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Metal Fulleride Salts: Prototypes of Highly Correlated Molecular Systems

  • Serena Margadonna
  • Kosmas Prassides
Conference paper
Part of the NATO Science Series book series (NAII, volume 139)

Abstract

Metal fiilleride salts are highly-correlated systems, which display a remarkable sensitivity of their structural and electronic properties on many chemically and physically tunable parameters, including interfullerene separation, orientational order/disorder, valence state, orbital degeneracy, low-symmetry distortions and metal- C60 interactions. In this chapter, we discuss some key issues of current research on fiillerene-based materials, including the metal-antiferromagnetic insulator transition at large interfullerene separations, the tuning of the electronic and magnetic properties by weak intermolecular interactions and the intermediate valence behaviour of rare-earth fullerides.

Keywords

Lower Unoccupied Molecular Orbital Weak Intermolecular Interaction Heavy Fermion System Intermediate Valence Valence Transition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media Dordrecht 2004

Authors and Affiliations

  • Serena Margadonna
    • 1
  • Kosmas Prassides
    • 2
  1. 1.Department of ChemistryUniversity of CambridgeUK
  2. 2.Department of ChemistryUniversity of SussexUK

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