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From Mechanism and Kinetics to Precise ATRP Synthesis

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New Smart Materials via Metal Mediated Macromolecular Engineering

Abstract

Controlled/living radical polymerizations (CRP) give access to polymers with precisely controlled molecular weight, narrow molecular weight distribution, well-defined architecture and composition. CRP can be applied to a wide range of monomers and are tolerant to impurities and functional groups. Atom transfer radical polymerization (ATRP) is one of the most widely used CRP techniques. The mechanistic and kinetic studies of ATRP are of fundamental importance since they give access to polymers with various functionalities, compositions, and topologies.

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References

  1. M. Szwarc, Nature 1956, 178, 1168.

    Article  CAS  Google Scholar 

  2. M. Szwarc, M. Levy, R. Milkovich, J. Am. Chem. Soc. 1956, 78, 2656.

    Article  CAS  Google Scholar 

  3. K. Matyjaszewski, in Controlled Radical Polymerization (ACS Symp. Ser. 685), ACS, Washington, DC, 1998.

    Book  Google Scholar 

  4. K. Matyjaszewski, in Controlled/Living Radical Polymerization. Progress in ATRP, NMP, and RAFT (ACS Symp. Ser. 768), ACS, Washington, DC, 2000.

    Book  Google Scholar 

  5. K. Matyjaszewski, T. P. Davis, Wiley, Hoboken, NJ, 2002.

    Google Scholar 

  6. K. Matyjaszewski, in Advances in Controlled/Living Radical Polymerization (ACS Symp. Ser. 854), ACS, Washington, DC, 2003.

    Book  Google Scholar 

  7. K. Matyjaszewski, in Controlled/Living Radical Polymerization: From Synthesis to Materials (ACS Symp. Ser. 944), ACS, Washington, DC, 2006.

    Book  Google Scholar 

  8. W. A. Braunecker, K. Matyjaszewski, Prog. Polym. Sci. 2007, 32, 93.

    Article  CAS  Google Scholar 

  9. J.-S. Wang, K. Matyjaszewski, J. Am. Chem. Soc. 1995, 117, 5614.

    Article  CAS  Google Scholar 

  10. M. Kato, M. Kamigaito, M. Sawamoto, T. Higashimura, Macromolecules 1995, 28, 1721.

    Article  Google Scholar 

  11. K. Matyjaszewski, J. Xia, Chem. Rev. 2001, 101, 2921.

    Article  CAS  Google Scholar 

  12. M. Kamigaito, T. Ando, M. Sawamoto, Chem. Rev. 2001, 101, 3689.

    Article  CAS  Google Scholar 

  13. H. Fischer, Chem. Rev. 2001, 101, 3581.

    Article  CAS  Google Scholar 

  14. W. Tang, N. V. Tsarevsky, K. Matyjaszewski, J. Am. Chem. Soc. 2006, 128, 1598.

    Article  CAS  Google Scholar 

  15. H. Kaneyoshi, Y. Inoue, K. Matyjaszewski, Polym. Mater. Sci. Eng. 2004, 91, 41.

    CAS  Google Scholar 

  16. T. E. Patten, J. Xia, T. Abernathy, K. Matyjaszewski, Science 1996, 272, 866.

    Article  CAS  Google Scholar 

  17. D. M. Haddleton, C. B. Jasieczek, M. J. Hannon, A. J. Shooter, Macromolecules 1997, 30, 2190.

    Article  CAS  Google Scholar 

  18. W. Tang, A. K. Nanda, K. Matyjaszewski, Macromol. Chem. Phys. 2005, 206, 1171.

    Article  CAS  Google Scholar 

  19. J. Xia, K. Matyjaszewski, Macromolecules 1997, 30, 7697.

    Article  CAS  Google Scholar 

  20. J. Xia, S. G. Gaynor, K. Matyjaszewski, Macromolecules 1998, 31, 5958.

    Article  CAS  Google Scholar 

  21. C. Konak, B. Ganchev, M. Teodorescu, K. Matyjaszewski, P. Kopeckova, J. Kopecek, Polymer 2002, 43, 3735.

    Article  CAS  Google Scholar 

  22. J. Xia, K. Matyjaszewski, Macromolecules 1999, 32, 2434.

    Article  CAS  Google Scholar 

  23. J. Xia, X. Zhang, K. Matyjaszewski, ACS Symp. Ser. 2000, 760, 207.

    Article  CAS  Google Scholar 

  24. N. V. Tsarevsky, W. A. Braunecker, S. J. Brooks, K. Matyaszewski, Macromolecules 2006, 39, 6817.

    Article  CAS  Google Scholar 

  25. N. V. Tsarevsky, W. A. Braunecker, W. Tang, S. J. Brooks, K. Matyaszewski, G. R. Weisman, E. H. Wong, J. Mol. Catal. A: Chem 2006, 257, 132.

    Article  CAS  Google Scholar 

  26. H. Tang, N. Arulsamy, M. Radosz, Y. Shen, N. V. Tsarevsky, W. A. Braunecker, W. Tang, K. Matyjaszewski, J. Am. Chem. Soc. 2006, 128, 16277.

    Article  CAS  Google Scholar 

  27. T. Pintauer, B. McKenzie, K. Matyjaszewski, ACS Symp. Ser. 2003, 854, 130.

    Article  CAS  Google Scholar 

  28. M. K. Gray, H. Zhou, S. T. Nguyen, J. M. Torkelson, Macromolecules 2004, 37, 5586.

    Article  CAS  Google Scholar 

  29. K. Ohno, A. Goto, T. Fukuda, J. Xia, K. Matyjaszewski, Macromolecules 1998, 31, 2699.

    Article  CAS  Google Scholar 

  30. K. Matyjaszewski, H.-J. Paik, P. Zhou, S. J. Diamanti, Macromolecules 2001, 34, 5125.

    Article  CAS  Google Scholar 

  31. T. Pintauer, K. Matyjaszewski, Coord. Chem. Rev. 2005, 249, 1155.

    Article  CAS  Google Scholar 

  32. J. Xia, K. Matyjaszewski, Macromolecules 1997, 30, 7692.

    Article  CAS  Google Scholar 

  33. G. Moineau, P. Dubois, R. Jerome, T. Senninger, P. Teyssie, Macromolecules 1998, 31, 545.

    Article  CAS  Google Scholar 

  34. J. Xia, K. Matyjaszewski, Macromolecules 1999, 32, 5199.

    Article  CAS  Google Scholar 

  35. M. Li, N. M. Jahed, K. Min, K. Matyjaszewski, Macromolecules 2004, 37, 2434.

    Article  CAS  Google Scholar 

  36. K. Min, M. Li, K. Matyjaszewski, J. Polym. Sci. Part A: Polym. Chem. 2005, 43, 3616.

    Article  CAS  Google Scholar 

  37. J. Queffelec, S. G. Gaynor, K. Matyjaszewski, Macromolecules 2000, 33, 8629.

    Article  CAS  Google Scholar 

  38. K. Matyjaszewski, S. Coca, S. G. Gaynor, M. Wei, B. E. Woodworth, Macromolecules 1997, 30, 7348.

    Article  CAS  Google Scholar 

  39. W. Jakubowski, K. Matyjaszewski, Macromolecules 2005, 38, 4139.

    Article  CAS  Google Scholar 

  40. K. Min, H. Gao, K. Matyjaszewski, J. Am. Chem. Soc. 2005, 127, 3825.

    Article  CAS  Google Scholar 

  41. K. Min, H. Gao, K. Matyjaszewski, Macromolecules 2007, 40, 1789.

    Article  CAS  Google Scholar 

  42. H. Tang, M. Radosz, Y. Shen, Macromol. Rapid Commun. 2006, 27, 1127.

    Article  CAS  Google Scholar 

  43. K. Min, W. Jakubowski, K. Matyjaszewski, Macromol. Rapid Commun. 2006, 27, 594.

    Article  CAS  Google Scholar 

  44. J. K. Oh, K. Matyjaszewski, J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 3787.

    Article  CAS  Google Scholar 

  45. J. K. Oh, C. Tang, H. Gao, N. V. Tsarevsky, K. Matyjaszewski, J. Am. Chem. Soc. 2006, 128, 5578.

    Article  CAS  Google Scholar 

  46. K. Matyjaszewski, K. Min, W. Tang, J. Huang, W. A. Braunecker, N. V. Tsarevsky, W. Jakubowski, Proc. Natl. Acad. Sci. (U.S.A.) 2006, 103, 15309.

    Article  CAS  Google Scholar 

  47. W. Jakubowski, K. Matyjaszewski, Angew. Chem. Int. Ed. 2006, 45, 4482.

    Article  CAS  Google Scholar 

  48. W. Jakubowski, K. Min, K. Matyjaszewski, Macromolecules 2006, 39, 39.

    Article  CAS  Google Scholar 

  49. J. Pietrasik, H. Dong, K. Matyjaszewski, Macromolecules 2006, 39, 6384.

    Article  CAS  Google Scholar 

  50. S. G. Gaynor, K. Matyjaszewski, ACS Symp. Ser. 1998, 685, 396.

    Article  CAS  Google Scholar 

  51. N. V. Tsarevsky, S. A. Bencherif, K. Matyjaszewski, Macromolecules 2007, 40, 4439.

    Article  CAS  Google Scholar 

  52. D. E. Betts, T. Johnson, D. Leroux, J. M. Desimone, ACS Symp. Ser. 1998, 685, 418.

    Article  CAS  Google Scholar 

  53. K. L. Beers, S. Boo, S. G. Gaynor, K. Matyjaszewski, Macromolecules 1999, 32, 5772.

    Article  CAS  Google Scholar 

  54. K. L. Beers, S. G. Gaynor, K. Matyjaszewski, S. S. Sheiko, M. Moeller, Macromolecules 1998, 31, 9413.

    Article  CAS  Google Scholar 

  55. X. Zhang, J. Xia, K. Matyjaszewski, Macromolecules 1998, 31, 5167.

    Article  CAS  Google Scholar 

  56. M. Teodorescu, K. Matyjaszewski, Macromolecules 1999, 32, 4826.

    Article  CAS  Google Scholar 

  57. M. Teodorescu, K. Matyjaszewski, Macromol. Rapid Commun. 2000, 21, 190.

    Article  CAS  Google Scholar 

  58. Y. Xia, X. Yin, N. A. D. Burke, H. D. H. Stoever, Macromolecules 2005, 38, 5937.

    Article  CAS  Google Scholar 

  59. D. Bontempo, R. C. Li, T. Ly, C. E. Brubaker, H. D. Maynard, Chem. Commun. 2005, 37, 4702.

    Article  Google Scholar 

  60. K. Ohno, Y. Tsujii, T. Fukuda, J. Polym. Sci. Part A: Polym. Chem. 1998, 36, 2473.

    Article  CAS  Google Scholar 

  61. A. Marsh, A. Khan, D. M. Haddleton, M. J. Hannon, Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 2000, 41, 440.

    CAS  Google Scholar 

  62. J.-F. Lutz, A. F. Thuenemann, R. Nehring, J. Polym. Sci. Part A: Polym. Chem. 2005, 43, 4805.

    Article  CAS  Google Scholar 

  63. D. A. Shipp, J.-L. Wang, K. Matyjaszewski, Macromolecules 1998, 31, 8005.

    Article  CAS  Google Scholar 

  64. D. Mecerreyes, G. Moineau, P. Dubois, R. Jerome, J. L. Hedrick, C. J. Hawker, E. E. Malmstrom, M. Trollsas, Angew. Chem. Int. Ed. 1998, 37, 1274.

    Article  CAS  Google Scholar 

  65. W. H. Binder, R. Sachsenhofer, Macromol. Rapid Commun. 2007, 28, 15.

    Article  CAS  Google Scholar 

  66. J.-F. Lutz, Angew. Chem. Int. Ed. 2007, 46, 1018.

    Article  CAS  Google Scholar 

  67. B. S. Sumerlin, N. V. Tsarevsky, G. Louche, R. Y. Lee, K. Matyjaszewski, Macromolecules 2005, 38, 7540.

    Article  CAS  Google Scholar 

  68. H. Gao, G. Louche, B. S. Sumerlin, N. Jahed, P. Golas, K. Matyjaszewski, Macromolecules 2005, 38, 8979.

    Article  CAS  Google Scholar 

  69. J.-F. Lutz, H. G. Boerner, K. Weichenhan, Macromol. Rapid Commun. 2005, 26, 514.

    Article  CAS  Google Scholar 

  70. P. L. Golas, N. V. Tsarevsky, B. S. Sumerlin, L. M. Walker, K. Matyjaszewski, Aust. J. Chem. 2007, 60, 1.

    Article  Google Scholar 

  71. H. Gao, K. Matyjaszewski, Macromolecules 2006, 39, 4960.

    Article  CAS  Google Scholar 

  72. H. Gao, K. Matyjaszewski, J. Am. Chem. Soc. 2007, 129, 6633.

    Article  CAS  Google Scholar 

  73. H. Durmaz, F. Karatas, U. Tunca, G. Hizal, J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 3947.

    Article  CAS  Google Scholar 

  74. D. Greszta, K. Matyjaszewski, T. Pakula, Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 1997, 38, 709.

    CAS  Google Scholar 

  75. K. Matyjaszewski, D. A. Shipp, J.-L. Wang, T. Grimaud, T. E. Patten, Macromolecules 1998, 31, 6836.

    Article  CAS  Google Scholar 

  76. T. Kowalewski, N. V. Tsarevsky, K. Matyjaszewski, J. Am. Chem. Soc. 2002, 124, 10632.

    Article  CAS  Google Scholar 

  77. J.-F. Lutz, D. Neugebauer, K. Matyjaszewski, J. Am. Chem. Soc. 2003, 125, 6986.

    Article  CAS  Google Scholar 

  78. J.-F. Lutz, W. Jakubowski, K. Matyjaszewski, Macromol. Rapid Commun. 2004, 25, 486.

    Article  CAS  Google Scholar 

  79. Y. Okamoto, S. Habaue, Y. Isobe, ACS Symp. Ser. 2003, 854, 59.

    Article  CAS  Google Scholar 

  80. K. Matyjaszewski, Polym. Int. 2003, 52, 1559.

    Article  CAS  Google Scholar 

  81. K. Matyjaszewski, P. J. Miller, E. Fossum, Y. Nakagawa, Appl. Organomet. Chem. 1998, 12, 667.

    Article  CAS  Google Scholar 

  82. S. Angot, K. S. Murthy, D. Taton, Y. Gnanou, Macromolecules 1998, 31, 7218.

    Article  CAS  Google Scholar 

  83. A. Heise, C. Nguyen, R. Malek, J. L. Hedrick, C. W. Frank, R. D. Miller, Macromolecules 2000, 33, 2346.

    Article  CAS  Google Scholar 

  84. K. Matyjaszewski, P. J. Miller, J. Pyun, G. Kickelbick, S. Diamanti, Macromolecules 1999, 32, 6526.

    Article  CAS  Google Scholar 

  85. Y. Gnanou, D. Taton, Macromol. Symp. 2001, 174, 333.

    Article  CAS  Google Scholar 

  86. X. Zhang, J. Xia, K. Matyjaszewski, Macromolecules 2000, 33, 2340.

    Article  CAS  Google Scholar 

  87. J. Xia, X. Zhang, K. Matyjaszewski, Macromolecules 1999, 32, 4482.

    Article  CAS  Google Scholar 

  88. H. Gao, N. V. Tsarevsky, K. Matyjaszewski, Macromolecules 2005, 38, 5995.

    Article  CAS  Google Scholar 

  89. C. J. Hawker, J. M. J. Frechet, R. B. Grubbs, J. Dao, J. Am. Chem. Soc. 1995, 117, 10763.

    Article  CAS  Google Scholar 

  90. S. G. Gaynor, S. Edelman, K. Matyjaszewski, Macromolecules 1996, 29, 1079.

    Article  CAS  Google Scholar 

  91. K. Matyjaszewski, S. G. Gaynor, Macromolecules 1997, 30, 7042.

    Article  CAS  Google Scholar 

  92. R. Baudry, D. C. Sherrington, Macromolecules 2006, 39, 1455.

    Article  CAS  Google Scholar 

  93. N. V. Tsarevsky, K. Matyjaszewski, Macromolecules 2002, 35, 9009.

    Article  CAS  Google Scholar 

  94. N. V. Tsarevsky, B. S. Sumerlin, K. Matyjaszewski, Macromolecules 2005, 38, 3558.

    Article  CAS  Google Scholar 

  95. B. A. Laurent, S. M. Grayson, J. Am. Chem. Soc. 2006, 128, 4238.

    Article  CAS  Google Scholar 

  96. J. Listak, W. Jakubowski, L. Mueller, A. Plichta, K. Matyjaszewski, M. R. Bockstaller, Macromolecules 2008, 41, 5919.

    Article  CAS  Google Scholar 

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Acknowledgments

The financial support from NSF (DMR 05-49353, CHE-04-05627, and Graduate Research Fellowship for L.M.) is appreciated.

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Authors and Affiliations

  1. Chemistry Department, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburg, PA, 15213, USA

    Laura Mueller, Patricia Golas & Krzysztof Matyjaszewski

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  1. Laura Mueller
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  2. Patricia Golas
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  3. Krzysztof Matyjaszewski
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Editors and Affiliations

  1. Polymer IRC, Chemistry Department, Durham University, Durham, United Kingdom

    Ezat Khosravi

  2. Department of Chemistry, Istanbul Technical University, Istanbul, Turkey

    Yusuf Yagci

  3. Institute of Macromolecular Chemistry, National Academy of Science, Kiev, Ukraine

    Yuri Savelyev

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Mueller, L., Golas, P., Matyjaszewski, K. (2009). From Mechanism and Kinetics to Precise ATRP Synthesis. In: Khosravi, E., Yagci, Y., Savelyev, Y. (eds) New Smart Materials via Metal Mediated Macromolecular Engineering. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3278-2_1

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