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Isoscapes pp 139–160Cite as

Statistical and Geostatistical Mapping of Precipitation Water Isotope Ratios

Abstract

More than 5 decades of monitoring has documented wide and systematic variation in the stable isotopic composition of precipitation across the globe. This variation is controlled by climatological processes that govern the source, transport and precipitation of atmospheric moisture. Given the ordered and spatially continuous nature of these processes, variation in precipitation isotopic composition represents a near-ideal system for spatial analysis using geostatistical methods. Spatial analysis of precipitation isotopic composition has a long history, and a wide range of methodologies have been applied to the problem of mapping and predicting isotopic compositions at scales ranging from 102 to 104 km. These range from basic space-only interpolation approaches to more quantitative regression and coupled geostatistical/regression techniques, each with particular benefits and drawbacks. Within the last decade, improved methods for generating quantitative predictions of precipitation isotope ratio distributions and the widespread dissemination of precipitation isoscapes via the world wide web have help spur the development of numerous applications of these data products in climatology, hydrology, ecology, and forensics. Current and future research emphasis on continued improvements in water isotope ratio monitoring and novel isoscapes model parameterizations should help lead to the development of dynamic precipitation isoscapes, incorporating both spatial and temporal variation, and enable new research and applications.

Keywords

  • Isotopic Composition
  • Spatial Autocorrelation
  • Geostatistical Method
  • Semivariogram Model
  • Water Isotope

These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  • Birks SJ, Gibson JJ, Gourcy L, Aggarwal PK and Edwards TWD (2002) Maps and animations offer new opportunities for studying the global water cycle. Eos Trans. AGU (electronic supplement) 83. http://www.agu.org/eos_elec/020082e.html

  • Bowen GJ (2008) Spatial analysis of the intra-annual variation of precipitation isotope ratios and its climatological corollaries. J Geophys Res 113:D05113. doi:10.1029/2007JD009295

    CrossRef  Google Scholar 

  • Bowen GJ, Ehleringer JR, Chesson LA, Stange E, Cerling TE (2007) Stable isotope ratios of tap water in the contiguous USA. Water Resour Res 43:W03419. doi:10.1029/2006wr005186

    CrossRef  Google Scholar 

  • Bowen GJ, Revenaugh J (2003) Interpolating the isotopic composition of modern meteoric precipitation. Water Resour Res 39:1299. doi:10.1029/2003WR002086

    CrossRef  Google Scholar 

  • Bowen GJ, Wassenaar LI, Hobson KA (2005) Global application of stable hydrogen and oxygen isotopes to wildlife forensics. Oecologia 143:337–348. doi:10.1007/s00442-004-1813-y

    CrossRef  Google Scholar 

  • Bowen GJ, Wilkinson B (2002) Spatial distribution of δ18O in meteoric precipitation. Geology 30:315–318

    CrossRef  Google Scholar 

  • Burnett AW, Mullins HT, Patterson WP (2004) Relationship between atmospheric circulation and winter precipitation δ18O in central New York State. Geophys Res Lett 31:L22209. doi:10.1029/2004GL021089: 1–4

    CrossRef  Google Scholar 

  • Craig H, Gordon LI (1965) Deuterium and oxygen-18 variations in the ocean and the marine atmosphere. In: Tongiorgi E (ed) Proceedings of a conference on stable isotopes in oceanographic studies and paleotemperatures. Spoleto, Italy

    Google Scholar 

  • Cressie NAC (1993) Statistics for spatial data. Wiley, New York, p 900 pp

    Google Scholar 

  • Cressman GP (1959) An operative objective analysis system. Mon Weather Rev 87:367–374

    CrossRef  Google Scholar 

  • Dansgaard W (1964) Stable isotopes in precipitation. Tellus 16:436–468

    CrossRef  Google Scholar 

  • Dutton A, Wilkinson BH, Welker JM, Bowen GJ, Lohmann KC (2005) Spatial distribution and seasonal variation in 18O/16O of modern precipitation and river water across the conterminous United States. Hydrol Process 19:4121–4146. doi:10.1002/hyp. 5876

    CrossRef  CAS  Google Scholar 

  • Farquhar GD et al (1993) Vegetation effects on the isotope composition of oxygen in atmospheric CO2. Nature 363:439–443

    CrossRef  CAS  Google Scholar 

  • Fekete BM, Gibson JJ, Aggarwal P, Vorosmarty CJ (2006) Application of isotope tracers in continental scale hydrological modeling. J Hydrol 330:444–456. doi:10.1016/j.jhydrol.2006.04.029

    CrossRef  Google Scholar 

  • Friedman I, Smith GI, Johnson CA, Moscati RJ (2002) Stable isotope compositions of waters in the Great Basin, United States – 2. Modern precipitation. J Geophys Res 107:4401. doi:10.1029/2001JD000566

    CrossRef  Google Scholar 

  • Gat JR, Bowser CJ, Kendall C (1994) The contribution of evaporation from the Great Lakes to the continental atmosphere; estimate based on stable isotope data. Geophys Res Lett 21:557–560

    CrossRef  Google Scholar 

  • Gat JR et al (2003) Isotope composition of air moisture over the Mediterranean Sea: an index of the air–sea interaction pattern. Tellus 55B:953–965

    CAS  Google Scholar 

  • Gibson JJ et al (2005) Progress in isotope tracer hydrology in Canada. Hydrolog Process 19:303–327

    CrossRef  CAS  Google Scholar 

  • Hendricks MB, DePaolo DJ, Cohen RC (2000) Space and time variation of δ18O and δD in precipitation: can paleotemperature be estimated from ice cores? Global Biogeochem Cycles 14:851–861

    CrossRef  CAS  Google Scholar 

  • IAEA (1992) Statistical treatment of data on environmental isotopes in precipitation. IAEA, Vienna, p 781 pp

    Google Scholar 

  • IAEA (2001) GNIP Maps and Animations. http://isohis.iaea.org

  • IAEA/WMO (2004) Global network for isotopes in precipitation, the GNIP database. http://www-naweb.iaea.org/napc/ih/GNIP/IHS_GNIP.html

  • Ingraham NL, Taylor BE (1991) Light stable isotope systematics of large-scale hydrologic regimes in California and Nevada. Water Resour Res 27:77–90

    CrossRef  CAS  Google Scholar 

  • Jacob H, Sonntag C (1991) An 8-year record of the seasonal variation of 2H and 18O in atmospheric water vapour and precipitation at Heidelberg, Germany. Tellus 43B:291–300

    CAS  Google Scholar 

  • Jouzel J, Merlivat L (1984) Deuterium and oxygen 18 in precipitation: modelling of the isotopic effects during snow formation. J Geophys Res 89:11749–11757

    CrossRef  CAS  Google Scholar 

  • Kurita N, Yoshida N, Inoue G, Chayanova EA (2004) Modern isotope climatology of Russia: a first assessment. J Geophys Res 109:D03102. doi:10.1029/2003JD003404

    CrossRef  Google Scholar 

  • Lawrence JR et al. (2004) Stable isotopic composition of water vapor in the tropics. J Geophys Res 109. DOI 10.1029/2003JD004046

    Google Scholar 

  • Lee J-E, Fung I (2007) “Amount effect” of water isotopes and quantitative analysis of post-condensation processes. Hydrol Process. doi:10.1002/hyp. 6637

    Google Scholar 

  • Lykoudis SP, Argiriou AA (2007) Gridded data set of the stable isotopic composition of precipitation over the eastern and central Mediterranean. J Geophys Res 112:D18107. doi:10.1029/2007JD008472

    CrossRef  Google Scholar 

  • Masson-Delmotte V et al (2008) A review of Antarctic surface snow isotopic composition: observations, atmospheric circulation, and isotopic modeling. J Clim 21:3359–3387. doi:10.1175/2007JCLI2139.1

    CrossRef  Google Scholar 

  • Meehan TD, Giermakowski JT, Cryan PM (2004) GIS-based model of stable hydrogen isotope ratios in North American growing-season precipitation for use in animal movement studies. Isot Environ Health Stud 40:291–300

    CrossRef  CAS  Google Scholar 

  • Merlivat L, Jouzel J (1979) Global climatic interpretation of the deuterium-oxygen 18 relationship for precipitation. J Geophys Res 84:5029–5033

    CrossRef  Google Scholar 

  • New M, Hulme M, Jones P (1999) Representing twentieth-century space-time climate variability. Part I: development of a 1961–90 mean monthly terrestrial climatology. J Clim 12:829–856

    CrossRef  Google Scholar 

  • Peixoto JP, Oort AH (1996) The climatology of relative humidity in the atmosphere. J Clim 9:3443–3463

    CrossRef  Google Scholar 

  • Peng H, Mayer B, Harris S, Krouse HR (2004) A 10-year record of stable isotope ratios of hydrogen and oxygen in precipitation at Calgary, Alberta, Canada. Chem Phys Meteorol 56:147–159. doi:10.1111/j.1600-0889.2004.00094.x

    Google Scholar 

  • Rozanski K, Araguás-Araguás L and Gonfiantini R (1993) Isotopic patterns in modern global precipitation. In: Swart PK, Lohmann KC, McKenzie J, Savin S (eds) Climate change in continental isotopic records. Geophysical Monograph 78. American Geophysical Union, Washington, D.C., pp 1–36

    Google Scholar 

  • Salati E, Dall’Olio A, Matsui E, Gat JR (1979) Recycling of water in the Amazon Basin: an isotopic study. Water Resour Res 15:1250–1258

    CrossRef  CAS  Google Scholar 

  • Schmidt GA, LeGrande AN, Hoffmann G (2007) Water isotope expressions of intrinsic and forced variability in a coupled ocean-atmosphere model. J Geophys Res 112:D10103. doi:10.1029/2006JD007781

    CrossRef  Google Scholar 

  • U. S. National Geophysical Data Center (1998) ETOPO-5 five minute gridded world elevation. NGDC, Boulder, Colorado, USA. http://www.ngdc.noaa.gov/mgg/global/etopo5.HTML

  • Ufnar DF, González LA, Ludvigson GA, Brenner RL, Witzke BJ (2004) Evidence for increased latent heat transport during the Cretaceous (Albian) greenhouse warming. Geology 32:1049–1052. doi:10.1130/G20828.1

    CrossRef  Google Scholar 

  • van der Veer, G., et al. (2009), Spatial interpolation of the deuterium and oxygen-18 composition of global precipitation using temperature as ancillary variable, Journal of Geochemical Exploration, 101(2): 175–184. doi:10.1016/j.gexplo.2008.06.008.

    Google Scholar 

  • Welker JM (2000) Isotopic (δ18O) characteristics of weekly precipitation collected across the USA: an initial analysis with application to water source studies. Hydrol Process 14:1449–1464

    CrossRef  Google Scholar 

  • Worden J, Noone D, Bowman K (2007) Importance of rain evaporation and continental convection in the tropical water cycle. Nature 445:528–532. doi:10.1038/nature05508

    CrossRef  CAS  Google Scholar 

  • Yurtsever Y and Gat JR (1981) Atmospheric waters. In: Gat JR, Gonfiantini R (eds) Stable isotope hydrology: deuterium and oxygen-18 in the water cycle. International Atomic Energy Agency, Vienna, pp 103–142

    Google Scholar 

Download references

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Correspondence to Gabriel J. Bowen .

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Bowen, G.J. (2010). Statistical and Geostatistical Mapping of Precipitation Water Isotope Ratios. In: West, J., Bowen, G., Dawson, T., Tu, K. (eds) Isoscapes. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3354-3_7

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