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Preparation and Characterization of Polyhedral Oligosilsesquioxanes

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Applications of Polyhedral Oligomeric Silsesquioxanes

Part of the book series: Advances in Silicon Science ((ADSS,volume 3))

Abstract

Polyhedral OligoSilSesquioxanes are often abbreviated by the acronym POS or POSS® and are compounds of the general formula Sin O3n/2Rn (often denoted as TnRn). The commonest of these compounds are the cubic T8R8 POS species since many hydrolysis/condensation reactions of simple RSiX3 compounds (X = Cl, OMe or OEt) give the T8R8 cage as a major product, usually along with small amounts of other TnRn cages and polymeric by-products. Few T4R4 POS have been prepared as they seem to require very bulky R-groups to stabilize the strained POS system and to prevent formation of larger, more stable POS cages.

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Acknowledgments

We thank the UK Energy Research Centre for financial support to DBC.

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Authors and Affiliations

  1. Department of Chemistry, Imperial College London, South Kensington, London, SW7 2AZ, UK

    David B. Cordes & Paul D. Lickiss

  2. Department of Chemistry, Imperial College London, South Kensington, London, UK

    David B. Cordes & Paul D. Lickiss

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  1. David B. Cordes
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  1. Michigan Molecular Institute, W. Saint Andrews Rd. 1910, Midland, 48640, Michigan, USA

    Claire Hartmann-Thompson

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Cordes, D.B., Lickiss, P.D. (2011). Preparation and Characterization of Polyhedral Oligosilsesquioxanes. In: Hartmann-Thompson, C. (eds) Applications of Polyhedral Oligomeric Silsesquioxanes. Advances in Silicon Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3787-9_2

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