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Basis of Derivative Spectrophotometry

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Book cover Derivative Spectrophotometry and Electron Spin Resonance (ESR) Spectroscopy for Ecological and Biological Questions

Abstract

Photobiological processes occur under the influence of light of ultraviolet (UV), visible, and near infrared spectral regions. Generally, values of light flux intensity, I, and wavelength, λ are used in optical measurements. The frequency index \( \bar{\nu } \) is also considered to characterize an absorbed light. Frequency is expressed in reciprocal seconds [c−1] and presents itself as the ratio of a radiation velocity c to a wavelength λ [cm or nm]:

$$ \bar{\nu } = c/\lambda = {3.10^{{17}}}/{\lambda_{\rm{nm}}}, $$

where c =3 × 1010 cm⋅c−1 or 3 × 1017 nm⋅c−1, the velocity of light. The frequently used index is the wavenumber \( \bar{\nu } \) equal to the number of waves in 1 cm. The wavenumber is a reciprocal wavelength expressed in reciprocal centimeters:

$$ [{\hbox{c}}{{\hbox{m}}^{{ - 1}}}]:\bar{\nu } = 1/{\lambda_{\rm{cm}}} = {10^7}/{\lambda_{\rm{nm}}} $$

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Authors and Affiliations

  1. Sechenov Institute of Evolutionary Physiol. and Biochem., Russian Academy of Science, Thorez Av. 44, Saint-Petersburg, Russia

    Vladimir S. Saakov

  2. Department of Physics, State Electrotechnical University, Saint-Petersburg, Russia

    Valery Z. Drapkin, Yuri V. Bogachev & Mikhail N. Knyazev

  3. Sechenov Inst. of Evolutionary Physiol. and Biochem., Russian Academy of Science, Saint-Petersburg, Russia

    Alexander I. Krivchenko & Eugene V. Rozengart

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  1. Vladimir S. Saakov
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Correspondence to Vladimir S. Saakov .

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Saakov, V.S., Drapkin, V.Z., Krivchenko, A.I., Rozengart, E.V., Bogachev, Y.V., Knyazev, M.N. (2013). Basis of Derivative Spectrophotometry. In: Derivative Spectrophotometry and Electron Spin Resonance (ESR) Spectroscopy for Ecological and Biological Questions. Springer, Vienna. https://doi.org/10.1007/978-3-7091-1007-2_2

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