Abstract
A new use of vibrational intensity spectroscopy is proposed for the characterization of non-linear optical responses of polyconjugated organic molecules. The experimental and theoretical results obtained for several molecules are reported and discussed. These data prove that it is possible to use the vibrational approach as a new method for measuring molecular hyperpolarizabilities, which in some cases can be competitive with the more traditional ones. A theoretical justification of the method is also presented.
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References
D. S. Chemla, J. Zyss (eds.), Nonlinear Optical Properties of Organic Molecules and Crystals, Vols. 1 and 2, Academic Press, New York, 1987.
D. J. Williams, Angew. Chem. Int. Ed. Engl. 1984, 23, 690.
P. N. Prasad, D. J. Williams, Introduction to Nonlinear Optical Effects in Molecules and Polymers, Wiley, New York, 1991.
S. R. Marder, J. E. Sohn, G. D. Stucky (eds.). Materials for Nonlinear Optics, American Chemical Society, Washington, D. C., 1991.
R. A. Hann, D. Bloor (eds.). Organic Materials for Nonlinear Optics, Royal Society of Chemistry, London, 1989.
C. Castiglioni, M. Gussoni, G. Zerbi, J. Mol. Struct. 1989, 198, 475.
M. Gussoni, C. Castiglioni, M. N. Ramos, M. Rui, G. Zerbi, J. Mol. Struct. 1990, 224, 445.
J. C. Decius, J. Mol. Spectrosc. 1975, 57, 348.
A. J. van Straten, W. M. A. Smit, J. Mol. Spectrosc. 1976, 62, 297.
M. Gussoni, C. Castighoni, M. Miragoli, G. Lugh, G. Zerbi, Spectrochim. Acta 1985, 41 A, 371.
G. Zerbi, M. Gussoni, C. Castiglioni, Springer Series in Solid State Science 63, 1985, 156.
C. Castighoni, M. Del Zoppo, G. Zerbi, J. Raman Spectrosc. 1993, 24, 485.
W. L. Peticolas, C. Blazej, Chem. Phys. Lett. 1979, 63, 604.
M. Gussoni, C. Castiglioni, G. Zerbi, in: Advances in Material Science Spectroscopy (R. H. Clark, R. E. Hester, eds.), Wiley, Chichester, 1991, Chap. 5.
C. Castighoni, M. Gussoni, M. Del Zoppo, G. Zerbi, Solid State Commun. 1992, 82, 13.
C. Castiglioni, M. Del Zoppo, P. Zuhani, G. Zerbi, Synth. Met. 1995, 74, 171.
M. Del Zoppo, C. Castighoni, G. Zerbi, M. Rui, M. Gussoni, Synth. Met. 1992, 51, 135.
M. Del Zoppo, C. Castiglioni, M. Veronelli, G. Zerbi, Synth. Met. 1993, 57, 3919.
P. Zuhani, M. Del Zoppo, C. Castiglioni, G. Zerbi, C. Andraud, T. Brotin, A. Collet, J. Phys. Chem. 1995, 99, 16242.
L. T. Cheng, W. Tam, S. H. Marder, A. E. Stiegman, G. Rikken, C. W. Spangler, J. Phys. Chem. 1991, 95, 10643.
J. Zyss, T. Chau Van, C. Dhenaut, I. Ledoux, Chem. Phys. 1993, 177, 281.
C. Andraud, A. Collet, Private communication.
G. J. B. Hurst, M. Dupuis, E. Clementi, J. Chem. Phys. 1988, 89, 385.
J. P. Hermann, J. Ducuing, J. Appl. Phys. 1974, 45, 5100.
M. Veronelli, Thesis, Politecnico di Milano, 1994.
V. Hernandez, G. Zerbi, to be pubhshed.
D. Beljonne, Z. Shuai, J. L. Brédas, J. Chem. Phys. 1993, 98, 8819.
P. Zuhani, M. Del Zoppo, C. Castiglioni, G. Zerbi, S. R. Marder, J. W. Perry, J. Chem. Phys. 1995, 103, 9935.
S. R. Marder, D. N. Beratan, L.-T. Cheng, Science 1991, 252, 103.
S. R. Marder, J. W. Perry, G. Bourhill, C. B. Gorman, B. G. Tiemann, K. Mansour, Science 1993, 261, 186.
F. Meyers, S. R. Marder, B. M. Pierce, J. L. Brédas, Chem. Phys. Lett. 1994, 228, 171.
C. Castighoni, M. Del Zoppo, G. Zerbi, Phys. Rev. B 1996, 53, 13319.
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Del Zoppo, M., Castiglioni, C., Zuliani, P., Zerbi, G. (1997). From Vibrational Intensity Spectroscopy to Non-linear Optical Properties of Organic Molecules in Electronics and Photonics. In: Mink, J., Keresztury, G., Kellner, R. (eds) Progress in Fourier Transform Spectroscopy. Mikrochimica Acta Supplement, vol 14. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6840-0_12
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DOI: https://doi.org/10.1007/978-3-7091-6840-0_12
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