The concepts of ozone depletion potentials (ODPs) and global warming potentials (GWPs) have been extensively used in policy consideration and scientific studies of ozone and climate issues. Most recent candidate-replacement compounds have atmospheric lifetimes shorter than 1 year in order to limit their environmental effects. Especially for chemicals with extremely short lifetimes, on the order of several to tens of days, the stratospheric halogen loading and ozone loss from such gases strongly depend on the location of emissions. Using a state-of-the-art three-dimensional global chemistry-transport model (CTM) of the troposphere and the stratosphere, we have calculated the potential effects of very short-lived substances (VSLS) such as n-propyl bromide (nPB), iodotrifluoromethane (CF3I), and methyl iodine (CH3I) on atmospheric ozone. The model-derived lifetimes and ODPs of these halogenated compounds for mid-latitude emissions and of CF3I for tropical emissions are presented in this chapter. On the other hand, ozone depletion due to emission of bromochlorofluorocarbons, or Halons, leads to cooling of the climate system in the opposite direction to direct warming contribution of the Halons as greenhouse gases. This cooling is a key indirect effect of Halons on radiative forcing or climate. Using atmospheric models, CTMs and a radiative transfer model, we have explicitly calculated the indirect GWPs of Halon-1211 and -1301 for a 100-year time horizon. The calculated indirect effects of Halon-1211 are much smaller than those published in earlier studies. Nevertheless, our new model-based assessment of the indirect GWPs of the two major Halons confirms the importance of indirect effects on climate.
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References
Atkinson, R. (1994). Gas-phase chemistry of organic compounds. Journal of Physical and Chemical Reference Data Monographs, 1994, 2, 1–216.
Bell, N., Hsu, L., Jacob, D. J., Schultz, M. G., Blake, D. R., Butler, J. H., et al. (2002). Methyl iodide: Atmospheric budget and use as a tracer of marine convection in global models. Journal of Geophysical Research, 107, 4340, doi: 10.1029/2001JD001151.
Bridgeman, C. H., Pyle, J. A., & Shallcross, D. E. (2000). A three-dimensional model calcula- tion of the ozone depletion potential of 1-bromopropane (1-C3H7Br). Journal of Geophysical Research, 105(26), 493–426, 502.
Briegleb, B. P. (1992a). Delta-Eddington approximation for solar radiation in the NCAR community climate model. Journal of Geophysical Research, 97, 7603–7612.
Briegleb, B. P. (1992b). Longwave band model for thermal radiation in climate studies. Journal of Geophysical Research, 97, 11475–11485.
Bösch, H., Camy-Peyret, C., Chipperfield, M. P., Fitzenberger, R., Harder, H., Platt, U., et al. (2003). Upper limits of stratospheric IO and OIO inferred from center-to-limb-darkening- corrected balloon-borne solar occultation visible spectra: Implications for total gaseous iodine and stratospheric ozone. Journal of Geophysical Research, 108(D15), 4455. doi: 10.1029/2002JD003078.
Burkholder, J. B., Gilles, M. K., Gierczak, T., & Ravishankara, A. R. (2002). The atmospheric degradation of 1-bromopropane (CH3CH2CH2Br): The photochemistry of bromoacetone. Geophysical Research Letters, 29, 1822. doi: 10.1029/2002GL014712.
Cohan, D. S., Sturrock, G. A., Biazar, A. P., & Fraser, P. J. (2003). Atmospheric methyl iodide at Cape Grim, Tasmania, from AGAGE Observations. Journal of Atmospheric Chemistry, 44(2), 131–150.
Connell, P. S., Kinnison, D. E., Bergmann, D. J., Patten, K. O., Wuebbles, D. J., Daniel, R. G., et al. (1996). Environmental aspects of halon replacements: Considerations for advanced agents and the ozone depletion potential of CF3I. Proceedings of the Conference on the Halon Options Technical Working Conference (HOTWC), in Albuquerque, NM.
Daniel, J. S., Solomon, S., & Albritton, D. L. (1995). On the evaluation of halocarbon radiative forcing and dlobal warming potentials. Journal of Geophysical Research, 100,(D1) 1271–1285.
Fisher, D. A., Hales, C. H., Filkin, D. L., Ko, M. K. W., Sze, N., Connell, P. S., et al. (1990). Model calculations of the relative effects of CFCs and their replacements on stratospheric ozone. Nature, 344, 508–512. doi: 10.1038/344508a0.
Fisher, D. A., Hales, C. H., Wang, W. C., Ko, M. K. W., & Sze, N. D. (1990). Model calculations of the relative effects of CFCs and their replacements on global warming. Nature, 344, 513–516. doi: 10.1038/344513a0.
Forster, P. M., Burkholder, J. B., Clerbaux, C., Coheur, P. F., Dutta, M., Gohar, L. K., et al. (2004). Resolving uncertainties in the radiative forcing of HFC-134a. Journal of Quantitative Spectroscopy and Radiative Transfer, doi: 10.1016/j.jqsrt.2004.08.038.
Gilles, M. K., Burkholder, J. B., Gierczak, T., Marshall, P., & Ravishankara, A. R. (2002). Rate coefficient and product branching measurements for the reaction OH + Bromopropane from 230 to 360 K. Journal of Physical Chemistry A, 106, 5358–5366, doi: 10.1021/jp014736+.
Guillas, S., Tiao, G., Wuebbles, D. J., & Zubrow, A. (2006). Statistical diagnostic and correction of a chemistry-transport model for the prediction of total column ozone. Atmospheric Chemistry Physics, 6, 525–537.
Horowitz, L., Walters, S., Mauzerall, D., Emmons, L., Rasch, P., Granier, C., et al. (2003). A global simulation of tropospheric ozone and related tracers: Description and evaluation of MOZART, version 2. Journal of Geophysical Research, 108(D24), 4784, doi: 10.1029/2002JD002853.
Intergovernmental Panel on Climate Change (IPCC) (1990). Climate change, The IPCC scientific assessment. In J. T. Houghton, G. J. Jenkins, and J. J. Ephraums (Eds.), (Chapter 2, Radiative Forcing on Climate, Shine, K. P., R. G. Derwent, D. J. Wuebbles, J.-J. Morcrette, lead authors). New York: Cambridge University Press.
Intergovernmental Panel on Climate Change (IPCC) (2001). Climate change 2001: The Scientific Basis. Contribution of Working Group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change. In J. T. Houghton, Y. Ding, D. J. Griggs, M. Noguer, P. J. van der Linden, and D. Xiaosu (Eds.), Cambridge/New York Cambridge University Press.
Intergovernmental Panel on Climate Change and Technology and Economic Assessment Panel (IPCC/TEAP) (2005). IPCC/TEAP Special Report on Safeguarding the Ozone Layer and the Global Climate System: Issues Related to Hydrofluorocarbons and Perfluorocarbons. New York: Cambridge University Press, 478pp.
Jain, A. K., Briegleb, B. P., Minschwaner, K., & Wuebbles, D. J. (2000). Radiative forcings and global warming potentials of 39 greenhouse gases. Journal of Geophysical Research, 105, 20773–20790.
Kinnison, D. E., Brasseur, G. P., Walters, S., Garcia, R. R., Marsh, D. R., Sassi, F., et al. (2007). Sensitivity of chemical tracers to meteorological parameters in the MOZART-3 chemical transport model. Journal of Geophysical Research, 112, doi: 10.1029/2006JD007879.
Kwok, E. S. C., & Atkinson, R. (1995). Estimating hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: An update. Atmospheric Environment, 29, 1685–1695.
Lacis, A. A., Wuebbles, D. J., & Logan, J. A. (1990). Radiative forcing of climate by changes in the vertical distribution of ozone. Journal of Geophysical Research, 95(D7), 9971–9981.
Li, Y., Patten, K. O., Youn, D., & Wuebbles, D. J. (2006). Potential impacts of CF3I on ozone as a replacement for CF3Br in aircraft applications. Atmospheric Chemistry Physics, 6, 4559–4568.
Miller, A. J., Cai, A., Tiao, G., Wuebbles, D. J., Flynn, L. E., Yang, S. K., et al. (2006). Examination of Ozonesonde data for trends and trend changes incorporating solar and Arctic Oscillation signals. Journal of Geophysical Research, 111, D13305, doi: 10.1029/2005JD006684.
Martínez-Avilés, M. (2008). On the atmospheric degradation of very short lived brominated compounds and their reservoir Species. Ph.D. thesis: Purdue University at West Lafayette.
Naik, V., Jain, A. K., Patten, K. O., & Wuebbles, D. J. (2000). Consistent sets of atmospheric lifetimes and radiative forcings on climate for CFC replacements: HCFCs and HFCs. Journal of Geophysical Research, 105, 6903–6914.
Naik, V., Mauzerall, D., Horowitz, L., Schwarzkopf, D., Ramaswamy, V., & Oppenheimer, M. (2005). Net radiative forcing due to changes in regional emissions of tropospheric ozone precursors. Journal of Geophysical Research, 110, doi: 10.1029/2005JD005908.
Nelson, D. D. Jr., Wormhoudt, J. C., Zahniser, M. S., Kolb, C. E., Ko, M. K. W., & Weisenstein, D. K. (1997). OH reaction kinetics and atmospheric impact of 1-bromopropane. Journal of Physical Chemistry A, 101, 4987–4990.
Newman, P. A., Nash, E. R., Kawa, S. R., Montzka, S. A., & Schauffler, S. M. (2006). When will the Antarctic ozone hole recover? Geophysical Research Letters, 33, L12814, doi: 10.1029/2005GL025232.
Newman, P. A., Daniel, J. S., Waugh, D. W., & Nash, E. R. (2007). A new formulation of equivalent effective stratospheric chlorine (EESC). Atmospheric Chemistry and Physics, 7, 4537–4552.
Olsen, S. C., Hannegan, B. J., Zhu, X., & Prather, M. J. (2000). Evaluating ozone depletion from very short-lived halocarbons. Geophyscial Research Letters, 27, 1475–1478.
Pan, L. L., Wei, J. C., Kinnison, D. E., Garcia, R. R., Wuebbles, D. J., & Brasseur, G. P. (2007). A set of diagnostics for evaluating chemistry-climate models in the extratropical tropopause region. Journal of Geophysical Research, 112, D09316, doi: 10.1029/2006JD007792.
Ramaswamy, V., Schwarzkopf, M. D., & Shine, K. P. (1992). Radiative forcing of climate from halocarbon induced global stratospheric ozone loss. Nature, 355, 810–812.
Reinsel, G. R., Miller, A. J., Flynn, L. E., Nagatani, R. M., Tiao, G. C., Weatherhead, E. C., et al. (2005). Trend analysis of total ozone data for turnaround and dynamical contributions. Journal of Geophysical Research, 110, doi: 10.1029/2004JD004662.
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Huie, R. E., Orkin, V. L., et al. (2003). Chemical kinetics and photochemical data for use in atmospheric studies. California: NASA/JPL Publication 02–25. Pasadena, 334.
Sassi, F., Boville, B. A., Kinnison, D. E., & Garcia, R. R. (2005). The effects of interactive ozone chemistry on simulations of the middle atmosphere. Geophysical Research, Letters, 32, LO7811, doi: 10.1029/2004GL022131.
Solomon, S., Mills, M., Heidt, L. E., Pollock, W. H., & Tuck, A. F. (1992). On the evaluation of ozone depletion potentials. Journal of Geophysical Research, 97, 824–842.
Solomon, S., Burkholder, J. B., Ravishankara, A. R., & Garcia, R. R. (1994). Ozone depletion and global warming potentials of CF3I. Journal of Geophysical Research, 99(D10), 20929–20935.
Stamnes, K., Tsay, S. C., Wiscombe, W., & Jayaweera, K. (1988). Numerically stable algorithm for discrete-ordinate-method radiative transfer in multiple scattering and emitting layered media. Applied Optics, 27, 2502–2509.
Velders, G. J. M., Anderson, S. O., Daniel, J. S., Fahey, D. W., & McFarland, M. (2007). The importance of the Montreal Protocol in protecting climate. Proceedings of the National Academy of Sciences, 104, 4814–4819.
Vogt, R., Sander, R., Von Glasow, R., & Crutzen, P. (1999). Iodine chemistry and its role in halogen activation and ozone loss in the marine boundary layer: A model study. Journal of Atmospheric Chemistry, 32, 375–395.
Wallington, T. J., Hurley, M. D., Xia, J., Wuebbles, D. J., Sillman, S., Ito, A., et al. (2006). Formation of C7F15COOH (PFOA) during the atmospheric oxidation of 8:2 fluorotelomer alcohol (n-C8F17CH2CH2OH). Environmental Science and Technology, 40, 924–930.
Wei, C. F., Kotamarthi, V. R., Ogunsola, O. J., Horowitz, L. W., Walters, S., et al. (2003). Seasonal variability of ozone mixing ratios and budgets in the tropical southern Pacific: A GCTM perspective. Journal of Geophysical Research, 107, 8235, doi: 10.1029/2001JD000772.
World Meteorological Organization (WMO) (1995). Scientific Assessment of Ozone Depletion: 1994, Global Ozone, Research and Monitoring Project — Report 37, Switzerland: Geneva.
World Meteorological Organization (WMO) (1999). Scientific Assessment of Ozone Depletion: 1998, Global Ozone, Research and Monitoring Project — Report 44, Switzerland: Geneva.
World Meteorological Organization (WMO) (2003). Scientific Assessment of Ozone Depletion: 2002, Global Ozone, Research and Monitoring Project — Report 47, Switzerland: Geneva.
World Meteorological Organization (WMO) (2007). Scientific Assessment of Ozone Depletion: 2006, Global Ozone, Research and Monitoring Project — Report 50, Switzerland: Geneva.
Wuebbles, D. J. (1981). The relative efficiency of a number of halocarbons for destroying stratospheric ozone, Lawrence Livermore National Laboratory report UCID-18924.
Wuebbles, D. J. (1983). Chlorocarbon emission scenarios: Potential impact on stratospheric ozone. Journal of Geophysical Research, 88, 1433–1443.
Wuebbles, D. J., & Hayhoe, K. (2002). Atmospheric methane and global change. Earth Science Reviews, 57, 177–210.
Wuebbles, D. J., Patten, K. O., Johnson, M. T., & Kotamarthi, R. (2001). The new methodology for Ozone Depletion Potentials of short-lived compounds: n-propyl bromide as an example. Journal of Geophysical Research, 106, 14,551–14,571.
Youn, D., Choi, W., Lee, H., & Wuebbles, D. J. (2006). Interhemispheric differences in changes of long-lived tracers in the middle stratosphere over the last decade. Geophysical Research Letters, 33, L03807, doi: 10.1029/2005GL024274.
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Wuebbles, D.J., Youn, D., Patten, K., Wang, D., Martínez-Avilés, M. (2009). Metrics for Ozone and Climate: Three-Dimensional Modeling Studies of Ozone Depletion Potentials and Indirect Global Warming Potentials. In: Zerefos, C., Contopoulos, G., Skalkeas, G. (eds) Twenty Years of Ozone Decline. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2469-5_23
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