Abstract
Small angle X-ray or neutron scattering (SAXS or SANS) techniques offer a powerful means of investigating the adsorption of vapour by high surface area carbons. While traditional vapour phase adsorption methods yield overall adsorbed amounts, scattering observations give complementary direct information on the location of the adsorption sites as well as an independent measure of the internal surface area of the substrate. Data collected from the traditional small angle region (range of transfer momentum q < 1 Å−1) may be used to calculate the density of the condensed phase in the micropores, while that collected from the higher resolution range (q > 1 Å−1) contains information both on the adsorbed amount and on spatial correlations within the adsorbed phase, as well as between it and the substrate. The effects of adsorption of a single species of molecule can be monitored by SAXS alone. The presence of more than one species, however, requires the use of SANS combined with contrast variation, i.e., employing selective isotopic substitution, for instance by replacing hydrogen by deuterium. In this article we discuss the adsorption of water vapour on two nanoporous carbons.
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Abbreviations
- AC:
-
Activated carbon
- APET:
-
Activated carbon from poly(ethylene terephthalate)
- BET:
-
Brunauer-Emmett-Teller model [5]
- BM2:
-
Bending magnet #2 at ESRF
- CRG:
-
Collaborative research group
- ESRF:
-
European Synchrotron Radiation Facility
- NPC:
-
Nanoporous carbon
- RH:
-
Relative humidity
- SAXS:
-
Small angle X-ray scattering
- SANS:
-
Small angle neutron scattering
- WAXS:
-
Wide angle X-ray scattering
References
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Acknowledgments
We are grateful to the European Synchrotron Radiation Facility, Grenoble, for access to the French CRG beamline BM2, and to Norit for providing the carbon samples. We express our gratitude to Cyrille Rochas, Jean-François Bérar, György Bosznai and Orsolya Czakkel for their assistance. This research was supported by the EU – Hungarian Government joint fund (GVOP – 3.2.2 – 2004 – 07 – 0006/3.0).
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Geissler, E., László, K. (2011). Applications of Small Angle X-Ray Scattering Techniques for Characterizing High Surface Area Carbons. In: Mikhalovsky, S., Khajibaev, A. (eds) Biodefence. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0217-2_5
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DOI: https://doi.org/10.1007/978-94-007-0217-2_5
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