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Metal Fulleride Salts: Prototypes of Highly Correlated Molecular Systems

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Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics

Part of the book series: NATO Science Series ((NAII,volume 139))

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Abstract

Metal fiilleride salts are highly-correlated systems, which display a remarkable sensitivity of their structural and electronic properties on many chemically and physically tunable parameters, including interfullerene separation, orientational order/disorder, valence state, orbital degeneracy, low-symmetry distortions and metal- C60 interactions. In this chapter, we discuss some key issues of current research on fiillerene-based materials, including the metal-antiferromagnetic insulator transition at large interfullerene separations, the tuning of the electronic and magnetic properties by weak intermolecular interactions and the intermediate valence behaviour of rare-earth fullerides.

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK

    Serena Margadonna

  2. Department of Chemistry, University of Sussex, Brighton BN1 9QJ, UK

    Kosmas Prassides

Authors
  1. Serena Margadonna
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  2. Kosmas Prassides
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Editors and Affiliations

  1. Laboratoire de Chimie du Solide et Inorganique Moléculaire, LCSIM, UMR CNRS 6511, Institut de Chimie de Rennes, Université de Rennes, Rennes Cedex, France

    Lahcène Ouahab

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    Eduard Yagubskii

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© 2004 Springer Science+Business Media Dordrecht

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Margadonna, S., Prassides, K. (2004). Metal Fulleride Salts: Prototypes of Highly Correlated Molecular Systems. In: Ouahab, L., Yagubskii, E. (eds) Organic Conductors, Superconductors and Magnets: From Synthesis to Molecular Electronics. NATO Science Series, vol 139. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-1027-6_10

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  • DOI: https://doi.org/10.1007/978-94-007-1027-6_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-1942-5

  • Online ISBN: 978-94-007-1027-6

  • eBook Packages: Springer Book Archive

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