Abstract
We performed two types of experiments on polycrystalline SrTiO3 thin films at temperatures between 573 and 1273 K in reducing gas mixtures containing CO or CH4. Using an FT-IR spectrometer with a long-path gas cell, we analysed the composition of the gas mixture by means of absorption measurements before and after its exposure to the sample, and in a second step we measured the emission from the surface of the metal oxide. The absorption experiments revealed two different catalytically activated processes of CO oxidation, at 950 and 1100 K respectively. In the temperature region where catalytic conversion predominates, the oxidation of CO has an Eley-Rideal type characteristic, whereas the oxidation of CH4 obeys a Langmuir-Hinshelwood mechanism. The experiments with CH4 showed a pronounced dependence on the oxygen partial pressure above 1040 K, which could originate from reduction of the SrTiO3 surface. We found emission from physisorbed CO2 in CO-containing atmospheres, but no emission from adsorbed molecules was found in the experiments with CH4.
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© 1997 Springer-Verlag Wien
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Meyer, F.A., Pohle, R., Gerblinger, J., Meixner, H. (1997). Emission and Absorption Experiments on Strontium Titanate in Reducing Atmospheres. In: Mink, J., Keresztury, G., Kellner, R. (eds) Progress in Fourier Transform Spectroscopy. Mikrochimica Acta Supplement, vol 14. Springer, Vienna. https://doi.org/10.1007/978-3-7091-6840-0_115
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DOI: https://doi.org/10.1007/978-3-7091-6840-0_115
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