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Advanced Analysis of Surface Films Formed on Passive Metals and Alloys Using X-ray Photoelectron Spectroscopy

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Progress in Advanced Structural and Functional Materials Design

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Abstract

Most of high corrosion resistance advanced structural and functional metals and alloys are protected by passive films, that is oxide and/or hydroxide films of few nm in thickness. In this chapter, properties of oxide/hydroxide film formed on metals and alloys are briefly summarized, then the procedure of quantitative analysis of passive film using X-ray photoelectron spectroscopy is described in detail as a one of characterization technique. Passive films on Cr containing high corrosion alloys, such as stainless steels, high nickel alloys, Co–Cr alloys, consist of highly Cr enriched oxide layer and covering hydroxide layer. Assuming the duplex model, the thickness and the content including chemical states in both layers, are quantitatively estimated from deconvoluted XPS spectra acquired without any sputtering technique.

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Authors and Affiliations

  1. Division of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka, 565-0871, Japan

    Shinji Fujimoto

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  1. Shinji Fujimoto
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Correspondence to Shinji Fujimoto .

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Editors and Affiliations

  1. , Graduate School of Engineering, Osaka University, Yamada-oka, Suita 2-1, Osaka, 565-0871, Japan

    Tomoyuki Kakeshita

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Fujimoto, S. (2013). Advanced Analysis of Surface Films Formed on Passive Metals and Alloys Using X-ray Photoelectron Spectroscopy. In: Kakeshita, T. (eds) Progress in Advanced Structural and Functional Materials Design. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54064-9_6

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