Skip to main content

Some Aspects of Development in Direct Cathodic Deprotonation

  • Conference paper
Novel Trends in Electroorganic Synthesis

Abstract

Data on direct deprotonation of different types of organic acids were observed. It was noted that from the formal view point direct deprotonation was good in amperostatic electrolysis of weak acids reduced at the discharge potential of a supporting electrolyte where their latent indirect deprotonation occured. Such processes were called “Cathodic Deprotonation in Simple Systems” (CDSS). Characteristic features of CDSS processes were discussed and new facts of their realization were given.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. D.E. Batrac, and M.D. Hawley, J. Am. Chem. Soc., 1972, 94, 640.

    Article  Google Scholar 

  2. W.M. Moore, M. Finkelstein, and S.D. Ross, Tetrahedron, 1980, 727.

    Google Scholar 

  3. J.K Howie, J.J. Hotus, and D. T. Sawyer, J. Am. Chem. Soc., 1977, 99, 6323.

    Article  CAS  Google Scholar 

  4. V.A. Petrosyan, V.A. Frolowsky, and D.A. Sadilenko, Elektrokhimiya (in press).

    Google Scholar 

  5. A.V. Bukhtiarov, V.N. Golyshin, and A.P. Tomilov, Zn. Obshch. Khim., 1988, 58, 157.

    CAS  Google Scholar 

  6. A.V. Bukhtiarov, V.V. Mikheev, A.V. Lebedev, A.P. Tomilov, and O.V. Kuz’min, Zn. Obshch. Khim., 1988, 58, 684.

    CAS  Google Scholar 

  7. A.V. Bukhtiarov, V.V. Mikheev, A.V. Lebedev, A.P. Tomilov, and O.V. Kuz’min, Zn. Obshch. Khim.,1989 59, 421.

    Google Scholar 

  8. V.A. Petrosyan, Russ. Chem. Bull., 1995, 44, 1353 ( Engl. Transi).

    Google Scholar 

  9. J.C. Le Menn, J. Sarrazin, and A. Tallec, Can. J. Chem., 1989, 67, 1332;

    Article  Google Scholar 

  10. M. Kimura, T. Kurata, and Y. Sawaki, in Studies in Organic Chemistry Recent Advances in Electroorganic Synthesis (Edited by S. Torii) Kodansha Tokyo, Elsevier Amsterdam, 1987, 30, 269.

    Google Scholar 

  11. V.A. Petrosyan, E.E. Nifant’ev, M.E. Niyazimbetov, R.K Magdeeva, N. S. Magomedova, and V.K Bel’sky, Russ. Chem. Bull.,1996, 45,427 (Engl. Transl.).

    Google Scholar 

  12. E.J. Corey, and Isao Kuwajima, Tetrahedron Lett, 1972, 487.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1998 Springer Japan

About this paper

Cite this paper

Petrosyan, V.A. (1998). Some Aspects of Development in Direct Cathodic Deprotonation. In: Torii, S. (eds) Novel Trends in Electroorganic Synthesis. Springer, Tokyo. https://doi.org/10.1007/978-4-431-65924-2_125

Download citation

  • DOI: https://doi.org/10.1007/978-4-431-65924-2_125

  • Publisher Name: Springer, Tokyo

  • Print ISBN: 978-4-431-65926-6

  • Online ISBN: 978-4-431-65924-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics