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Molecular Spectroscopy and Reactions of Actinides in the Gas Phase and Cryogenic Matrices

  • Chapter
The Chemistry of the Actinide and Transactinide Elements

Abstract

In this chapter we review the spectroscopic data for actinide molecules and the reaction dynamics for atomic and molecular actinides that have been examined in the gas phase or in inert cryogenic matrices. The motivation for this type of investigation is that physical properties and reactions can be studied in the absence of external perturbations (gas phase) or under minimally perturbing conditions (cryogenic matrices). This information can be compared directly with the results from high-level theoretical models.

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Authors
  1. Michael C. Heaven
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  2. John K. Gibson
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  3. Joaquim Marçalo
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Editors and Affiliations

  1. Argonne National Laboratory, Argonne, Illinois, USA

    Lester R. Morss

  2. Lawrence Berkeley National Laboratory, Berkeley, California, USA

    Norman M. Edelstein

  3. University of Liège, Berkeley, Liège, Belgium

    Jean Fuger

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Heaven, M.C., Gibson, J.K., Marçalo, J. (2010). Molecular Spectroscopy and Reactions of Actinides in the Gas Phase and Cryogenic Matrices. In: Morss, L.R., Edelstein, N.M., Fuger, J. (eds) The Chemistry of the Actinide and Transactinide Elements. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-0211-0_38

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