Abstract
High spatial resolution X-ray microanalysis of thin foils, in a transmission electron microscope, was applied to determine solute content profiles existing across the α lamellae formed by discontinuous precipitation (DP) in an Al-22 at. % Zn alloy. This technique, combined with the in situ observation of the kinetics of the process, allowed us to treat the DP reaction as a local phenomenon. The calculated diffusivity at a moving reaction front was found to be in good agreement with the data on diffusion at a stationary grain boundary and, in this way, the discrepancies resulting from the consideration of the DP as a global reaction were eliminated
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References
D. Turnbull, Acta Metall. 1955, 3, 55.
J. W. Cahn, Acta Metall. 1959, 7, 18.
K. N. Tu, D. B. Turnbull, Scripta Metall. 1967, 1, 173.
J. Petermann, E. Hornbogen, Z. Metallkd. 1968, 59, 814.
M. Hillert, Acta Metall. 1982, 30, 1689.
W. Gust, DsC Thesis, University of Stuttgart, 1980.
T. H. Chuang, Ph. D. Thesis, University of Stuttgart, 1983.
S. Abdou, Ph. D. Thesis, Suez Canal University, Port Said, 1987.
C. F. Yang, G. Sarkar, R. A. Fournelle, Acta Metall. 1988, 36, 1511.
G. R. Purdy, in: Materials Science and Technology. A Comprehensive Treatment, Vol. 5-Phase Transformations in Materials, (R. W. Cahn, P. Haasen, E. J. Kramer, eds. ), VCH Vevlogsgesellschoft, 1995, p. 331.
I. Kaur, W. Gust, Defect and Diffusion Forum 1989, 66, 765.
A. Pawłowski, P. Zięba, Arch. Metallurgy 1990, 35, 401.
A. Hässner, Kristall und Technik 1974, 9, 1371.
V. Suresh, S. Gupta, Z. Metallkd. 1986, 77, 529.
P. Zięba, A. Pawłowski, Mater. Sci. Eng. A 1994, 187, 57.
P. Zięba, A. Pawłowski, Arch. Metallurgy 1988, 33, 627.
G. W. Lorimer, G. Cliff, J. N. Clark, Developments in Electron Microscopy and Analysis (J. A. Venables, ed.) The Academic Press, London, 1976 p. 153.
P. M. Kelly, A. Jostsons, R. G. Blake, J. G. Napier, Phys. Stat. Sol. A 1975, 31, 111.
G. Cliff, G. W. Lorimer, J. Microscopy 1975, 103, 203.
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© 1998 Springer-Verlag Wien
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Zięba, P. (1998). Analytical Electron Microscopy of Diffusional Interfaces in an Al-22 at.% Zn Alloy. In: Love, G., Nicholson, W.A.P., Armigliato, A. (eds) Modern Developments and Applications in Microbeam Analysis. Mikrochimica Acta Supplement, vol 15. Springer, Vienna. https://doi.org/10.1007/978-3-7091-7506-4_9
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DOI: https://doi.org/10.1007/978-3-7091-7506-4_9
Publisher Name: Springer, Vienna
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