Abstract
The chemistry of metathesis polymerization-derived monolithic supports is summarized. Since ring-opening metathesis polymerization (ROMP) triggered by well-defined transition metal alkylidenes is a living polymerization method, it allows for the controlled and highly reproducible synthesis of stationary phases in terms of both the nature and total content of the functional group(s) of interest. In addition, the high functionality tolerance of ROMP allows for creating monolithic supports with an unprecedented diversity in terms of functional groups that may be introduced. Applications in various areas of chemistry such as separation science heterogeneous catalysis and tissue engineering are summarized.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Penczek, S., Kubisa, P., Szymanski, R., 1991, Makromol. Chem. Rapid Commun., 12: 77–80.
Matyjaszewski, K., 1993, Macromolecules, 26: 1787–1788.
Peters, E. C., Švec, F., Fréchet, J. M. J., Viklund, C., Irgum, K., 1999, Macromolecules, 32: 6377–6379.
Schrock, R. R., 1990, Acc. Chem. Res., 23: 158–165.
Schrock, R. R., 1993, Ring-Opening Polymerization, 1st ed., Hanser, Munich, pp. 129–156.
Švec, F., Tennikova, T. B., Deyl, Z., 2003, Monolithic Materials: Preparation, Properties and Application (In: J. Chromatogr. Libr., Ed.), Elsevier, Amsterdam, Vol. 67, pp. 1–773.
Švec, F., 2004, LC-GC: LC Column Technol. Suppl., June: 18.
Švec, F., 2005, LC-GC Europe, 18: 17–20.
Švec, F., Huber, C. G., 2006, Anal. Chem., 78: 2100–2107.
Švec, F., Geiser, L., 2006, LCGC North America, 24(S4): 22–27.
Buchmeiser, M. R., 2007, Polymer, 48: 2187–2198.
Sinner, F., Buchmeiser, M. R., 2000, Angew. Chem., 112: 1491–1494.
Mayr, B., Tessadri, R., Post, E., Buchmeiser, M. R., 2001, Anal. Chem., 73: 4071–4078.
Buchmeiser, M. R., 2004, New. J. Chem., 28: 549–557.
Buchmeiser, M. R., 2003, Metathesis-Based Polymers for Organic Synthesis and Catalysis, In: Polymeric Materials in Organic Synthesis and Catalysis, 1st ed., Wiley-VCH, Weinheim, pp. 1–559.
Buchmeiser, M. R., 2005, Metathesis Polymerization from and to Surfaces, In: Adv. Polym. Sci. (Surface-Initiated Polymerization I), Springer, Berlin/Heidelberg/ New York, Vol. 197, pp. 137–172.
Love, J. A., Morgan, J. P., Trnka, T. M., Grubbs, R. H., 2002, Angew. Chem., 114: 4207–4209.
Halász, I., Martin, K., 1978, Angew. Chem., 90: 954–961.
Bandari, R., Prager-Duschke, A., Kühnel, C., Decker, U., Schlemmer, B., Buchmeiser, M. R., 2006, Macromolecules, 39: 5222–5229.
Lubbad, S., Mayr, B., Huber, C. G., Buchmeiser, M. R., 2002, J. Chromatogr. A, 959: 121–129.
Mayr, B., Hölzl, G., Eder, K., Buchmeiser, M. R., Huber, C. G., 2002, Anal. Chem., 74: 6080–6087.
Gatschelhofer, C., Magnes, C., Pieber, T. R., Buchmeiser, M. R., Sinner, F. M., 2005, J. Chromatogr. A, 1090: 81–89.
Sinner, F. M., Gatschelhofer, C., Mautner, A., Magnes, C., Buchmeiser, M. R., Pieber, T. R., 2008, J. Chromatogr. A., 1191: 274–281.
Sedláková, P., Miksik, I., Gatschelhofer, C., Sinner, F. M., Buchmeiser, M. R., 2007, Electrophoresis, 28: 2219–2222.
Buchmeiser, M. R., Lubbad, S., Mayr, M., Wurst, K., 2003, Inorg. Chim. Acta, 345: 145–153.
Lubbad, S., Buchmeiser, M. R., 2003, Macromol. Rapid Commun., 24: 580–584.
Eder, K., 2007, Macromol. Rapid Commun., 28: 2029–2032.
Eder, K., Reichel, E., Schottenberger, H., Huber, C. G., Buchmeiser, M. R., 2001, Macromolecules, 34: 4334–4341.
Bandari, R., Knolle, W., Prager-Duschke, A., Buchmeiser, M. R., 2007, Macromol. Chem. Phys., 208: 1428–1436.
Bandari, R., Knolle, W., Buchmeiser, M. R., 2007, Macromol. Symp., 254: 87–92.
Bandari, R., Elsner, C., Knolle, W., Kühnel, C., Decker, U., Buchmeiser, M. R., 2007, J. Sep. Sci., 30: 2821–2827.
Bandari, R., Knolle, W., Buchmeiser, M. R., 2008, J. Chromatogr. A., 1191: 268–273.
Bandari, R., Knolle, W., Buchmeiser, M. R., 2007, Macromol. Rapid Commun., 28: 2090–2094.
Sinner, F., Buchmeiser, M. R., 2000, Macromolecules, 33: 5777–5786.
Mayr, M., Mayr, B., Buchmeiser, M. R., 2001, Angew. Chem., 113: 3957–3960.
Krause, J. O., Lubbad, S., Mayr, M., Nuyken, O., Buchmeiser, M. R., 2003, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.), 44: 790–791.
Krause, J. O., Lubbad, S., Nuyken, O., Buchmeiser, M. R., 2003, Adv. Synth. Catal., 345: 996–1004.
Krause, J. O., Wurst, K., Nuyken, O., Buchmeiser, M. R., 2004, Chem. Eur. J., 10: 777–784.
Krause, J. O., Lubbad, S. H., Nuyken, O., Buchmeiser, M. R., 2003, Macromol. Rapid Commun., 24: 875–878.
Acknowledgment
Financial support provided by the Deutsche Forschungsgemeinschaft (DFG), the Free State of Saxony and the Federal Government of Germany is gratefully acknowledged.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2009 Springer Science+Business Media B.V.
About this paper
Cite this paper
Buchmeiser, M.R. (2009). Polymeric Monoliths: Novel Materials for Separation Science, Heterogeneous Catalysis and Regenerative Medicine. In: Khosravi, E., Yagci, Y., Savelyev, Y. (eds) New Smart Materials via Metal Mediated Macromolecular Engineering. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3278-2_16
Download citation
DOI: https://doi.org/10.1007/978-90-481-3278-2_16
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-481-3276-8
Online ISBN: 978-90-481-3278-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)