Abstract
Thermodynamic calculations have been done for the factors e.g., free energy (∆F), enthalpy (∆H), and lattice energy (U) by the various researchers namely Vaughn (1955), Schicltz and Soliman (1966), and Mazumdar and Mukherjee (1983) in predicting the nature of intermediate spinel phase, and second the course of mullite formation reaction of kaolinite.
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A.I. Avgustink, M. Petrosyan, O.P. J. Appl. Chem. U.S.S.R. 25, 216 (1952)
M. Born and J.E. Mayer, Lattice Theory of Ionic Crystals. Z. Phys. 75,1–18 (1932)
A.K. Chakraborty, D.K. Ghosh, P. Kundu, Comment on Structural characterization of the spinel phase in the Kaolin–Mullite research series through lattice energy. J. Am. Ceram. Soc. 68(8), C-200–C-201 (1986)
A.F. Kapustinsky, J. Gen, Kemp. Moscow 13, 497 (1943)
C. Kroser, Theoretischer warme bedraf der glaschme. Z.Proze Se (Glastech. Ber.) 26, 202 (1953)
S. Mazumdar and B. Mukherjee, Structural characterization of the spinel phase in the kaolinmullite reaction series through lattice energy. J. Am. Ceram. Soc. 66(9), 610–12 (1983)
N.C. Schieltz, M.R. Soleman (1966) Thermodynamics of various high temperature transformation of Kaolinite. in ed. by Earl I Proceedings of the 13th Natational Conference on Clays, Madison, Wisconsin, Pergamon press, Monograph, No. 25 pp. 419–425 (1966)
B.S. Shvetsov and C.O. Gevorkyan, Thermochemical investigation of the kaolin heating process. J.Appl.Chem.(U.S.S.R), 15, 302–18 (1942)
F. Vaughan, Energy changes when kaolin minerals are heated. Clay Miner. Bull. 2(13), 265–274 (1955).
D.R. Waldbaum, Thermodynamic properties of mullite, sillimanite, andalusite, Kyanite. Am. Miner 50, 186–195 (1965)
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Chakraborty, A.K. (2014). Thermodynamic Approach. In: Phase Transformation of Kaolinite Clay. Springer, New Delhi. https://doi.org/10.1007/978-81-322-1154-9_12
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DOI: https://doi.org/10.1007/978-81-322-1154-9_12
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