Abstract
In corresponding states (CS) theory the PVT properties of fluids are expressed in terms of the critical constants and one or more additional parameters. In this chapter the use of CS theory to correlate isotope effects on the physical properties of fluids is explored.
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Further Reading
Hirschfelder, J. O., Curtiss, C. F., Bird, R. B., Molecular Theory of Gases and Liquids, Wiley, New York, 1954.
V. B. Polyakov, V. B., Horita, J., Cole, D. R. and Chialvo, A. A. Novel corresponding-states principle approach for the equation of state of isotopologues: H2 18O as an example. J. Phys. Chem. B-111, 393 (2007).
Prausnitz, J. M. Molecular Thermodynamics of Fluid Phase Equilibria, Prentice Hall, Englewood Cliffs, NJ, 1969.
Rabinovitch, I. B. Influence of isotopy on the physicochemical properties of liquids. Consultants Bureau, New York, 1970.
Van Ness, H. C., Abbott, M. M., Classical Thermodynamics of Nonelectrolyte Solutions, McGraw-Hill, New York. 1982.
Van Hook, W. A., Rebelo, L. P. N. and Wolfsberg, M. Isotope effects on VLE properties of fluids and corresponding states: critical point shifts on isotopic substitution. Fluid Phase Equilib. 257, 35 (2007).
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Wolfsberg, M., Van Hook, W.A., Paneth, P. (2009). Reduced Equations of State: Critical Property Isotope Effects. In: Isotope Effects. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2265-3_13
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DOI: https://doi.org/10.1007/978-90-481-2265-3_13
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