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The Fabrication of Nanoporous Metals (Au, Cu, Pd) and Their Application in Heterogeneous Molecular Transformations

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Book cover Development of New Catalytic Performance of Nanoporous Metals for Organic Reactions

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Abstract

Nanoporous metals (Au, Cu, Pd) fabricated by chemical or electrochemical dealloying, possess intriguing properties towards enormous promising potentials for heterogeneous catalysis, such as unique pore structure, tunable nanoporosity, large specific surface area, high density of atomic steps and kinks, as well as high thermal stability. Here, we summarized nanoporous metals fabricated from different alloys by dealloying and their applications in heterogeneous catalysis. They showed high catalytic activity and selectivity and could be reused several times without obvious loss of activity.

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References

  1. Zhang J, Li CM (2012) Nanoporous metals: fabrication strategies and advanced electrochemical applications in catalysis, sensing and energy systems. Chem Soc Rev 41:7016–7031

    Article  CAS  Google Scholar 

  2. Chen LY, Yu JS, Fujita T et al (2009) Nanoporous copper with tunable nanoporosity for SERS applications. Adv Funct Mater 19:1221–1226

    Article  CAS  Google Scholar 

  3. Forty AJ (1979) Corrosion micromorphology of noble metal alloys and depletion gilding. Nature 282:597–598

    Article  CAS  Google Scholar 

  4. Erlebacher J, Aziz MJ, Karma A et al (2001) Evolution of nanoporosity in dealloying. Nature 410:450–453

    Article  CAS  Google Scholar 

  5. Senior NA, Newman RC (2006) (2006) Synthesis of tough nanoporous metals by controlled electrolytic dealloying. Nanotechnology 17:2311–2316

    Article  CAS  Google Scholar 

  6. Kameoka S, Tsai AP (2008) CO oxidation over a fine porous gold catalyst fabricated by selective leaching from an ordered AuCu3 intermetallic compound. Catal Lett 121:337–341

    Article  CAS  Google Scholar 

  7. Zhang Z, Wang Y, Qi Z (2009) Fabrication and characterization of nanoporous gold composites through chemical dealloying of two phase Al–Au alloys. J Mater Chem 19:6042–6050

    Article  CAS  Google Scholar 

  8. Zhang Z, Wang Y, Qi Z et al (2009) Generalized fabrication of Nanoporous metals (Au, Pd, Pt, Ag, and Cu) through chemical dealloying. J Phys Chem C 113:12629–12636

    Article  CAS  Google Scholar 

  9. Wang X, Zhang Z, Ji H et al (2012) Dealloying of single-phase Al2Au to nanoporous gold ribbon/film with tunable morphology in inorganic and organic acidic media. Appl Surf Sci 258:9073–9079

    Article  CAS  Google Scholar 

  10. Fang C, Bandaru NM, Ellis AV et al (2012) Electrochemical fabrication of nanoporous gold. J Mater Chem 22:2952–2957

    Article  CAS  Google Scholar 

  11. Gupta G, Thorp JC, Mara NA et al (2012) Morphology and porosity of nanoporous Au thin films formed by dealloying of AuxSi1−x. J Appl Phys 112:094320

    Article  CAS  Google Scholar 

  12. Hayes JR, Hodge AM, Biener J et al (2006) Monolithic nanoporous copper by dealloying Mn–Cu. J Mater Res 21:2611–2616

    Article  CAS  Google Scholar 

  13. Zhao C, Qi Z, Wang X et al (2009) Fabrication and characterization of monolithic nanoporous copper through chemical dealloying of Mg–Cu alloys. Corros Sci 51:2120–2125

    Article  CAS  Google Scholar 

  14. Qi Z, Zhao C, Wang X et al (2009) Formation and characterization of monolithic Nanoporous copper by chemical dealloying of Al−Cu alloys. J Phys Chem C 113:6694–6698

    Article  CAS  Google Scholar 

  15. Li M, Zhou Y, Geng H (2012) Fabrication of nanoporous copper ribbons by dealloying of Al–Cu alloys. J Porous Mater 19:791–796

    Article  CAS  Google Scholar 

  16. Dan Z, Qin F, Sugawara Y et al (2012) Fabrication of nanoporous copper by dealloying amorphous binary Ti–Cu alloys in hydrofluoric acid solutions. Intermetallics 29:14–20

    Article  CAS  Google Scholar 

  17. Dan Z, Qin F, Sugawara Y et al (2013) Nanoporous copper dealloyed from a nanocrystallized Ticu alloy. Mater Sci Forum 750:72–75

    Article  CAS  Google Scholar 

  18. Yu J, Ding Y, Xu C et al (2008) Nanoporous metals by dealloying multicomponent metallic glasses. Chem Mater 20:4548–4550

    Article  CAS  Google Scholar 

  19. Hakamada M, Mabuchi M (2009) Fabrication of nanoporous palladium by dealloying and its thermal coarsening. J Alloys Compd 479:326–329

    Article  CAS  Google Scholar 

  20. Wang X, Wang W, Qi Z et al (2010) Fabrication, microstructure and electrocatalytic property of novel nanoporous palladium composites. J Alloys Compd 508:463–470

    Article  CAS  Google Scholar 

  21. Zhang C, Ji H, Sun J et al (2013) Fabrication of nanoporous Pd with superior hydrogen sensing properties by dealloying. Mater Lett 92:369–371

    Article  CAS  Google Scholar 

  22. Zielasek V, Jürgens B, Schulz C et al (2006) Gold catalysts: nanoporous gold foams. Angew Chem Int Ed 45:8241–8244

    Article  CAS  Google Scholar 

  23. Wittstock A, Neumann B, Schaefer A et al (2009) Nanoporous Au: an unsupported pure gold catalyst? J Phys Chem C 113:5593–5600

    Article  CAS  Google Scholar 

  24. Fajín JLC, Cordeiro MNDS, Gomes JRB (2011) On the theoretical understanding of the unexpected O2 activation by nanoporous gold. Chem Commun 47:8403–8405

    Article  CAS  Google Scholar 

  25. Moskaleva LV, Röhe S, Wittstock A et al (2011) Silver residues as a possible key to a remarkable oxidative catalytic activity of nanoporous gold. Phys Chem Chem Phys 13:4529–4539

    Article  CAS  Google Scholar 

  26. Wittstock A, Wichmann A, Biener J et al (2011) Nanoporous gold: a new gold catalyst with tunable properties. Faraday Discuss 152:87–98

    Article  CAS  Google Scholar 

  27. Fujita T, Guan P, McKenna K et al (2012) Atomic origins of the high catalytic activity of nanoporous gold. Nat Mater 11:775–780

    Article  CAS  Google Scholar 

  28. Xu C, Su J, Xu X et al (2007) Low temperature CO oxidation over unsupported nanoporous gold. J Am Chem Soc 129:42–43

    Article  CAS  Google Scholar 

  29. Xu C, Xu X, Su J et al (2007) Research on unsupported nanoporous gold catalyst for CO oxidation. J Catal 252:243–248

    Article  CAS  Google Scholar 

  30. Han D-Q, Zhou C-Q, Yin H-M et al (2011) Reactivity of the alkaline pretreated nanoporous gold for the CO oxidation. Catal Lett 141:1026–1031

    Article  CAS  Google Scholar 

  31. Yin H, Zhou C, Xu C et al (2008) Aerobic oxidation of d-Glucose on support-Free nanoporous gold. J Phys Chem C 112:9673–9678

    Article  CAS  Google Scholar 

  32. Wittstock A, Biener J, Bäumer M (2012) Nanoporous gold: a new material for catalytic and sensor applications. Phys Chem Chem Phys 12:12919–12930

    Article  CAS  Google Scholar 

  33. Wittstock A, Zielasek V, Biener J et al (2010) Nanoporous gold catalysts for selective gas-phase oxidative coupling of methanol at low temperature. Science 327:319–322

    Article  CAS  Google Scholar 

  34. Kosuda KM, Wittstock A, Friend CM et al (2012) Oxygen-mediated coupling of alcohols over nanoporous gold catalysts at ambient pressures. Angew Chem Int Ed 51:1698–1701

    Article  CAS  Google Scholar 

  35. Kong X-M, Shen L-L (2012) Selectivity control of ethanol gas-phase oxidation over nanoporous gold. Catal Commun 24:34–37

    Article  CAS  Google Scholar 

  36. Asao N, Ishikawa Y, Hatakeyama N et al (2010) Nanostructured materials as catalysts: nanoporous-gold-catalyzed oxidation of organosilanes with water. Angew Chem Int Ed 49:10093–10095

    Article  CAS  Google Scholar 

  37. Asao N, Hatakeyama N, Menggenbateer et al (2012) Aerobic oxidation of alcohols in the liquid phase with nanoporous gold catalysts. Chem Commun 48:4540–4542

    Article  CAS  Google Scholar 

  38. Asao N, Meggenbateer, Seya Y et al (2012) Nanoporous gold-catalyzed [4 + 2] benzannulation between ortho-alkynylbenzaldehydes and alkynes. Synlett 23:66–69

    Google Scholar 

  39. Ishikawa Y, Yamamoto Y, Asao N et al (2013) Selective hydrosilylation of alkynes with a nanoporous gold catalyst. Catal Sci Technol 3:2902–2905

    Article  CAS  Google Scholar 

  40. Tanaka S, Kaneko T, Asao N et al (2011) A nanostructured skeleton catalyst: Suzuki-coupling with a reusable and sustainable nanoporous metallic glass Pd-catalyst. Chem Commun 47:5985–5987

    Article  CAS  Google Scholar 

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Correspondence to Mei Yan .

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Yan, M. (2014). The Fabrication of Nanoporous Metals (Au, Cu, Pd) and Their Application in Heterogeneous Molecular Transformations. In: Development of New Catalytic Performance of Nanoporous Metals for Organic Reactions. Springer Theses. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54931-4_1

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