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Understanding of Unique Thermal Phase Behavior of Room Temperature Ionic Liquids: 1-Butyl-3-Methylimdiazolium Hexafluorophosphate as a Great Example

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Electronic Processes in Organic Electronics

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 209))

Abstract

Room temperature ionic liquids (RTILs) are salts that are liquid around room temperature. Because of their unique properties as liquid, they are considered to be “solvent of the future”, and potentially useful for electrolytes, environmental-friendly solvent, lubricant and so on. Applications of RTILs even cover the field of semiconductor. Some of their characteristics appear in thermal phase behavior, that is, they sometimes show premelting phenomenon, wide temperature range of supercooled liquid state and subsequently tendency to form glassy state, large thermal hysteresis and complex solid-solid phase transitions. 1-Butyl-3-methylimidazolium hexafluorophosphate is a representative RTIL with relatively simple ion structure. However, its thermal phase behavior is complicated and confusing. We built an apparatus for simultaneous measurements of Raman spectroscopy and calorimetry to provide conclusive results on thermal phase behavior and molecular structure of the RTIL. NMR spectroscopy is also carried out to probe molecular dynamics of both cation and anion in the crystalline states, the results of which are consistent with the simultaneous measurements.

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Authors and Affiliations

  1. University of California, Davis, One Shield Avenue, Davis, CA, 95616, USA

    Takatsugu Endo

  2. Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho,Inage, Chiba, 263-8522, Japan

    Keiko Nishikawa

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  1. Takatsugu Endo
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  2. Keiko Nishikawa
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Correspondence to Keiko Nishikawa .

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Editors and Affiliations

  1. Chiba University, Chiba, Japan

    Hisao Ishii

  2. Chiba University, Chiba, Japan

    Kazuhiro Kudo

  3. Chiba University, Chiba, Japan

    Takashi Nakayama

  4. Chiba University, Chiba, Japan

    Nobuo Ueno

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Endo, T., Nishikawa, K. (2015). Understanding of Unique Thermal Phase Behavior of Room Temperature Ionic Liquids: 1-Butyl-3-Methylimdiazolium Hexafluorophosphate as a Great Example. In: Ishii, H., Kudo, K., Nakayama, T., Ueno, N. (eds) Electronic Processes in Organic Electronics. Springer Series in Materials Science, vol 209. Springer, Tokyo. https://doi.org/10.1007/978-4-431-55206-2_17

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