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Instrumental Techniques for the Investigation of Heterogenised Catalysts: Characterisation and In situ Studies

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Heterogenized Homogeneous Catalysts for Fine Chemicals Production

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 33))

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Abstract

To design and optimise efficient supported catalysts, the detailed structural and electronic properties as a function of performance are required. This chapter describes characterisation methods which can be applied ex situ (before and after catalysis) as well as in situ or operando (during catalysis, under process conditions). We focus on spectroscopic techniques, i.e. IR, NMR and XAS, the combination which will shown to be specially good for supported organometallic systems, providing complementary insights in structural and electronic properties of support, ligand and reactant coordination to the metal site and the metal site itself. Selected organometallic systems are chosen to demonstrate the strengths and limitations of the individual and combined techniques.

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Authors and Affiliations

  1. School of Chemistry, University of Southampton, Southampton, SO17 1BJ, UK

    John Evans & Moniek Tromp

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  1. John Evans
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  2. Moniek Tromp
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Correspondence to John Evans .

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Editors and Affiliations

  1. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Pierluigi Barbaro

  2. Istituto di Chimica dei Composti, Organometallici (ICCOM), CNR Firenze, Via Madonna del Piano 10, Sesto Fiorentino, 50019, Firenze, Italy

    Francesca Liguori

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Evans, J., Tromp, M. (2010). Instrumental Techniques for the Investigation of Heterogenised Catalysts: Characterisation and In situ Studies. In: Barbaro, P., Liguori, F. (eds) Heterogenized Homogeneous Catalysts for Fine Chemicals Production. Catalysis by Metal Complexes, vol 33. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3696-4_13

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