Abstract
Although the first attempts to apply electrolyzed aqueous solutions for water disinfection were performed in Russia in the late nineteenth century, the deficiencies in construction of electrolyzers and stability of electrodes did not allow for their broad practical use. The developments in technology and design led to applications of electrolyzed aqueous solutions in the former USSR starting from the 1960s. At present, this technology is being developed in numerous countries around the world. It is reflected in an increased number of publications in peer-reviewed journals and other information sources. Moreover, a number of companies were established to pursue commercialization of the technology. The possibility of their use as power disinfectants of potable water and swimming pools, bactericidal agents for disinfection and sterilization of living tissues, materials, medical and food processing equipment, etc. have been demonstrated in various trials. However, the broader application of the technology is hindered by the lack of profound theoretical and experimental studies of production of electroactivated aqueous solutions and the mechanisms of their activity. In particular, the interrelation between technological and constructional characteristics of the apparatus and functional properties of produced solutions is most poorly understood. We offer an array of figures-of-merit allowing a fair comparison between the electrolyzers of different design.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Anonymous (1999) Electrochemical activation in medicine, agriculture, and industry. Proceedings of the 2nd international symposium, Moscow
Anonymous (1998) Cleaning and disinfection of equipment for gastrointestinal endoscopy. Report of a working party of the British Society of Gastroenterology Endoscopy Committee. Gut 42:585–593
Anonymous (2010) Puricore. Pure science. Pure life. http://www.puricore.com/. Accessed 2 June 2010
Aoki H, Nakamori M, Aoto N et al (1994) Wafer treatment using electrolysis-ionized water. Jp J Appl Phys 10:5686–5689
Bahir V (1996) Electrochemical activation: a strategy for creation of environmentally benign technologies. Activated Water Moscow 1:1–7
Balakhnin IA, Davydov ON, Kurovskaya LY (1994) The influence of Katolyt on the quantity of carp’s ectoparasites. Gidrobiologicheskii Zh 30:83–86
Basha CA, Bhadrinarayana NS, Anantharaman N et al (2008) Heavy metal removal from copper smelting effluent using electrochemical cylindrical flow reactor. J Hazard Mater 152:71–78
Bazaz’ian AG, Kozlovskaia LA, Zakharova TB et al (1998) Prophylactic disinfection of railway stations and cars by using electrolytic sodium hypochlorite. Gig Sanit 3:37–39
Bird R, Stewart V, Lightfoot E (1974) Yavlenia perenosa. Khimiya, Moscow
Cherkinskii SN, Laskina VP, Petranovskaia MR et al (1980) Hygienic evaluation of the method of water disinfection by direct electrolysis. Gig Sanit 11:72–73
Chizmadjev YuA, Markin VS, Tarasevich MR et al (1971) Macrokinetics of processes in porous media. Nauka, Moscow
Cooke P (1999) Treatment of biofilm on marine seismographic equipment. Radical Waters (PTY) Ltd Patent WO/1999/IB99/01697(WO/024432A1)
Davydov ON, Kurovskaya LY, Balakhnin IA (1997) Influence of catholyte on the activity of enzymes from carp eggs and embryos. Dopovidi Nat Akad Nauk Ukrayiny 4:164–168
Gutknecht J, Hartmann F, Kirmair N et al (1981) Anodic oxidation as a water disinfecting process in food plants and breweries. GIT Fachz Lab 25:472–481
Hata G, Uemura M, Weine FS et al (1996) Removal of smear layer in the root canal using oxidative potential water. J Endod 22:643–645
Hayashi H (2009) Why drink alkaline ionized water? http://www.ionizers.org/water.html. Accessed 31 May 2010
Hayashi H (1995) Water, the chemistry of life. Part IV. Explore! 6:28–31
Hayashi H, Kumon K, Nl Y et al (1997) Successful treatment of mediastinitis after cardiovascular surgery using electrolyzed strong acid aqueous solution. Artif Organs 21:39–42
Hinze GT (1999) Bactericidal treatment of sausage casings. Radical Waters (PTY) Ltd. Patent WO/1999/IB99/01695(WO/024265A1) 1–14
Hitomi S, Baba S, Yano H et al (1998) Antimicrobial effects of electrolytic products of sodium chloride – comparative evaluation with sodium hypochlorite solution and efficacy in handwashing. Kansenshogaku Zasshi 72:1176–1181
Horiba N, Hiratsuka K, Onoe T et al (1999) Bactericidal effect of electrolyzed neutral water on bacteria isolated from infected root canals. Oral Surg Oral Med Oral Pathol Oral Radiol Endod 87:83–87
Hotta K (2000) Electrolytic functional water and healthy life. Nippon Nogeikagaku Kaishi J Jpn Soc Biosci Biotechnol Agrochemistry 74:795–798
Inoue Y, Endo S, Kondo K et al (1997) Trial of electrolyzed strong acid aqueous solution lavage in the treatment of peritonitis and intraperitoneal abscess. Artif Organs 21:28–31
Ioirish AN, Artem’ev ET, Mazanko AF et al (1990) ELMA-1 electrochemical apparatus for making sodium hypochlorite solutions: use in medical institutions. Biomed Eng 24:85–87
Ito K, Nishida T, Murai S (1996) Inhibitory effects of acid water prepared by an electrolysis apparatus on early plaque formation on specimens of dentine. J Clin Periodontol 23:471–476
Iwasawa A, Nakamura Y (1996) Bactericidal effect of acidic electrolyzed water–comparison of chemical acidic sodium hydrochloride (NaOCl) solution. Kansenshogaku Zasshi 70:915–922
Izumi H (1999) Electrolyzed water as a disinfectant for fresh-cut vegetables. J Food Prot 64:536–539
Kim C, Hung YC, Brackett RE (2000) Roles of oxidation-reduction potential in electrolyzed oxidizing and chemically modified water for the inactivation of food-related pathogens. J Food Prot 63:19–24
Kirpichnikov PA, Bakhir VM, Hamer PU et al (1986) On the nature of electrochemical activation of media. Dokl Acad Nauk USSR Russ 286:663–667
Kloss AI (1988) Electron-radical dissociation and mechanism of water activation. Dokl Acad Nauk USSR Russ 303:1403–1406
Kreysa G (1985) Performance criteria and nomenclature in electrochemical engineering. J Appl Electrochem 15:175–179
Kreysa G (1981) Normalized space velocity – a new figure of merit for waste water electrolysis cells. Electrochim Acta 26:1693–1694
Kumon K (1997) What is functional water? Artif Organs 21:2–4
Lelianov AD, Grachev AM, Sergienko VI et al (1991) The use of an electrolytic solution of sodium hypochlorite in acute suppurative diseases of the soft tissues. Klin Khir 12:16–19
Lysyi AE, Anchishkina LM, Suslova VN et al (1993) Effectiveness of an electrolysis unit for decontamination of biologically purified sewage waters. Gig Sanit 2:19–20
Middleton AM, Chadwick MV, Sanderson JL et al (2000) Comparison of a solution of super-oxidized water (Sterilox) with glutaraldehyde for the disinfection of bronchoscopes, contaminated in vitro with Mycobacterium tuberculosis and Mycobacterium avium-intracellulare in sputum. J Hosp Infect 45:278–282
Miroshnikov AI (1998) Inhibition of growth of E. coli cells by anolites of sodium and potassium chloride after processing solutions in a diaphragmatic electrolyzer. Biofizika 43:1032–1036
Miyamoto M, Inoue K, Hoki M et al (1998) Effect of “acidic oxidative potential water” on microbial contamination harvesting porcine pancreas for islet xenotransplantation. Transplant Proc 30:3431–3432
Morita C, Sano K, Morimatsu S et al (2000) Disinfection potential of electrolyzed solutions containing sodium chloride at low concentrations. J Virol Meth 85:163–174
Nakae H, Inaba H (2000) Effectiveness of electrolyzed oxidized water irrigation in a burn-wound infection model. J Trauma 49:511–514
Nelson D (2000) Newer technologies for endoscope disinfection: electrolyzed acid water and disposable-component endoscope systems. Gastrointest Endosc Clin N Am 10:319–328
Nikulin VA (1977) Use of an electrolyzed sodium chloride solution for disinfection in therapeutic and prophylactic institutions. Sov Med 12:105–108
Nishida T (1997) The effect of oxidizing water on metallic restorations in the mouth: in vitro reduction behavior of oxidizing water. J Nihon Univ Sch Dent 39:38–48
Ogino H, Ueda Y, Sugita T et al (2000) Treatment for abdominal aortic graft infection: irrigation with electrolyzed strong aqueous acid, in-situ grafting, and omentoplasty. Thorac Cardiovasc Surg 48:43–44
Petrosian EA (1993) Sodium hypochlorite in the treatment of suppurative peritonitis. Vestn Khir Im II Grek 150:18–21
Petrushanko IYu, Lobyshev VI (2001) Nonequilibrium state of electrochemically activated water and its bilogical activity. Biofizika 46:389–401
Prilutskii VI and Bakhir VM (1997) Electrochemically activated water: anomalous characteristics, mechanisms of biological action. Nauka, Moscow
Prilutskii VI, Bakhir VM, Popov AI (1996) The disinfection of water, water-supply systems, tanks and pools by using an electrochemically activated solution of a neutral anolyte. Vopr Kurortol Fizioter Lech Fiz Kult 4:31–32
Raghu S, Basha CA (2007) Electrochemical treatment of procion black 5B using cylindrical flow reactor – A pilot plant study. J Hazard Mat B139:381–390
Ross TK, Wragg AA (1965) Electrochemical mass transfer studies in annuli. Electrochim Acta 10:1093–1106
Sasai-Takedatsu M, Kojima T, Yamamoto A et al (1997) Reduction of Staphylococcus aureus in atopic skin lesions with acid electrolytic water-a new therapeutic strategy for atopic dermatitis. Allergy 52:1012–1016
Sato T, Tanaka T, Ohya H (1989) Bactericidal effect of an electrodialysis system on E. coli cells. Bioelectrochem Bioenerg 21:47–54
Schwab H, Strauch D, Muller W (1975) Hygienic differentiation of technical processes in handling liquid drug. 2. Examination of the Electro-M process using laboratory standards. Berl Münch Tierärztl Wochenschr 88:148–151
Sekiya S, Ohmori K, Harii K (1997) Treatment of infectious skin defects or ulcers with electrolyzed strong acid aqueous solution. Artif Organs 21:32–38
Selkon JB, Babb JR, Morris R (1999) Evaluation of the antimicrobial activity of a new super-oxidized water, Sterilox, for the disinfection of endoscopes. J Hosp Infect 41:59–70
Sergunina LA (1968) An effective method of electrolysis for decontamination of drinking water. Gig Sanit 33:16–21
Shiba A, Ozeki M, Takizawa H (1996) Is it possible for electrolyzed acid water to be applied to the dental region? J Showa Univ Dent Soc 16:457–464
Shimizu Y, Furusawa T, Mizunuma K et al (1994) Disinfectant action of electrolyzed oxidizing water to dental instruments and finger. J Dent Med 40:905–911
Shimmura S, Matsumoto K, Yaguchi H et al (2000) Acidic electrolysed water in the disinfection of the ocular surface. Exp Eye Res 70:1–6
Shirahata S, Kabayama S, Nakano M (1997) Electrolyzed-reduced water scavenges active oxygen species and protects DNA from oxidative damage. Biochem Biophys Res Commun 234:269–274
Shura-Bura BL, Gritsenko VK (1968) Substantiation of the rationale of the use of electrolyzed sea water for disinfection. Voen Med Zh 7:47–51
Stoner GE, Cahen GL, Sachyani M, Gileady E (1982) The mechanism of low frequency a.c. electrochemical disinfection. Bioelectrochem Bioenerg 9:229–243
Tanaka H, Hirakata Y, Kaku M et al (1996) Antimicrobial activity of superoxidized water. J Hosp Infect 34:43–49
Tanaka N, Fujisawa T, Daimon T et al (1999) The cleaning and disinfecting of hemodialysis equipment using electrolyzed strong acid aqueous solution. Artif Organs 23:303–309
Tanaka N, Fujisawa T, Daimon T et al (1999) The effect of electrolyzed strong acid aqueous solution on hemodialysis equipment. Artif Organs 23:1055–1062
Tsuji S, Kawano S, Oshita M et al (1999) Endoscope disinfection using acidic electrolytic water. Endoscopy 31:528–535
Usviatsov BI, Kirillichev AI, Voronina LG (1997) The suppressive action of a magnetic-laser ray and of an electrolytic solution of sodium hypochlorite on the factors of causative agent persistence. Zh Mikrobiol Epidemiol Immunobiol 4:102–105
Venkitanarayanan KS, Ezeike GO, Hung YC et al (1999) Inactivation of Escherichia coli O157:H7 and Listeria monocytogenes on plastic kitchen cutting boards by electrolyzed oxidizing water. J Food Prot 62:857–860
Walsh FS (2001) Electrochemical technology for environmental treatment and clean energy conversion. Pure Appl Chem 73:1819–1837
Walsh FS, Reade G (1994) Design and performance of electrochemical reactors for efficient synthesis and environmental treatment. Part 1. Electrode geometry and figures of merit. Analyst 119:791–796
Watanabe T, Kishikawa Y, Shirai W (1997) Influence of alkaline ionized water on rat erythrocyte hexokinase activity and myocardium. J Toxicol Sci 22:141–152
Wilk IJ, Altmann RS, Berg JD (1987) Antimicrobial activity of electrolyzed saline solutions. Sci Total Environ 63:191–197
Yang Z, Li Y, Slavik MF (1999) Antibacterial efficacy of electrochemically activated solution for poultry spraying and chilling. J Food Sci 64:469–472
Zahn M (1979) Electromagnetic field theory: a problem solving approach. John Wiley & Sons, New York
Zinkevich V, Beech IB, Tapper R et al (2000) The effect of super-oxidized water on Escherichia coli. J Hosp Infect 46:153–156
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2011 Springer Science+Business Media B.V.
About this paper
Cite this paper
Gnatko, E.N., Kravets, V.I., Leschenko, E.V., Omelchenko, A. (2011). Emergence of the Science and Technology of Electroactivated Aqueous Solutions: Applications for Environmental and Food Safety. In: Alpas, H., Berkowicz, S., Ermakova, I. (eds) Environmental Security and Ecoterrorism. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-1235-5_8
Download citation
DOI: https://doi.org/10.1007/978-94-007-1235-5_8
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-007-1234-8
Online ISBN: 978-94-007-1235-5
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)