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Thiocyanato Bridged Heterodinuclear Complex [Cu(bpy)2(µ-NCS)Ru(bpy)2(NO3)](PF6)2 and Its Binding with Cd(II), Hg(II), Pb(II) and Ag(I) Ions

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Abstract

The precursor complexes of composition [Cu(bpy)2(H2O)](PF6)2 1 and [Cu(bpy)2(NCS)](PF6) 2 (bpy = 2,2′-bipyridine) were initially prepared and characterized using spectroscopic (IR, UV-vis, ESR, Emission) along with their mass, elemental analysis, and single crystal X-ray crystallographic data. Complex 2 is linked with a known complex Ru(bpy)2(NO3)2 prepared in situ. The resulting heterobimetallic complex of composition [Cu(bpy)2(μ-NCS)Ru(bpy)2(NO3)](PF6)2 3 was isolated and characterized by its spectroscopic, mass, and elemental analysis data and its geometry is optimized without any constraint with plane-wave ab initio density functional theory using solid state package Abinit. The emission and electrochemical properties of these complexes are studied. The multiresponsive chemosensor property of complex 3 for Hg(II) ions as compared to Cd(II), Pb(II) and Ag(I) ions is monitored using UV-vis and fluorescence titrations.

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Acknowledgements

Authors thank authorities of CDRI Lucknow, India for providing analytical data. Authors (NK&LM) acknowledge the authorities of UGC and CSIR, New Delhi, India for the financial assistance.

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Authors and Affiliations

  1. Department of Chemistry, Banaras Hindu University, 221005, Varanasi, India

    Niraj Kumari & Lallan Mishra

  2. Electronic Structure and Theory Group, National Chemical Laboratory, 441008, Pune, India

    Mudit Dixit

  3. Institute of Inorganic Chemistry, Goettingen University, Goettingen, Germany

    Herbert W. Roesky

Authors
  1. Niraj Kumari
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  2. Mudit Dixit
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  3. Herbert W. Roesky
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  4. Lallan Mishra
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Corresponding author

Correspondence to Lallan Mishra .

Editor information

Editors and Affiliations

  1. Faculty of Science, Dept. Chemistry, University of Mauritius, Reduit, Mauritius

    Minu Gupta Bhowon

  2. Faculty of Science, Dept. Chemistry, University of Mauritius, Reduit, Mauritius

    Sabina Jhaumeer-Laulloo

  3. Faculty of Science, Dept. Chemistry, University of Mauritius, Reduit, Mauritius

    Henri Li Kam Wah

  4. Faculty of Science, Dept. Chemistry, University of Mauritius, Reduit, Mauritius

    Ponnadurai Ramasami

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Kumari, N., Dixit, M., Roesky, H.W., Mishra, L. (2012). Thiocyanato Bridged Heterodinuclear Complex [Cu(bpy)2(µ-NCS)Ru(bpy)2(NO3)](PF6)2 and Its Binding with Cd(II), Hg(II), Pb(II) and Ag(I) Ions. In: Gupta Bhowon, M., Jhaumeer-Laulloo, S., Li Kam Wah, H., Ramasami, P. (eds) Chemistry for Sustainable Development. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-8650-1_15

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