenerated electronic state in an impurity centre of a crystal is proposed. The coupling of optical electron(s) with non-totally symmetrical vibration(s) and with phonons are taken into account. The latter interaction results in the replacement of vibronic lines by phonon-assisted bands. The widths of bands, the rates of the energy relaxation of vibronic states and the shapes of optical spectra are calculated for some values of parameters.
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Acknowledgements
The research was supported by the ETF grants TLOFY0145 and GLOFY7741.
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Hizhnyakov, V., Pae, K., Vaikjärv, T. (2011). Vibronic Transitions to a State with Jahn-Teller Effect: Contribution of Phonons. In: Atanasov, M., Daul, C., Tregenna-Piggott, P. (eds) Vibronic Interactions and the Jahn-Teller Effect. Progress in Theoretical Chemistry and Physics, vol 23. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-2384-9_9
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